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    METHOD FOR PRODUCING THIOLANE SKELETON-TYPE GLYCOCONJUGATE, AND THIOLANE SKELETON-TYPE GLYCOCONJUGATE
    2.
    发明申请
    METHOD FOR PRODUCING THIOLANE SKELETON-TYPE GLYCOCONJUGATE, AND THIOLANE SKELETON-TYPE GLYCOCONJUGATE 有权
    用于生产硫醇酮型糖苷酸盐的方法，以及硫醇型骨架型糖蛋白

    公开(公告)号：US20160355536A1

    公开(公告)日：2016-12-08

    申请号：US15238232

    申请日：2016-08-16

    申请人： FUJIFILM Corporation

    发明人： Takayuki ITO ,  Toru WATANABE ,  Hideki OKADA ,  Hidenobu KUNIYOSHI

    IPC分类号： C07H13/08 ,  C07D333/32 ,  C07H15/04

    CPC分类号： C07H13/08 ,  C07D333/32 ,  C07H15/04 ,  C07H15/18

    摘要： There is provided a production method of a compound represented by the following formula (II) through a step of reacting a compound represented by the following General Formula (I) with a sulfur compound. In General Formulas (I) and (II), R1 represents a hydrogen atom or an acyl group, R2 represents a hydrogen atom, a fluorine atom, an acyloxy group, an arylmethyloxy group, an allyloxy group, an arylmethyloxycarbonyloxy group, or an allyloxycarbonyloxy group, R3 represents a hydrogen atom or an acyloxy group, R5 represents an alkyl group or an aryl group, and X represents a leaving group. Here, in a case where R2 is a fluorine atom, an acyloxy group, an arylmethyloxy group, an allyloxy group, an arylmethyloxycarbonyloxy group, or an allyloxycarbonyloxy group, R3 is an acyloxy group.

    摘要翻译： 在通式（I）和（II）中，R 1表示氢原子或酰基，R 2表示氢原子，氟原子，酰氧基，芳基甲氧基，烯丙氧基，芳基甲氧基羰基氧基或烯丙氧羰基氧基 基团，R 3表示氢原子或酰氧基，R 5表示烷基或芳基，X表示离去基团。 这里，在R 2为氟原子，酰氧基，芳基甲氧基，烯丙氧基，芳基甲氧基羰基氧基或烯丙氧基羰基氧基的情况下，R 3为酰氧基。