Removal of halogenated organic compounds from hydrocarbon streams
    5.
    发明授权
    Removal of halogenated organic compounds from hydrocarbon streams 失效
    从烃流中去除卤代有机化合物

    公开(公告)号:US5928500A

    公开(公告)日:1999-07-27

    申请号:US947099

    申请日:1997-10-08

    摘要: This invention is a process for removing minor amounts of organic halide e.g., organic chloride, contaminants from hydrocarbon feedstocks by contact with a regenerable solid adsorbent comprising a metal and/or metal hydride selected from nickel, cobalt or iron, or mixtures thereof on a porous refractory support, such as silica, whereby the halide present in the hydrocarbon feedstock is converted substantially to an insoluble metal halide salt of the supported metal or metal hydride with the hydrocarbon feedstock being recovered from the contacting step substantially free of organic halide contaminant. Also disclosed is a process for regeneration of the adsorbent loaded with metal halide from the hydrocarbon feedstock contacting step and an integrated process where the regenerated adsorbent is reused to remove additional organic halide from the hydrocarbon feedstock.

    摘要翻译: 本发明是一种通过与包含选自镍,钴或铁的金属和/或金属氢化物或其混合物的可再生固体吸附剂接触的烃原料中的少量有机卤化物例如有机氯化物,或其混合物与多孔 耐火载体,例如二氧化硅,其中存在于烃原料中的卤化物基本上转化为负载金属或金属氢化物的不溶性金属卤化物盐,其中烃原料从基本上不含有机卤化物污染物的接触步骤中回收。 还公开了一种从烃原料接触步骤中再生装载有金属卤化物的吸附剂的方法和其中再生的吸附剂被再次用于从烃原料中除去另外的有机卤化物的一体化方法。

    Method for preparing dual colloid catalyst compositions
    6.
    发明授权
    Method for preparing dual colloid catalyst compositions 失效
    双胶体催化剂组合物的制备方法

    公开(公告)号:US4590177A

    公开(公告)日:1986-05-20

    申请号:US639442

    申请日:1984-08-10

    CPC分类号: B01J37/036 B01J23/78

    摘要: Disclosed is a method for preparing dual colloid catalyst compositions wherein a gel, or colloidal suspension is formed by admixing (a) a 0.6 to 10M aqueous solution containing one or more soluble salts or complexes of one or more transition metals, wherein at least one of the transition metals is reducible and hydrolyzable, and one or more elements selected from Cr, Al, Si, Th, U, the lanthanides, and elements from Groups IA and IIA of the Periodic Table of the Elements, with (b) a 0.5 to 10N aqueous base solution. The solid material is separated from the resulting gel, or colloidal suspension and washed and dried.

    摘要翻译: 公开了一种制备双重胶体催化剂组合物的方法,其中通过混合(a)含有一种或多种一种或多种过渡金属的一种或多种可溶性盐或络合物的0.6至10M水溶液形成凝胶或胶态悬浮液,其中至少一种 过渡金属是可还原的和可水解的,以及选自元素周期表的IA,IIA族中的Cr,Al,Si,Th,U,镧系元素和元素中的一种或多种元素,(b)0.5至 10N水​​溶液。 将固体材料与所得凝胶或胶体悬浮液分离并洗涤并干燥。

    CATALYST AND CATALYST CARRIER
    7.
    发明申请
    CATALYST AND CATALYST CARRIER 有权
    催化剂和催化剂载体

    公开(公告)号:US20140100379A1

    公开(公告)日:2014-04-10

    申请号:US13648303

    申请日:2012-10-10

    IPC分类号: B01J27/02 C07D301/04

    摘要: The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO2 and no more than 0.04 wt percent Na2O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m2/g) no greater than 0.50 g/m2. Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt %, relative to the weight of the catalyst. A reactor to system for the epoxidation of olefins is also disclosed.

    摘要翻译: 本发明的载体包括至少85wt%的α氧化铝,至少0.06wt%的SiO 2和不超过0.04wt%的Na 2 O. 载体的吸水率不大于0.35g / g,吸水率(g / g)与表面积(m2 / g)不大于0.50g / m 2。 本发明的另一方面是用于烯烃环氧化的催化剂,其包含分散在其上的上述载体和银,其中载体具有单峰,双峰或多峰孔分布,并且其中银的量为5至50重量% 相对于催化剂的重量。 还公开了用于烯烃的环氧化反应器的反应器。