Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones
    8.
    发明授权
    Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones 有权
    用双 - 和多 - 2-恶唑烷酮交联水凝胶的方法

    公开(公告)号:US06472478B1

    公开(公告)日:2002-10-29

    申请号:US09601349

    申请日:2000-08-18

    IPC分类号: C08F830

    摘要: The invention relates to a process for the gel or surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked and dried by means of an increase in temperature, the crosslinker being a compound of the formula in which R1 and R2 independently of one another are H, hydroxyl, phenyl or C1-C6-alkyl, R3 is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R4 and R5 independently of one another are C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl, hydroxyl, C1-C12-alkoxy or hydrogen, dissolved in an inert solvent, to water-absorbing polymers which can be obtained by said process, and to their use in hygiene articles, packaging materials and nonwovens.

    摘要翻译: 本发明涉及一种吸水聚合物的凝胶或表面后交联方法,其中聚合物用表面后交联溶液处理,并且在处理之间或之后,通过温度升高进行后交联和干燥,交联剂为 R 1和R 2彼此独立地是H,羟基,苯基或C 1 -C 6烷基的化合物,R 3是氢,C 1 -C 12 - 烷基,C 1 -C 12 - 烯基或C 6 -C 12 - 芳基,R 4和R 5 彼此独立地是溶解在惰性溶剂中的C 1 -C 12烷基,C 1 -C 12 - 烯基,C 6 -C 12 - 芳基,羟基,C 1 -C 12 - 烷氧基或氢,可以通过所述 过程,以及它们在卫生用品,包装材料和无纺布中的应用。

    Method for the secondary cross-linking of hydrogels with N-acyl-2-oxazolidinones
    9.
    发明授权
    Method for the secondary cross-linking of hydrogels with N-acyl-2-oxazolidinones 失效
    水凝胶与N-酰基-2-恶唑烷酮二次交联的方法

    公开(公告)号:US06559239B1

    公开(公告)日:2003-05-06

    申请号:US09831920

    申请日:2001-05-29

    IPC分类号: C08F830

    摘要: Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the surface postcrosslinking solution comprises as crosslinker a compound of the formula I where R1, R2, R3 and R4 are independently hydrogen, C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl or C1-C12-alkoxy, R5 is C1-C16-alkyl, C1-C4-hydroxyalkyl, C6-C12-aryl, C1-C16-alkenyl or a group of the formula —(CH2)n—COOH or —(CH2)n—SO3H in the form of the acid or a respective metal salt, ammonium salt or triethanolammonium salt thereof or —(CH2—CH2—O—)m—R6, R6 is hydrogen or C1-C16-alkyl, n is from 1 to 10, m is from 1 to 20 dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.

    摘要翻译: 通过用表面后交联溶液处理的聚合物进行凝胶和/或表面后吸附吸水性聚合物的方法制备液体吸收聚合物,并且在处理之间和之后通过升高温度进行后交联和干燥,其中表面 后交联溶液包含作为交联剂的式I化合物,其中R 1,R 2,R 3和R 4独立地是氢,C 1 -C 12 - 烷基,C 1 -C 12 - 烯基,C 6 -C 12 - 芳基或C 1 -C 12 - 烷氧基,R 5是C 1 -C 16 - 烷基,C 1 -C 4 - 羟基烷基,C 6 -C 12 - 芳基,C 1 -C 16 - 烯基或式 - (CH 2)n -COOH或 - (CH 2)n -SO 3 H的基团,其形式为酸或相应的 金属盐,铵盐或三乙醇铵盐或 - (CH 2 -CH 2 -O-)m -R 6,R 6是氢或C 1 -C 16 - 烷基,n为1至10,m为1至20,溶于惰性溶剂 ,用于卫生用品,包装材料和无纺布。

    Method for the secondary cross-linking of hydrogels with 2-oxotetrahydro-1,3-oxazines
    10.
    发明授权
    Method for the secondary cross-linking of hydrogels with 2-oxotetrahydro-1,3-oxazines 有权
    水凝胶与2-氧代四氢-1,3-恶嗪二次交联的方法

    公开(公告)号:US06657015B1

    公开(公告)日:2003-12-02

    申请号:US09831382

    申请日:2001-05-17

    IPC分类号: C08F830

    摘要: Liquid-absorbent polymers are prepared by a process for the gel and/or surface postcrosslinking of water-absorbent polymers by the polymer being treated with a surface postcrosslinking solution and being postcrosslinked and dried during and after the treatment by raising the temperature, wherein the crosslinker comprises a compound of the formula I where R1 is hydrogen, C1-C4-alkyl, C1-C4-hydroxyalkyl, trialkylsilyl or acetyl and R2, R2′, R3, R3′, R4, R4′ are each independently hydrogen, C1-C12-alkyl, C2-C12-alkenyl or C6-C12-aryl, dissolved in an inert solvent, and are used in hygiene articles, packaging materials and nonwovens.

    摘要翻译: 通过用表面后交联溶液处理的聚合物对吸水性聚合物进行凝胶和/或表面后交联的方法制备液体吸收性聚合物,并且在处理期间和之后通过升高温度进行后交联和干燥,其中交联剂 包括其中R 1为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 羟基烷基,三烷基甲硅烷基或乙酰基且R 2,R 2',R 3,R 3'的式I化合物, >,R 4,R 4'各自独立地为氢,C 1 -C 12 - 烷基,C 2 -C 12 - 烯基或C 6 -C 12 - 芳基,溶于惰性溶剂中,并用于卫生用品,包装材料 和无纺布。