Preparation of low-solvent alkyl diketenes
    5.
    发明授权
    Preparation of low-solvent alkyl diketenes 失效
    低溶剂烷基双烯酮的制备

    公开(公告)号:US5672721A

    公开(公告)日:1997-09-30

    申请号:US638225

    申请日:1996-04-26

    摘要: A process for the preparation of low-solvent alkyl diketenes of the general formula: ##STR1## in which R.sup.1 denotes C.sub.10 -C.sub.30 alkyl or C.sub.10 -C.sub.30 alkenyl and R.sup.2 denotes hydrogen or C.sub.1 -C.sub.8 alkyl, by causing carboxylic chlorides of the formula II ##STR2## in which R.sup.1 and R.sup.2 have the aforementioned meanings, to react with tertiary amines of the formula III ##STR3## in which R.sup.3, R.sup.4, R.sup.5 denote C.sub.1 -C.sub.12 alkyl or C.sub.3 -C.sub.12 cycloalkyl and R.sup.3 and R.sup.4 together denote a C.sub.2 -C.sub.11 alkylene dichain optionally interrupted by oxygen or nitrogen, in a substantially water-immiscible, inert solvent, wherein distillation is carried out at temperatures ranging from 80.degree. to 130.degree. C. and pressures ranging from 10 to 500 mbar and subsequently with the addition of water or steam.

    摘要翻译: 制备通式如下的低溶剂烷基双烯酮的方法:其中R 1表示C 10 -C 30烷基或C 10 -C 30烯基,R 2表示氢或C 1 -C 8烷基,通过使羧酸氯化物 其中R 1和R 2具有上述含义的式II(II)与式III的叔胺反应,其中R 3,R 4,R 5表示C 1 -C 12烷基或C 3 -C 12 环烷基,R3和R4一起表示在基本上与水不混溶的惰性溶剂中任选地被氧或氮中断的C 2 -C 11亚烷基双键,其中蒸馏在80-130℃的温度下进行, 10至500毫巴,随后加入水或蒸汽。

    METHOD FOR PRODUCING ETHYLENE COPOLYMERS
    7.
    发明申请
    METHOD FOR PRODUCING ETHYLENE COPOLYMERS 审中-公开
    乙烯共聚物生产方法

    公开(公告)号:US20110184129A1

    公开(公告)日:2011-07-28

    申请号:US12301776

    申请日:2007-05-15

    IPC分类号: C08F220/06 C08F2/06 C08F2/00

    摘要: Process for the continuous preparation of ethylene copolymers by free-radical copolymerization of ethylene and at least one comonomer (b) selected from among ethylenically unsaturated carboxylic acids, esters of ethylenically unsaturated carboxylic acids, ethylenically unsaturated phosphonic acids and esters of ethylenically unsaturated phosphonic acids, wherein one or more inhibitors are metered separately from ethylene and the comonomer or comonomers (b) into the reaction mixture.

    摘要翻译: 通过乙烯和至少一种选自烯键式不饱和羧酸,烯属不饱和羧酸酯,烯属不饱和膦酸和烯属不饱和膦酸酯的共聚单体(b)的自由基共聚连续制备乙烯共聚物的方法, 其中将一种或多种抑制剂与乙烯和共聚单体或共聚单体(b)分开计量加入到反应混合物中。

    COMPOSITE MATERIALS AND METHOD FOR PRODUCTION THEREOF
    8.
    发明申请
    COMPOSITE MATERIALS AND METHOD FOR PRODUCTION THEREOF 审中-公开
    复合材料及其生产方法

    公开(公告)号:US20100266792A1

    公开(公告)日:2010-10-21

    申请号:US12528295

    申请日:2008-02-20

    IPC分类号: C08L97/02 B32B1/00

    摘要: Composite materials comprising at least one natural fiber, at least one thermoplastic polymer, and at least one random copolymer having a molar mass Mn of up to 20,000 g/mol. The random copolymer is produced from the copolymerization of ethylene and at least one comonomer. The comonomer is selected from the group consisting of ethylenically unsaturated C3-C10 monocarboxylic acids; ethylenically unsaturated C4-C10 dicarboxylic acids or their anhydrides; epoxy esters of ethylenically unsaturated C3-C10 monocarboxylic acids, and (b4) comonomers of the general formula I: wherein R1 and R2 are a hydrogen or an unbranched or branched C1-C10-alkyl; R3 is identical or different and is a hydrogen, unbranched and branched C1-C10-alkyl or C3-C12-cycloalkyl, where two radicals R3 may be bonded together to form a 3-10-membered ring; X is an oxygen, sulfur or N—R4; R4 is an unbranched or branched C1-C10-alkyl; and A1 is a divalent group selected from C1-C10-alkylene, C4-C10-cycyloalkylene, and phenylene.

    摘要翻译: 包含至少一种天然纤维,至少一种热塑性聚合物和至少一种摩尔质量Mn高达20,000g / mol的无规共聚物的复合材料。 无规共聚物由乙烯与至少一种共聚单体的共聚制得。 共聚单体选自烯属不饱和C3-C10单羧酸; 烯键式不饱和C4-C10二羧酸或其酸酐; 烯属不饱和C3-C10单羧酸的环氧酯和(b4)通式I的共聚单体:其中R 1和R 2是氢或无支链或支链C 1 -C 10 - 烷基; R 3相同或不同,为氢,无支链和支链C 1 -C 10 - 烷基或C 3 -C 12 - 环烷基,其中两个基团R 3可以键合在一起形成3-10元环; X是氧,硫或N-R4; R4是无支链或支链的C1-C10-烷基; A1是选自C1-C10-亚烷基,C4-C10-氰基亚烷基和亚苯基的二价基团。