Three-dimensional (3D) printing with discolorable near-infrared absorbing dye

    公开(公告)号:US10857733B2

    公开(公告)日:2020-12-08

    申请号:US16077753

    申请日:2017-02-06

    Abstract: In an example of a three-dimensional (3D) printing method, a polymeric or polymeric composite build material is applied. A fusing agent is selectively applied on at least a portion of the polymeric or polymeric composite build material. The fusing agent includes a discolorable near-infrared absorbing dye, a thiol surfactant, a reducing agent, and a balance of water. Near-infrared radiation is applied to the polymeric or polymeric composite build material at a condition that maintains a temperature of the selectively applied fusing agent below a decomposition temperature of the fusing agent and that allows the discolorable near-infrared absorbing dye to harvest near-infrared radiation energy, in order to fuse the portion of the polymeric or polymeric composite build material in contact with the fusing agent to form a layer and to initiate discoloration of the discolorable near-infrared absorbing dye in the layer.

    Three-dimensional (3D) printing method

    公开(公告)号:US10583612B2

    公开(公告)日:2020-03-10

    申请号:US15100584

    申请日:2014-01-29

    Abstract: In a 3D printing method, a coalescent dispersion for forming a 3D object is selected. The dispersion includes an aqueous vehicle and an infrared or near-infrared binding agent dissolved or dispersed therein. The binding agent is a phthalocyanine having a polar group attached to each side chain or a naphthalocyanine having a polar group attached to each side chain. A sinterable material is deposited and heated to a temperature ranging from about 50 C to about 350 C. The dispersion is selectively applied on at least a portion of the sinterable material. The sinterable material and the dispersion applied thereon are exposed to infrared or near-infrared radiation. The binding agent absorbs the radiation and converts it to thermal energy. At least the portion of the sinterable material in contact with the binding agent is at least cured to form a first layer of the 3D object.

    Three-dimensional (3D) printing method

    公开(公告)号:US10434708B2

    公开(公告)日:2019-10-08

    申请号:US15121730

    申请日:2014-04-30

    Abstract: In a 3D printing method, a sinterable material is applied and heated to a temperature ranging from about 50° C. to about 400° C. A coalescent agent is selectively applied on a portion of the sinterable material, and a modifying agent is selectively applied on the portion and/or on another portion of the sinterable material. The modifying agent consists of an inorganic salt, a surfactant, a co-solvent, a humectant, a biocide, and water. The sinterable material is exposed to radiation, whereby the coalescent agent at least partially cures the portion of the sinterable material in contact with the coalescent agent, and the modifying agent i) reduces curing of the portion of the sinterable material in contact with both the coalescent agent and the modifying agent ii) prevents curing of the other portion of the sinterable material in contact with the modifying agent, or iii) both i and ii.

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