公开(公告)号：US20160130379A1

公开(公告)日：2016-05-12

申请号：US14971487

申请日：2015-12-16

Applicant: Honeywell International Inc. ,  Universite de Montpellier ,  Centre National de la Recherche Scientifique

Inventor： Alagappan Thenappan ,  Eric Rainal ,  Bruno Ameduri ,  Frederic Boschet ,  Noureddine Ajellal ,  Gerald Lopez

IPC: C08F214/24

CPC classification number: C08F214/24 ,  C08F259/00 ,  C08J5/18 ,  C08J2327/12

Abstract: A polymeric molecule having the formula: X—[C(A)2C(B)(B′)]n-Q[CY═C(Z)(Z′)] or [C(A)2=C(B)]n-Q[C(Y)(Y′)—C(Z)(Z′)]—X′, wherein A is either H or F; B and B′ are either H, F, or Cl, and are not necessarily the same; X and X′ are Br, Cl or I (and are not necessarily the same); Y and Y′ are F, Br, Cl or I (and are not necessarily the same); and wherein Z and Z′ are F, Br, Cl or I (and are not necessarily the same); Q is optional and is either oxygen (O) or sulfur (S); and n is at least 1.

Abstract translation: 具有下式的聚合物分子：X- [C（A）2C（B）（B'）] nQ [CY = C（Z）（Z'）]或[C（A）2 = C（B） [C（Y）（Y'）-C（Z）（Z'）] - X'，其中A为H或F; B和B'是H，F或Cl，并不一定相同; X和X'是Br，Cl或I（并不一定相同）; Y和Y'是F，Br，Cl或I（并不一定相同）; 并且其中Z和Z'是F，Br，Cl或I（并且不一定相同）; Q是任选的，并且是氧（O）或硫（S）; 且n至少为1。

公开(公告)号：US20150094428A1

公开(公告)日：2015-04-02

申请号：US14448062

申请日：2014-07-31

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Bruno Ameduri ,  Gerald Lopez

IPC: C08F299/00

CPC classification number: C08F214/242 ,  C08F2/38 ,  C08F214/24 ,  C08F293/005 ,  C08F2438/00

Abstract: Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “M” with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C1-C3 hydrocarbon, a C1-C6 hydrofluorocarbon, C1-C6 hydrochlorofluorocarbon, or C1-C6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.

Abstract translation: 公开了通过碘转移聚合合成CTFE基嵌段共聚物的方法。 在一个示例性实施方案中，一种方法包括使含氟单体“M”与式X-Y或Y-X-Y的链转移剂反应，其中X表示C1-C3烃，C1-C6氢氟烃，C1-C6 氯代氟代烃或C1-C6碳氟化合物，Y代表碘或溴，在自由基引发剂的存在下形成下式的大分子引发剂：X-聚（M）-Y或Y-聚（M）-X- 聚（M）-Y，其中聚（M）表示所述含氟单体的聚合物。 该方法还包括在自由基引发剂的存在下使大分子引发剂与氯三氟乙烯（CTFE）反应以形成下式的二嵌段或三嵌段CTFE基嵌段共聚物：X-聚（M） - 嵌段 - 聚（CTFE） 或PCTFE-嵌段 - 聚（M）-X-聚（M） - 嵌段-PCFEFE。

公开(公告)号：US09969899B2

公开(公告)日：2018-05-15

申请号：US14177784

申请日：2014-02-11

Applicant: Honeywell International Inc. ,  Centre National De La Recherche Scientifique

Inventor： Alagappan Thenappan ,  Bruno Ameduri ,  Gerald Lopez ,  Eric Rainal ,  Noureddine Ajellal ,  Gary Martin

IPC: C09D127/12 ,  B32B27/08 ,  C08J7/04 ,  B32B27/30 ,  B32B27/32 ,  B32B27/36 ,  C08F214/18 ,  C08J5/18

CPC classification number: C09D127/12 ,  B32B27/08 ,  B32B27/304 ,  B32B27/308 ,  B32B27/322 ,  B32B27/36 ,  B32B2307/412 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2439/00 ,  B32B2439/80 ,  B32B2581/00 ,  B32B2597/00 ,  C08F214/18 ,  C08J5/18 ,  C08J7/047 ,  C08J2327/06 ,  C08J2327/12 ,  C08J2367/02 ,  C08J2379/08 ,  C08J2427/04 ,  C08J2427/12 ,  Y10T428/31507 ,  Y10T428/31544

Abstract: Disclosed is a copolymer film that includes a first comonomer including a chlorofluoro olefin and a second comonomer that is selected from the group consisting of itaconic acid, 2,3-dihydropyran, D-glucal, glycerine carbonate vinyl ether, 2-hydroxypropyl acrylate, maleic anhydride, vinylidene chloride, and mixtures thereof.

公开(公告)号：US09777089B2

公开(公告)日：2017-10-03

申请号：US14971487

申请日：2015-12-16

Applicant: Honeywell International Inc. ,  Centre National de la Recherche Scientifique ,  Universite de Montpellier

Inventor： Alagappan Thenappan ,  Eric Rainal ,  Bruno Ameduri ,  Frederic Boschet ,  Noureddine Ajellal ,  Gerald Lopez

IPC: C08F214/24 ,  C08F259/00 ,  C08J5/18

CPC classification number: C08F214/24 ,  C08F259/00 ,  C08J5/18 ,  C08J2327/12

Abstract: A polymeric molecule having the formula: X—[C(A)2C(B)(B′)]n-Q[CY═C(Z)(Z′)] or [C(A)2=C(B)]n-Q[C(Y)(Y′)—C(Z)(Z′)]—X′, wherein A is either H or F; B and B′ are either H, F, or Cl, and are not necessarily the same; X and X′ are Br, Cl or I (and are not necessarily the same); Y and Y′ are F, Br, Cl or I (and are not necessarily the same); and wherein Z and Z′ are F, Br, Cl or I (and are not necessarily the same); Q is optional and is either oxygen (O) or sulfur (S); and n is at least 1.

公开(公告)号：US09394394B2

公开(公告)日：2016-07-19

申请号：US14448062

申请日：2014-07-31

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Bruno Ameduri ,  Gerald Lopez

IPC: C08F2/38 ,  C08F214/24 ,  C08F214/08 ,  C08F214/20 ,  C08F293/00

CPC classification number: C08F214/242 ,  C08F2/38 ,  C08F214/24 ,  C08F293/005 ,  C08F2438/00

Abstract: Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “M” with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C1-C3 hydrocarbon, a C1-C6 hydrofluorocarbon, C1-C6 hydrochlorofluorocarbon, or C1-C6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.

Abstract translation: 公开了通过碘转移聚合合成CTFE基嵌段共聚物的方法。 在一个示例性实施方案中，一种方法包括使含氟单体“M”与式X-Y或Y-X-Y的链转移剂反应，其中X表示C1-C3烃，C1-C6氢氟烃，C1-C6 氯代氟代烃或C1-C6碳氟化合物，Y代表碘或溴，在自由基引发剂的存在下形成下式的大分子引发剂：X-聚（M）-Y或Y-聚（M）-X- 聚（M）-Y，其中聚（M）表示所述含氟单体的聚合物。 该方法还包括在自由基引发剂的存在下使大分子引发剂与氯三氟乙烯（CTFE）反应以形成下式的二嵌段或三嵌段CTFE基嵌段共聚物：X-聚（M） - 嵌段 - 聚（CTFE） 或PCTFE-嵌段 - 聚（M）-X-聚（M） - 嵌段-PCFEFE。

公开(公告)号：US20140234630A1

公开(公告)日：2014-08-21

申请号：US14177784

申请日：2014-02-11

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Bruno Ameduri ,  Gerald Lopez ,  Eric Rainal ,  Noureddine Ajellal ,  Gary Martin

IPC: C09D127/12

CPC classification number: C09D127/12 ,  B32B27/08 ,  B32B27/304 ,  B32B27/308 ,  B32B27/322 ,  B32B27/36 ,  B32B2307/412 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2439/00 ,  B32B2439/80 ,  B32B2581/00 ,  B32B2597/00 ,  C08F214/18 ,  C08J5/18 ,  C08J7/047 ,  C08J2327/06 ,  C08J2327/12 ,  C08J2367/02 ,  C08J2379/08 ,  C08J2427/04 ,  C08J2427/12 ,  Y10T428/31507 ,  Y10T428/31544

Abstract: Disclosed is a copolymer film that includes a first comonomer including a chlorofluoro olefin and a second comonomer that is selected from the group consisting of itaconic acid, 2,3-dihydropyran, D-glucal, glycerine carbonate vinyl ether, 2-hydroxypropyl acrylate, maleic anhydride, vinylidene chloride, and mixtures thereof.

Abstract translation: 公开了一种共聚物膜，其包含第一共聚单体，其包含氯氟烯烃和选自衣康酸，2,3-二氢吡喃，D-葡萄糖，甘油碳酸酯乙烯基醚，丙烯酸2-羟丙酯，马来酸酐的第二共聚单体 酸酐，偏二氯乙烯及其混合物。

公开(公告)号：US09234062B2

公开(公告)日：2016-01-12

申请号：US13713630

申请日：2012-12-13

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Eric Rainal ,  Bruno Ameduri ,  Frédéric Boschet ,  Noureddine Ajellal ,  Gerald Lopez

IPC: C08F214/24 ,  C08F259/00 ,  C08F259/08 ,  C08F259/02 ,  C08J5/18

CPC classification number: C08F214/24 ,  C08F259/00 ,  C08J5/18 ,  C08J2327/12

Abstract: Fluorinated macromonomers, a PCTFE-g-poly(M) graft copolymer, and moisture barrier films and articles formed therefrom are provided. The PCTFE-g-poly(M) graft copolymers have a PCTFE backbone component and a plurality of pendant groups attached to the PCTFE backbone component.

Abstract translation: 提供氟化大分子单体，PCTFE-g-聚（M）接枝共聚物，以及防潮膜和由其形成的制品。 PCTFE-g-聚（M）接枝共聚物具有连接到PCTFE骨架组分的PCTFE骨架组分和多个侧基。

公开(公告)号：US20130184422A1

公开(公告)日：2013-07-18

申请号：US13713630

申请日：2012-12-13

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Eric Rainal ,  Bruno Ameduri ,  Frédéric Boschet ,  Noureddine Ajellal ,  Gerald Lopez

IPC: C08F214/24

CPC classification number: C08F214/24 ,  C08F259/00 ,  C08J5/18 ,  C08J2327/12

Abstract: Fluorinated macromonomers, a PCTFE-g-poly(M) graft copolymer, and moisture barrier films and articles formed therefrom are provided. The PCTFE-g-poly(M) graft copolymers have a PCTFE backbone component and a plurality of pendant groups attached to the PCTFE backbone component.

Abstract translation: 提供氟化大分子单体，PCTFE-g-聚（M）接枝共聚物，以及防潮膜和由其形成的制品。 PCTFE-g-聚（M）接枝共聚物具有连接到PCTFE骨架组分的PCTFE骨架组分和多个侧基。

公开(公告)号：US11654667B2

公开(公告)日：2023-05-23

申请号：US16864927

申请日：2020-05-01

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Gary M. Skwarek ,  Carl Altman ,  Jong Lee ,  Eric Rainal ,  Awdhoot Vasant Kerkar ,  Alagappan Thenappan

IPC: C08J5/18 ,  B32B27/32 ,  B32B27/36 ,  B32B27/34 ,  B65D75/30 ,  B32B37/15 ,  B29C48/00 ,  B29C48/18 ,  A61M35/00 ,  B32B27/08 ,  A61K9/70 ,  B29L31/00 ,  B29K27/00

CPC classification number: B32B27/322 ,  A61K9/703 ,  A61M35/00 ,  B29C48/0019 ,  B29C48/0021 ,  B29C48/022 ,  B29C48/18 ,  B32B27/08 ,  B32B27/325 ,  B32B27/34 ,  B32B27/36 ,  B32B37/153 ,  B65D75/30 ,  A61K9/7038 ,  A61K9/7084 ,  B29K2027/16 ,  B29L2031/712 ,  B32B2307/518 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2439/40 ,  B32B2439/80 ,  B32B2535/00

Abstract: Flexible packages, transdermal drug delivery devices, and methods for fabricating packages are provided. An exemplary flexible package includes a chemical and moisture resistant layer formed from poly(chlorotrifluoroethylene-co-vinylidene fluoride) (“P(CTFE-co-VDF)”) copolymer. Further, the exemplary flexible package includes a substance to be delivered. The substance is applied to or enclosed by the chemical and moisture resistant layer.

公开(公告)号：US09862811B2

公开(公告)日：2018-01-09

申请号：US14804660

申请日：2015-07-21

Applicant: Honeywell International Inc.

Inventor： Alagappan Thenappan ,  Eric Rainal

IPC: C08K5/19

CPC classification number: C08K5/19 ,  C08F14/24 ,  C08F2/16

Abstract: Methods for synthesizing stabilized polymers of chlorotrifluoroethylene and products manufactured using such polymers are disclosed herein. In one exemplary embodiment, a method for synthesizing chlorotrifluoroethylene (CTFE)-based polymers includes reacting, in the presence of an initiator and in a reaction medium at a pH of about 1.5 to about 2.5, one or more monomers comprising CTFE and after an amount of polymerization reaction time has passed, adding a neutralizing agent to the reaction medium to increase the pH of the reaction medium to within a range of about 1.8 to about 6.0.