摘要:
An apparatus for direct analysis of the redox products, or intermediates, of an electrochemical reaction by coupling an electrochemical cell to desorption electrospray ionization mass spectrometry.
摘要:
An apparatus for direct analysis of the redox products, or intermediates, of an electrochemical reaction by coupling an electrochemical cell to desorption electrospray ionization mass spectrometry.
摘要:
A microsecond time-resolved mass spectrometry device and method of using desorption electrospray ionization (10) was described for the kinetic study of fast reactions. The device includes a liquid jet generator (64) that is configured to emit a continuous liquid jet (50) having a length. An ambient ionization source (10) is directed toward a selected variable location along the continuous liquid jet (50) to desorb at least a portion of the continuous liquid jet (50). A mass analyzer (30) analyzes a mass-to-charge ratio of an ionized sample that is within the desorbed portion of the continuous liquid jet (50). The acquired mass spectra reflect the reaction progress in different reaction times and, therefore, may be used to derive the reaction rate.
摘要:
An apparatus and method for direct analysis of continuous-flow liquid samples by desorption electrospray ionization-mass spectrometry (DESI-MS) including a sample stage that is adapted to receive a liquid sample and a nebulizing ionizer that is configured to generate a charged, nebulized solvent and thereby desorb at least a portion of the liquid sample from the sample stage.
摘要:
An apparatus and method for direct analysis of continuous-flow liquid samples by desorption electrospray ionization-mass spectrometry (DESI-MS) including a sample stage that is adapted to receive a liquid sample and a nebulizing ionizer that is configured to generate a charged, nebulized solvent and thereby desorb at least a portion of the liquid sample from the sample stage.
摘要:
Devices and methods for mechanism-based feedback controller employed in a wind powered power system are provided. A controller can include a vector control-based voltage source converter with feedback control circuitry. The feedback control circuitry is configured to modulate either a power order or a dc-link voltage order to control coupling between voltage and power. The controller can be connected to a wind-based turbine generator of a wind farm and regulate power deployed to a power grid.
摘要:
Various examples are provided that are related to coupling dynamics for, e.g., power systems with iterative discrete decision making architectures. In one example, a method includes determining an output power adjustment using a frequency difference associated with a generator of a first area of a power system and price signals corresponding to power generation in the first area and in a second area coupled to the first area by a tie-line; and providing a power command based upon the output power adjustment to a control system of the generator. In another example, a power system control system includes first and second agents configured to control power generation of a first area and a second area of a power system, respectively. The second agent can control power generation of the second area using frequency differences of generators in the second area and price signals of the first and second areas.
摘要:
Disclosed are various embodiments that relate to multi-agent decision system based at least in part on a dual's dual problem formulation. The embodiments limited the amount of information exchanged among autonomous entities. The embodiments can incorporate existing AC optimal power flow (OPF) software systems. In one embodiments, a subgradient-based iterative method is used.
摘要:
Various examples are provided extended Kalman filtering estimators for generators. In one example, among others an extended Kalman filtering estimator includes a dynamics estimator configured to calculate an estimated variable such as an estimated dynamic state or an estimated parameter of a generator, a geometry estimator configured to estimate generator values, and a Kalman filter component configured to determine a correction to the estimated state variable.
摘要:
Various examples are provided for feedback control of power systems. The feedback control can provide simultaneous frequency regulation and economic operation of a power system. In one example, a method includes obtaining a frequency difference associated with a generator of a power system; determining an output power adjustment based at least in part upon the frequency difference and a cost function associated with the generator; and providing a power command to a secondary frequency control of the generator, the power command based upon the output power adjustment. In another example, a generator control system includes a primary frequency controller configured to control frequency droop of a generator of a power system; and a secondary frequency controller configured to adjust output power of the generator based at least in part upon a frequency difference associated with the generator and a cost function associated with the generator.