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公开(公告)号：US06197147B1
公开(公告)日：2001-03-06
申请号：US09091659
申请日：1999-04-05
申请人： Harald Bönsel , Joachim Clauss , Gregor Deckers , Georg Frank , Arnold Schneller , Helmut Witteler , Mike Römmler , Michael Heine
发明人： Harald Bönsel , Joachim Clauss , Gregor Deckers , Georg Frank , Arnold Schneller , Helmut Witteler , Mike Römmler , Michael Heine
IPC分类号： B32B3100
CPC分类号： H01M4/926 , C25B9/10 , H01M4/90 , H01M4/92 , H01M8/0213 , H01M8/1004 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , Y02P70/56 , Y10T156/1084
摘要： A process for producing laminates which contain at least one centrally arranged, ion-conductive membrane which is, at least over a substantial part of its two mutually opposite flat faces, electrically conductively bonded to at least one catalytically active substance and to at least one two-dimensional, gas-permeable, electron-conductive contacting material, the bonding of at least two of the said components having been effected by lamination. The process comprises carrying out the bonding of the ion-conductive membrane, of the catalytically active substance and of the electron-conductive contacting material continuously. The ion-conductive membrane is brought together with at least the electron-conductive contacting material in the exact position by means of transport and feeding devices and the two components are laminated and bonded to one another by pressing them together. The range of variation in the a.c. resistances of the laminates produced by the process according to the invention is ±10%. The laminates are particularly suitable for use in fuel cells or electrolysers.
摘要翻译： 一种制备层压体的方法，其包含至少一个中心布置的离子传导膜，其至少在其两个相互相对的平坦表面的至少大部分上与导电键合至至少一种催化活性物质和至少一种二 三维，透气，电子传导的接触材料，至少两个所述组分的结合已通过层压实现。 该方法包括连续地进行催化活性物质和电子传导性接触材料的离子传导膜的接合。 离子传导膜通过输送和进料装置与至少电子传导接触材料在精确位置一起被带到一起，并且两个部件通过将它们压在一起而彼此层压并结合。 a.c.的变化范围。 根据本发明的方法生产的层压体的电阻为±10％。 层压板特别适用于燃料电池或电解槽。
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公开(公告)号：US20050131196A1
公开(公告)日：2005-06-16
申请号：US11036635
申请日：2005-01-14
IPC分类号： B01D71/06 , B01D71/52 , C08G61/12 , C08G65/38 , C08G65/48 , C08G67/00 , C08L71/10 , H01B1/12 , H01M6/18 , H01M8/02 , H01M8/10 , H01M10/40 , C08G8/02
CPC分类号： C08G65/48 , B01D71/52 , C08G61/12 , C08G61/127 , H01M8/1025 , H01M8/1067 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—] (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.
摘要翻译： 式（II）的磺化芳族聚醚酮<？in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-]（II）<？在线公式描述=”在线公式“end =”tail“？>其中从1％至100％的O-亚苯基-CO单元 被SO 3 M基团取代，并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序，基团Ar，Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-，1,3-或1,4-亚苯基环，M考虑到离子价，包括一个或多个选自下列基团的元素：H，NR 4 其中R是H或C 1 -C 4 - 烷基，或碱金属或碱土金属或碱金属或碱土金属 来自亚组8的金属，并且优选为H，NR 4，...，L 2，Na，K，Ca，Mg，Fe或Pt。
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公开(公告)号：US07307138B2
公开(公告)日：2007-12-11
申请号：US11036635
申请日：2005-01-14
CPC分类号： C08G65/48 , B01D71/52 , C08G61/12 , C08G61/127 , H01M8/1025 , H01M8/1067 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—] (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.
摘要翻译： 式（II）的磺化芳族聚醚酮<？in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-]（II）<？在线公式描述=”在线公式“end =”tail“？>其中从1％至100％的O-亚苯基-CO单元 被SO 3 M基团取代，并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序，基团Ar，Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-，1,3-或1,4-亚苯基环，M考虑到离子价，包括一个或多个选自下列基团的元素：H，NR 4 其中R是H或C 1 -C 4 - 烷基，或碱金属或碱土金属或来自亚组8的金属，并且是 优选H，NR 4，...，Li，Na，K，Ca，Mg，Fe或Pt。
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4.发明授权Laser-markable molding compositions, moldings prepared using the same and methods of marking such moldings 有权可激光标记的成型组合物，使用其制备的模制品以及标记这种模制品的方法公开(公告)号：US07771646B2
公开(公告)日：2010-08-10
申请号：US11665550
申请日：2005-10-15
申请人： Joachim Clauss , Kurt Witan , Arnold Schneller , Klaus Kurz
发明人： Joachim Clauss , Kurt Witan , Arnold Schneller , Klaus Kurz
摘要： Laser-markable molding compositions, molding produced therewith and method of marking the same, wherein the molding compositions comprise: (a) at least one semicrystalline thermoplastic; and (b) at least one particulate additive selected from the group consisting of (i) light-sensitive salt compounds, (ii) inorganic oxides having an average particle diameter of less than 250 nm, and combinations thereof; wherein the light-sensitive salt compounds comprise compounds having two or more captions, wherein at least one of the two or more captions is selected from the group consisting of Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ag, Sn, Sb, La, Pr, Ta, W, and Ce; and wherein at least another of the two or more captions is selected from the group consisting of elements of periods 3-6 of main groups II and III, elements of periods 5-6 of main group IV, elements of periods 4-5 of transition groups III-VIII, and the lanthanoids.
摘要翻译： 可激光标记的模制组合物，由其制备的模制品及其标记方法，其中模塑组合物包含：（a）至少一种半结晶热塑性塑料; 和（b）至少一种选自（i）光敏盐化合物，（ii）平均粒径小于250nm的无机氧化物及其组合的颗粒添加剂; 其中所述感光盐化合物包含具有两个或多个阳离子的化合物，其中所述两种或更多种阳离子中的至少一种选自Ti，Cr，Mn，Fe，Co，Ni，Cu，Zn，Y， Zr，Nb，Mo，Ag，Sn，Sb，La，Pr，Ta，W和Ce; 并且其中所述两种或更多种阳离子中的至少另一种选自主要组II和III的周期3-6的元素，主组IV的周期5-6的元素，过渡期4-5的元素 III-VIII族和镧系元素。
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5.发明申请THERMOPLASTIC PARTIALLY CRYSTALLINE MOLDING COMPOUND HAVING A REDUCED SURFACE LUSTER AND PRODUCTS MADE THEREFROM 失效热塑性部分晶体结晶化合物，具有减少的表面LUSTER及其制成的产品公开(公告)号：US20090111932A1
公开(公告)日：2009-04-30
申请号：US12058124
申请日：2008-03-28
CPC分类号： C08L77/02 , C08K3/00 , C08K5/09 , C08L33/00 , C08L33/08 , C08L59/00 , C08L67/02 , C08L77/00 , C08L77/06 , C08L81/02 , C08L2201/00 , C08L2314/00 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to novel molding compositions based on semicrystalline engineering thermoplastics which, in conventional processing techniques, give moldings with reduced surface gloss. A feature of the molding compositions is that they comprise, in a polymer matrix, if appropriate with the usual additives, polymer particles with a median size d50 of from 0.1 μm to 100 μm, and comprise at least one other incompatible or semicompatible polymer which has not been chemically crosslinked, and also, if appropriate, comprise salt-like additives.The invention further relates to moldings which are produced by means of conventional processing techniques, in particular via injection molding, from these matt-effect molding compositions.
摘要翻译： 本发明涉及基于半结晶工程热塑性塑料的新型模塑组合物，其在常规加工技术中赋予具有降低的表面光泽度的模制品。 模塑组合物的特征在于，如果合适的话，它们在聚合物基体中包含常规添加剂，中值粒径d50为0.1〜100μm的聚合物颗粒，并且包含至少一种其它不相容或半不饱和的聚合物，其具有 未经化学交联，并且如果合适，还包含盐状添加剂。 本发明还涉及通过常规加工技术，特别是通过注射成型从这些亚光效应模制组合物生产的模制品。
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6.发明授权Process for preparation of oxymethylene polymers in a homogeneous phase, and use 失效在均相中制备甲醛聚合物的方法，并使用公开(公告)号：US07943726B2
公开(公告)日：2011-05-17
申请号：US11643223
申请日：2006-12-21
IPC分类号： C08G59/00
摘要： A process and an apparatus are described for preparation of oxymethylene polymers. This process encompasses polymerization, in a homogeneous phase, of a monomer which forms oxymethylene groups, as far as 90% of maximum conversion in the presence of an acetal of formaldehyde and of an initiator for cationic polymerization, followed by deactivation of the reaction mixture. The resultant oxymethylene polymers have alkyl ether end groups and are extremely stable.
摘要翻译： 描述了制备甲醛聚合物的方法和装置。 该方法包括在均相中聚合形成甲醛基的单体，在甲醛缩醛和阳离子聚合引发剂的存在下，最大转化率为90％，随后反应混合物失活。 所得的甲醛聚合物具有烷基醚端基并且非常稳定。
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7.发明授权Thermoplastic partially crystalline molding compound having a reduced surface luster and products made therefrom 失效热塑性部分结晶的模塑料具有降低的表面光泽和由其制成的产品公开(公告)号：US07655726B2
公开(公告)日：2010-02-02
申请号：US12058124
申请日：2008-03-28
IPC分类号： C08L51/04
CPC分类号： C08L77/02 , C08K3/00 , C08K5/09 , C08L33/00 , C08L33/08 , C08L59/00 , C08L67/02 , C08L77/00 , C08L77/06 , C08L81/02 , C08L2201/00 , C08L2314/00 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to novel molding compositions based on semicrystalline engineering thermoplastics which, in conventional processing techniques, give moldings with reduced surface gloss. A feature of the molding compositions is that they comprise, in a polymer matrix, if appropriate with the usual additives, polymer particles with a median size d50 of from 0.1 μm to 100 μm, and comprise at least one other incompatible or semicompatible polymer which has not been chemically crosslinked, and also, if appropriate, comprise salt-like additives. The invention further relates to moldings which are produced by means of conventional processing techniques, in particular via injection molding, from these matt-effect molding compositions.
摘要翻译： 本发明涉及基于半结晶工程热塑性塑料的新型模塑组合物，其在常规加工技术中赋予具有降低的表面光泽度的模制品。 模塑组合物的特征在于，如果合适的话，它们在聚合物基体中包含常规添加剂，中值粒径d50为0.1〜100μm的聚合物颗粒，并且包含至少一种其它不相容或半不饱和的聚合物，其具有 未经化学交联，并且如果合适，还包含盐状添加剂。 本发明还涉及通过常规加工技术，特别是通过注射成型从这些亚光效应模制组合物生产的模制品。
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8.发明申请Laser-markable flameproof molding compounds and laser-markable and laser-marked products obtained from said molding compounds 审中-公开可激光标记的防火成型化合物和由所述模塑料获得的可激光标记和激光标记的产品公开(公告)号：US20090048373A1
公开(公告)日：2009-02-19
申请号：US11665549
申请日：2005-10-15
申请人： Joachim Clauss , Hanno Huckstadt , Arnold Schneller , Klaus Kurz
发明人： Joachim Clauss , Hanno Huckstadt , Arnold Schneller , Klaus Kurz
CPC分类号： B41M5/267 , B41M5/28 , C08L101/00 , C08L2666/54
摘要： Novel halogen-free flame-retardant thermoplastic molding compositions are described, and give laser-markable moldings with increased quality of marking. The molding compositions comprise at least one thermoplastic A) and at least one light-sensitive compound of salt type B1) which within the polymer matrix when exposed to laser light changes its color or leads to a change in the color of the polymer matrix, and/or at least one light-sensitive or light-sensitizing oxide B2) which within the polymer matrix when exposed to laser light changes its color or leads to a change in the color of the polymer matrix, and at least one halogen-free compound or mixture C) which has a positive effect on the flammability and fire performance of the molding composition, and if appropriate, other conventional additives D).The invention further relates to moldings produced from these laser-markable flame-retardant molding compositions, and also to laser-marked moldings produced therefrom. A process for laser marking is also disclosed, as is the use of the laser-markable, flame-retardant molding compositions for production of laser-marked moldings.
摘要翻译： 描述了新型无卤阻燃热塑性成型组合物，并且具有提高标记质量的可激光标记模制品。 模塑组合物包含至少一种热塑性A）和至少一种B1型盐的敏感化合物，其在暴露于激光下时在聚合物基质内改变其颜色或导致聚合物基质颜色的变化，以及 /或至少一种光敏或光敏氧化物B2），其在暴露于激光下时在聚合物基质内变化其颜色或导致聚合物基质的颜色变化，以及至少一种不含卤素的化合物或 混合物C），其对成型组合物的可燃性和耐火性能以及其它常规添加剂D）的适当影响。 本发明还涉及由这些可激光标记的阻燃成型组合物制成的模制品，以及由其制成的激光标记的模制品。 还公开了用于激光标记的方法，以及使用可激光标记的阻燃模制组合物来生产激光标记的模制品。
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9.发明申请Process for preparation of oxymethylene polymers, selected polymers, and their use 失效制备甲醛聚合物，选择的聚合物及其用途的方法公开(公告)号：US20070179273A1
公开(公告)日：2007-08-02
申请号：US11643131
申请日：2006-12-21
IPC分类号： C08G65/34
摘要： An apparatus is described for preparation of oxymethylene homo- and copolymers. This encompasses heterogeneous polymerization of a monomer which forms oxymethylene groups in the presence of an acetal of formaldehyde and of an initiator for cationic polymerization, followed by the deactivation of the polymer in a homogeneous phase via treatment with a basic aprotic solvent or with an aprotic solvent which comprises a base. Oxymethylene homopolymers with very high stability are also described.
摘要翻译： 描述了制备甲醛均聚物和共聚物的装置。 这包括在甲醛缩醛和阳离子聚合引发剂存在下形成甲醛基的单体的非均相聚合，然后通过用碱性非质子溶剂或非质子溶剂处理使均相中的聚合物失活 其包括基座。 还描述了具有非常高稳定性的亚甲基均聚物。
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10.发明申请Thermoplastic partially crystalline molding compound having a reduced surface luster and products made therefrom 审中-公开热塑性部分结晶的模塑料具有降低的表面光泽和由其制成的产品公开(公告)号：US20060211806A1
公开(公告)日：2006-09-21
申请号：US10555046
申请日：2004-04-28
IPC分类号： C08G18/42
CPC分类号： C08L77/02 , C08K3/00 , C08K5/09 , C08L33/00 , C08L33/08 , C08L59/00 , C08L67/02 , C08L77/00 , C08L77/06 , C08L81/02 , C08L2201/00 , C08L2314/00 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to novel molding compositions based on semicrystalline engineering thermoplastics which, in conventional processing techniques, give moldings with reduced surface gloss. A feature of the molding compositions is that they comprise, in a polymer matrix, if appropriate with the usual additives, polymer particles with a median size d50 of from 0.1 μm to 100 μm, and comprise at least one other incompatible or semicompatible polymer which has not been chemically crosslinked, and also, if appropriate, comprise salt-like additives. The invention further relates to moldings which are produced by means of conventional processing techniques, in particular via injection molding, from these matt-effect molding compositions.
摘要翻译： 本发明涉及基于半结晶工程热塑性塑料的新型模塑组合物，其在常规加工技术中赋予具有降低的表面光泽度的模制品。 模塑组合物的特征在于，如果合适的话，它们在聚合物基质中包含中等尺寸d <100％至100μm的聚合物颗粒，并且包含至少 还没有化学交联的另一种不相容的或半不兼容的聚合物，如果合适的话也包括盐状添加剂。 本发明还涉及通过常规加工技术，特别是通过注射成型从这些亚光效应模制组合物生产的模制品。
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