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17 条记录 (耗时 0.03 秒)

    Process for continuous production of membrane-electrode composites
    1.
    发明授权
    Process for continuous production of membrane-electrode composites 有权
    连续生产膜 - 电极复合材料的方法

    公开(公告)号：US06197147B1

    公开(公告)日：2001-03-06

    申请号：US09091659

    申请日：1999-04-05

    申请人： Harald Bönsel ,  Joachim Clauss ,  Gregor Deckers ,  Georg Frank ,  Arnold Schneller ,  Helmut Witteler ,  Mike Römmler ,  Michael Heine

    发明人： Harald Bönsel ,  Joachim Clauss ,  Gregor Deckers ,  Georg Frank ,  Arnold Schneller ,  Helmut Witteler ,  Mike Römmler ,  Michael Heine

    IPC分类号： B32B3100

    CPC分类号： H01M4/926 ,  C25B9/10 ,  H01M4/90 ,  H01M4/92 ,  H01M8/0213 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  Y02P70/56 ,  Y10T156/1084

    摘要： A process for producing laminates which contain at least one centrally arranged, ion-conductive membrane which is, at least over a substantial part of its two mutually opposite flat faces, electrically conductively bonded to at least one catalytically active substance and to at least one two-dimensional, gas-permeable, electron-conductive contacting material, the bonding of at least two of the said components having been effected by lamination. The process comprises carrying out the bonding of the ion-conductive membrane, of the catalytically active substance and of the electron-conductive contacting material continuously. The ion-conductive membrane is brought together with at least the electron-conductive contacting material in the exact position by means of transport and feeding devices and the two components are laminated and bonded to one another by pressing them together. The range of variation in the a.c. resistances of the laminates produced by the process according to the invention is ±10%. The laminates are particularly suitable for use in fuel cells or electrolysers.

    摘要翻译： 一种制备层压体的方法，其包含至少一个中心布置的离子传导膜，其至少在其两个相互相对的平坦表面的至少大部分上与导电键合至至少一种催化活性物质和至少一种二 三维，透气，电子传导的接触材料，至少两个所述组分的结合已通过层压实现。 该方法包括连续地进行催化活性物质和电子传导性接触材料的离子传导膜的接合。 离子传导膜通过输送和进料装置与至少电子传导接触材料在精确位置一起被带到一起，并且两个部件通过将它们压在一起而彼此层压并结合。 a.c.的变化范围。 根据本发明的方法生产的层压体的电阻为±10％。 层压板特别适用于燃料电池或电解槽。

    Polymer electrolytes and process for their preparation
    2.
    发明授权
    Polymer electrolytes and process for their preparation 失效
    聚合物电解质及其制备方法

    公开(公告)号：US07307138B2

    公开(公告)日：2007-12-11

    申请号：US11036635

    申请日：2005-01-14

    申请人： Joachim Clauss ,  Gregor Deckers ,  Arnold Schneller ,  Helmut Witteler

    发明人： Joachim Clauss ,  Gregor Deckers ,  Arnold Schneller ,  Helmut Witteler

    IPC分类号： C08G8/02 ,  C08G65/00 ,  C08G65/48

    CPC分类号： C08G65/48 ,  B01D71/52 ,  C08G61/12 ,  C08G61/127 ,  H01M8/1025 ,  H01M8/1067 ,  H01M8/1072 ,  H01M8/1081 ,  Y02P70/56

    摘要： A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—]   (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.

    摘要翻译： 式（II）的磺化芳族聚醚酮<？in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-]（II）<？在线公式描述=”在线公式“end =”tail“？>其中从1％至100％的O-亚苯基-CO单元 被SO 3 M基团取代，并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序，基团Ar，Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-，1,3-或1,4-亚苯基环，M考虑到离子价，包括一个或多个选自下列基团的元素：H，NR 4 其中R是H或C 1 -C 4 - 烷基，或碱金属或碱土金属或来自亚组8的金属，并且是 优选H，NR 4，...，Li，Na，K，Ca，Mg，Fe或Pt。

    Polymer electrolytes and process for their preparation
    3.
    发明申请
    Polymer electrolytes and process for their preparation 失效
    聚合物电解质及其制备方法

    公开(公告)号：US20050131196A1

    公开(公告)日：2005-06-16

    申请号：US11036635

    申请日：2005-01-14

    申请人： Joachim Clauss ,  Gregor Deckers ,  Arnold Schneller ,  Helmut Witteler

    发明人： Joachim Clauss ,  Gregor Deckers ,  Arnold Schneller ,  Helmut Witteler

    IPC分类号： B01D71/06 ,  B01D71/52 ,  C08G61/12 ,  C08G65/38 ,  C08G65/48 ,  C08G67/00 ,  C08L71/10 ,  H01B1/12 ,  H01M6/18 ,  H01M8/02 ,  H01M8/10 ,  H01M10/40 ,  C08G8/02

    CPC分类号： C08G65/48 ,  B01D71/52 ,  C08G61/12 ,  C08G61/127 ,  H01M8/1025 ,  H01M8/1067 ,  H01M8/1072 ,  H01M8/1081 ,  Y02P70/56

    摘要： A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—]  (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.

    摘要翻译： 式（II）的磺化芳族聚醚酮<？in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-]（II）<？在线公式描述=”在线公式“end =”tail“？>其中从1％至100％的O-亚苯基-CO单元 被SO 3 M基团取代，并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序，基团Ar，Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-，1,3-或1,4-亚苯基环，M考虑到离子价，包括一个或多个选自下列基团的元素：H，NR 4 其中R是H或C 1 -C 4 - 烷基，或碱金属或碱土金属或碱金属或碱土金属 来自亚组8的金属，并且优选为H，NR 4，...，L 2，Na，K，Ca，Mg，Fe或Pt。

    Polybetaine stabilized platinum nanoparticles, method for the production thereof and utilization for fuel-cell catalysts
    6.
    发明授权
    Polybetaine stabilized platinum nanoparticles, method for the production thereof and utilization for fuel-cell catalysts 失效
    聚甜菜碱稳定的铂纳米粒子，其生产方法和燃料电池催化剂的利用

    公开(公告)号：US06391818B1

    公开(公告)日：2002-05-21

    申请号：US09555980

    申请日：2000-08-31

    申请人： Harald Bönsel ,  Gregor Deckers ,  Georg Frank ,  Hans Millauer ,  Thomas Soczka-Guth

    发明人： Harald Bönsel ,  Gregor Deckers ,  Georg Frank ,  Hans Millauer ,  Thomas Soczka-Guth

    IPC分类号： B01J3106

    CPC分类号： C25C5/02 ,  B01J35/0013 ,  B82Y30/00 ,  H01M4/92 ,  H01M4/926 ,  H01M2300/0082

    摘要： Polybetaine-stabilized nanosize platinum particles, a process for preparing them and their use for electrocatalysts in fuel cells Soluble nanosize particles which have a diameter of from 0.5 to 3 nm, preferably from 1 to 2 nm, comprise platinum alone or platinum and other metals of the platinum group and are embedded in a protective colloid which comprises polymeric betaines and can be degraded by hydrolysis. The betaine is preferably a carbobetaine of the formula —N+R1R2—(—CH2—)n—CO2−, a phosphobetaine of the formula —N+R1R2—(—CH2—)n—PO3— or, preferably, a sulfobetaine of the formula —N+R1R2—(—CH2—)n—SO3—, where R1 and R2 may, independently of one another, be identical or different and are alkyl radicals having from 1 to 6 carbon atoms and n is 1, 2 or 3. Also described are a process for preparing the nanosize particles and catalysts produced therefrom and also their use for fuel cells.

    摘要翻译： 聚甜菜碱稳定的纳米尺寸铂颗粒，其制备方法及其在燃料电池中的电催化剂的用途直径为0.5至3nm，优选1至2nm的可溶性纳米尺寸颗粒包含单独的铂或铂和其它金属 铂基团，并且嵌入包含聚合甜菜碱的保护胶体中，并且可以通过水解而降解。 甜菜碱优选为式-N + R1R2 - （ - CH2-）n-CO2-，式-N + R1R2 - （ - CH2-）n-PO3-的磷酸甜菜碱的碳甜蛋白，或优选为 式-N + R1R2 - （ - CH2-）n-SO3-，其中R1和R2可以彼此独立地相同或不同，并且是具有1至6个碳原子的烷基，n是1,2或 还描述了制备纳米尺寸颗粒和由其制备的催化剂的方法，以及它们在燃料电池中的用途。

    Hydrogenation catalyst, a process for its preparation, and use thereof
    8.
    发明授权
    Hydrogenation catalyst, a process for its preparation, and use thereof 失效
    氢化催化剂，其制备方法及其用途

    公开(公告)号：US5498587A

    公开(公告)日：1996-03-12

    申请号：US217151

    申请日：1994-03-24

    申请人： Gregor Deckers ,  Gerhard Diekhaus ,  Bernd Dorsch ,  Carl D. Frohning ,  Gerhardt Horn ,  Horst B. Horrig

    发明人： Gregor Deckers ,  Gerhard Diekhaus ,  Bernd Dorsch ,  Carl D. Frohning ,  Gerhardt Horn ,  Horst B. Horrig

    IPC分类号： B01J21/16 ,  B01J23/755 ,  B01J23/78 ,  B01J32/00 ,  B01J35/10 ,  B01J37/18 ,  C07B61/00 ,  C07C29/141 ,  C07C31/10 ,  C07C31/12 ,  C09K3/00 ,  B01J21/10 ,  B01J23/04

    CPC分类号： B01J35/10 ,  B01J23/755 ,  B01J23/78 ,  C07C29/141 ,  C07C31/10 ,  C07C31/12 ,  B01J35/0053 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/108

    摘要： A hydrogenation catalyst comprising 25 to 50% by weight of nickel (metallic) 10 to 35% by weight of nickel oxide 4 to 12% by weight of magnesium oxide 1 to 5% by weight of sodium oxide the remainder being a water-insoluble support material,wherein the total of nickel and nickel oxide is 40% to 70% by weight, and the catalyst has a surface area, determined by BET, of 80 to 200 m.sup.2 /g and a total pore volume of 0.35 to 0.6 ml/g. The total pore volume is made up of 30% to 60% by volume from pores having pore radii of .ltoreq.40 .ANG., 4% to 10% by volume from pores having pore radii of >40 to 300 .ANG., and 30% to 60% by volume from pores having pore radii of >300 to 5000 .ANG..A process for preparing the hydrogenation catalyst which comprises preparing, in a precipitation step, a green catalyst from a nickel salt, a magnesium salt, sodium carbonate, and the support material, separating off the mother liquor and partially washing the precipitate, slurrying the green catalyst in alkali solution, separating it from the liquid phase, drying it, and contacting the dried green catalyst with hydrogen until 48% to 86% by weight of the total nickel content is present in metallic form.The hydrogenation catalyst of the invention is particularly suitable for the hydrogenation of propanal, n-butanal, and i-butanal, especially at temperatures between 100.degree. and 160.degree. C.

    摘要翻译： 一种氢化催化剂，其包含25-50％重量的镍（金属），10-35％（重量）的氧化镍，4至12％（重量）的氧化镁，1至5％（重量）的氧化钠，其余为不溶于水的载体 材料，其中镍和氧化镍的总量为40重量％至70重量％，并且催化剂具有由BET测定的表面积为80至200m 2 / g，总孔体积为0.35至0.6ml / g 。 总孔体积由孔径为40μm〜40μm的孔径为4〜10体积％的孔径为30〜60体积％，孔径为40〜300埃的孔径为30〜 60％体积的孔径为> 300至5000的孔。 一种制备氢化催化剂的方法，包括在沉淀步骤中，从镍盐，镁盐，碳酸钠和载体材料中制备绿色催化剂，分离母液并部分洗涤沉淀物，将绿色 碱性溶液中的催化剂，将其与液相分离，干燥，并将干燥的生坯催化剂与氢气接触，直到总镍含量的48重量％至86重量％以金属形式存在。 本发明的氢化催化剂特别适用于丙醛，正丁醛和异丁醛的加氢，特别是在100至160℃的温度下。