摘要:
A process for producing laminates which contain at least one centrally arranged, ion-conductive membrane which is, at least over a substantial part of its two mutually opposite flat faces, electrically conductively bonded to at least one catalytically active substance and to at least one two-dimensional, gas-permeable, electron-conductive contacting material, the bonding of at least two of the said components having been effected by lamination. The process comprises carrying out the bonding of the ion-conductive membrane, of the catalytically active substance and of the electron-conductive contacting material continuously. The ion-conductive membrane is brought together with at least the electron-conductive contacting material in the exact position by means of transport and feeding devices and the two components are laminated and bonded to one another by pressing them together. The range of variation in the a.c. resistances of the laminates produced by the process according to the invention is ±10%. The laminates are particularly suitable for use in fuel cells or electrolysers.
摘要:
Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要:
Process for producing hollow bodies comprising fibre-reinforced ceramic materials, where cores whose shape corresponds to that of the hollow spaces are produced in a first step, a green body is produced in a second step by introducing the abovementioned cores and a press moulding compound into a mould, where the press moulding compound comprises carbon fibres and/or carbon threads and pitch and/or resins, the green body is cured in a third step by heating under pressure, and then carbonised in a fourth step by heating in the absence of oxidants to form a C/C body, which latter can be infiltrated with liquid metal with retention of its shape in a fifth step, with at least partial formation of carbides, where the cores comprise a material which is non-meltable but undergoes at least sufficient shrinkage above the curing temperature of the shaping by pressing of the press moulding compound for the shrunken core to be able to be taken out from the carbonised body; hollow bodies produced by this process and also their use as brake disks, clutch disks and friction disks
摘要:
Process for producing shaped bodies comprising fiber-reinforced ceramic materials, where a green body is produced in a first step by introducing a press moulding composition into a mold, where the press moulding composition comprises carbon fibers and/or carbon filaments and pitch and/or resins which, when treated thermally and with the exclusion of oxidizing agents, form carbon-containing residues, the green body is cured in a second step by heating to a temperature of from 120° C. to 280° C. under pressure, the cured green body, also referred to as intermediate body, is carbonized in a third step by heating in a nonoxidizing atmosphere to a temperature of from about 750° C. to about 1100° C. to form a C/C body, wherein heating in the first, second and/or third step is at least partly effected by an electric current being passed through the pressable composition, the green body and/or the cured green body, shaped bodies produced according to this process and their use as brake disks, clutch disks and friction disks
摘要:
A friction disc, in particular a brake or clutch disc, includes carbon fiber-reinforced ceramic composite material with at least one top surface formed as a friction surface. At least part of the friction surface is formed of a different material, in particular of a carbon-containing material. The different material exhibits lower wear and oxidation resistance than that of the rest of the friction surface and a supporting zone of the friction disc. A visual, audible or mechanical signal is produced under operating conditions due to comparatively greater wear. The signal provides a warning that the service life of the friction disc is being exceeded. A process for producing the friction disc is also provided.
摘要:
A method is provided for producing a fiber-reinforced material which is composed, at least in a region of a surface layer, of a ceramic composite and has carbon-containing fibers reaction-bonded to a matrix containing the elements Si and C. In particular a method of producing fiber-reinforced silicon carbide is provided in which a structure of a matrix contains cracks and/or pores, at least at ambient temperature, because of a high thermal expansion coefficient compared with that of the fibers. Metals are selectively electrodeposited in the open pores and cracks of the matrix and, in particular, in a region of the electrically conductive reinforcing fibers. As a result, the open pores and cracks are filled and, in addition, metallic top layers are optionally formed that are firmly keyed to the ceramic composite and that may serve as an interlayer for glass top layers or ceramic top layers. A fiber-reinforced composite material, as well as moldings, in particular brake discs, brake linings or clutch plates, composed of such a composite material, are also provided.
摘要:
A friction or sliding body includes at least two composite materials reinforced with fiber bundles and containing a ceramics matrix. A first composite material forms the outside of the sliding body as a friction layer and a second composite material forms a supporting body joined areally to the friction layer. The fiber bundle lengths of the friction layer are significantly shorter than the fiber bundle lengths of the supporting body. The fiber bundles of the friction layer have a clear alignment perpendicular to the surface. The surface of the friction layer is formed substantially only of small regions of free carbon with a diameter of at most 1.2 mm, and a total fraction of the area of free carbon on the surface is at most 35%. The surface has an extremely fine crack structure and the friction layer exhibits virtually no stresses in the vicinity of the surface. A process for producing a friction or sliding body and a brake disc or brake lining are also provided.
摘要:
Protection products and armored products made of a fiber-reinforced composite material with a ceramic matrix, include a protection element for partial or complete absorption of at least one impact-like load focussed at a point. The protection element has a body having at least one dimension at least equal to 3 cm, in a direction perpendicular to a load to be absorbed. The body includes a fiber-reinforced composite material having a ceramic matrix with at least 10% by weight of silicon carbide and having reinforcing fibers. At least 5% by weight of the reinforcing fibers are carbon fibers and/or graphite fibers.
摘要:
Porous carbon fibers, whose active centers are formed by pores that are filled at least in part by carbon and/or metal and/or metal carbide, obtainable by carbonization of organic or inorganic polymers, the use thereof for the adsorption or separation of gaseous substances, in particular of CO2, and also a method for the production thereof. First, a spinning mixture containing polyacrylonitrile-based polymer A and an organic or metallo-organic polymer B is produced. Next, the spinning mixture is spun to form mixed fibers of polymer A and polymer B. The mixed fiber is stabilized by oxidation. This is followed by carbonization or graphitization of the mixed fiber under non-oxidizing conditions in such a way that the polymer B forms a carbon and/or metal and/or metal carbide residue of at least 22 wt %, the residue forming active centers.
摘要:
The invention relates to the detection of oxidation of carbon-containing fibers or fiber bundles embedded in a nonconductive or semiconducting ceramic matrix in composites wherein use is made of the eddy current method.