Process for continuous production of membrane-electrode composites
    1.
    发明授权
    Process for continuous production of membrane-electrode composites 有权
    连续生产膜 - 电极复合材料的方法

    公开(公告)号:US06197147B1

    公开(公告)日:2001-03-06

    申请号:US09091659

    申请日:1999-04-05

    IPC分类号: B32B3100

    摘要: A process for producing laminates which contain at least one centrally arranged, ion-conductive membrane which is, at least over a substantial part of its two mutually opposite flat faces, electrically conductively bonded to at least one catalytically active substance and to at least one two-dimensional, gas-permeable, electron-conductive contacting material, the bonding of at least two of the said components having been effected by lamination. The process comprises carrying out the bonding of the ion-conductive membrane, of the catalytically active substance and of the electron-conductive contacting material continuously. The ion-conductive membrane is brought together with at least the electron-conductive contacting material in the exact position by means of transport and feeding devices and the two components are laminated and bonded to one another by pressing them together. The range of variation in the a.c. resistances of the laminates produced by the process according to the invention is ±10%. The laminates are particularly suitable for use in fuel cells or electrolysers.

    摘要翻译: 一种制备层压体的方法,其包含至少一个中心布置的离子传导膜,其至少在其两个相互相对的平坦表面的至少大部分上与导电键合至至少一种催化活性物质和至少一种二 三维,透气,电子传导的接触材料,至少两个所述组分的结合已通过层压实现。 该方法包括连续地进行催化活性物质和电子传导性接触材料的离子传导膜的接合。 离子传导膜通过输送和进料装置与至少电子传导接触材料在精确位置一起被带到一起,并且两个部件通过将它们压在一起而彼此层压并结合。 a.c.的变化范围。 根据本发明的方法生产的层压体的电阻为±10%。 层压板特别适用于燃料电池或电解槽。

    Polymer electrolytes and process for their preparation
    2.
    发明申请
    Polymer electrolytes and process for their preparation 失效
    聚合物电解质及其制备方法

    公开(公告)号:US20050131196A1

    公开(公告)日:2005-06-16

    申请号:US11036635

    申请日:2005-01-14

    摘要: A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—]  (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.

    摘要翻译: 式(II)的磺化芳族聚醚酮<?in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-](II)<?在线公式描述=”在线公式“end =”tail“?>其中从1%至100%的O-亚苯基-CO单元 被SO 3 M基团取代,并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序,基团Ar,Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-,1,3-或1,4-亚苯基环,M考虑到离子价,包括一个或多个选自下列基团的元素:H,NR 4 其中R是H或C 1 -C 4 - 烷基,或碱金属或碱土金属或碱金属或碱土金属 来自亚组8的金属,并且优选为H,NR 4,...,L 2,Na,K,Ca,Mg,Fe或Pt。

    Polymer electrolytes and process for their preparation
    3.
    发明授权
    Polymer electrolytes and process for their preparation 失效
    聚合物电解质及其制备方法

    公开(公告)号:US07307138B2

    公开(公告)日:2007-12-11

    申请号:US11036635

    申请日:2005-01-14

    IPC分类号: C08G8/02 C08G65/00 C08G65/48

    摘要: A sulfonated aromatic polyether ketone of the formula (II) [Ar—O—Ar′—CO—Ar′—O—Ar—CO—Ar″—CO—]   (II) in which from 1% to 100% of the O-phenylene-CO units are substituted with an SO3M group and sulfonated and unsulfonated O-phenylene-CO units can be in any desired sequence with respect to one another, the radicals Ar, Ar′ and Ar″ independently of one another are substituted or unsubstituted 1,2-, 1,3- or 1,4-phenylene rings, and M, taking into account the ionic valencies, comprises one or more elements selected from the following group: H, NR4+, where R is H or C1-C4-alkyl, or an alkali metal or alkaline earth metal or a metal from subgroup 8, and is preferably H, NR4+, Li, Na, K, Ca, Mg, Fe or Pt.

    摘要翻译: 式(II)的磺化芳族聚醚酮<?in-line-formula description =“In-line Formulas”end =“lead”→[Ar-O-Ar'-CO-Ar'-O-Ar- CO-Ar“ - CO-](II)<?在线公式描述=”在线公式“end =”tail“?>其中从1%至100%的O-亚苯基-CO单元 被SO 3 M基团取代,并且磺化和未磺化的O-亚苯基-CO单元可以相对于彼此以任何所需的顺序,基团Ar,Ar'和Ar“独立地为一个 另一个是取代或未取代的1,2-,1,3-或1,4-亚苯基环,M考虑到离子价,包括一个或多个选自下列基团的元素:H,NR 4 其中R是H或C 1 -C 4 - 烷基,或碱金属或碱土金属或来自亚组8的金属,并且是 优选H,NR 4,...,Li,Na,K,Ca,Mg,Fe或Pt。

    Process for producing a cation-exchanging polymer electrolyte membrane (PEM)
    6.
    发明授权
    Process for producing a cation-exchanging polymer electrolyte membrane (PEM) 失效
    阳离子交换聚合物电解质膜(PEM)的制造方法

    公开(公告)号:US06214891B1

    公开(公告)日:2001-04-10

    申请号:US09171756

    申请日:1998-12-22

    IPC分类号: C08J520

    摘要: A method for preparing a cation exchange membrane, comprising the introduction of an organic polymer having sulfonic acid groups and of finely disperse electrically conductive particles of a catalyst material into a liquid phase, the resulting suspension being used to coat a foil of a cation exchange material on at least one side, wherein the organic polymer having sulfonic acid groups is soluble in an aprotic polar solvent and contains units of the formulae (Ar1X) and (Ar2Y) which are at least partially substituted by sulfonic acid groups, Ar1 and Ar2 being identical or different bivalent arylene radicals, X being oxygen or sulfur and Y being a carbonyl radical, sulfoxide radical or sulfonyl radical and said material being dissolved in a solvent, a finely disperse electrically conductive catalyst material being suspended in the solution and this suspension being used to coat a foil which contains a polymeric cation exchanger having sulfonic acid groups and the coating which still contains solvent being treated with a liquid which is miscible with the solvent, but in which the dissolved cation exchange material is insoluble, so that pores are formed in the top layer of the membrane.

    摘要翻译: 一种制备阳离子交换膜的方法,包括引入具有磺酸基的有机聚合物和将催化剂材料的导电颗粒细分散到液相中,所得悬浮液用于涂覆阳离子交换材料的箔 在至少一面上,其中具有磺酸基的有机聚合物可溶于非质子极性溶剂,并且含有至少部分被磺酸基取代的式(Ar1X)和(Ar2Y)单元,Ar1和Ar2相同 或不同的二价亚芳基,X为氧或硫,Y为羰基,亚砜基或磺酰基,所述物质溶于溶剂中,将细分散的导电催化剂材料悬浮于溶液中,该悬浮液用于 涂覆含有具有磺酸基团的聚合物阳离子交换剂的箔,并且涂层仍然含有 溶剂用可与溶剂混溶的液体处理,但其中溶解的阳离子交换材料不溶,使得在膜的顶层中形成孔。

    Polymer electrolytes and process for their production
    7.
    发明授权
    Polymer electrolytes and process for their production 失效
    聚合物电解质及其生产工艺

    公开(公告)号:US6096856A

    公开(公告)日:2000-08-01

    申请号:US983626

    申请日:1998-06-24

    摘要: The invention relates to a process for the chlorosulfonation of polyarylene sulfide in which the polyarylene sulfide is completely dissolved in chlorosulfonic acid at a temperature of -10 to +20 C., then agitated at reaction temperatures in the +5 to +20 C. range for a reaction time of 180 min at the most, possibly with the addition of oleum or acetic anhydride and the precipitated in an aqueous medium. The polyarylene sulfide is preferably poly-p-phenylene sulfide. The invention also relates to chlorosulfonated polyarylene sulfide produced by this process, which dissolves in a quantity of 10 to 50 wt % in N-methyl pyrrolidone and has a mean molecular weight Mw of >50,000 g/mol. Finally, the invention also relates to the use of chlorosulfonated polyarylene sulfide for the production of molding, foils, fibres or diaphragms with a proton conductivity in the 2 to 200 mS/cm range.

    摘要翻译: PCT No.PCT / EP96 / 03118 Sec。 371日期:1998年6月24日 102(e)1998年6月24日PCT 1996年7月16日PCT公布。 出版物WO97 / 05191 日期:1997年02月13日本发明涉及聚芳硫醚的氯磺化方法,其中聚芳硫醚在-10〜+ 20℃的温度下完全溶解在氯磺酸中,然后在+5〜 + 20℃,反应时间最多为180分钟,可能加入发烟硫酸或乙酸酐,并在水性介质中沉淀。 聚芳硫醚优选为聚对苯硫醚。 本发明还涉及通过该方法制备的氯磺化聚芳硫醚,其在N-甲基吡咯烷酮中的溶解量为10〜50重量%,平均分子量Mw> 50,000g / mol。 最后,本发明还涉及氯磺化聚芳硫醚用于生产质子传导率在2至200mS / cm范围内的模制品,箔,纤维或隔膜的用途。