摘要:
Preparation of mixtures of O-phenoxyalkylhydroxylamines Ia and Ib ##STR1## and the corresponding salt mixtures by a) converting mixtures of isomers of O-(2-hydroxyethyl)oximes IIa and IIb ##STR2## with a sulfonyl halide III ##STR3## into a mixture of sulfonates IVa and IVb ##STR4## b) reacting this mixture of IVa and IVb with a phenol HO-Ar (V) to give a mixture of O-phenoxyalkoximes VIa and VIb ##STR5## c) hydrolyzing this mixture in the presence of an acid and, if desired d) liberating the O-phenoxyalkylhydroxylamines Ia and Ib from the resulting salts using a mineral acid. Compounds Ia/Ib and VIa/VIb are important intermediates for crop protection agents.
摘要:
Hydroxylamine ethers I ##STR1## (where X is NO.sub.2, CN, halogen, alkyl or haloalkyl, Y is H, NO.sub.2, CN, halogen, alkyl or haloalkyl, n is 0-2 or 1-4 where Y and all radicals X are halogen and Alk is unsubstituted or substituted alkylene) and their salts with mineral acids or strong organic acids are prepared by reacting either a hydroximino compound II ##STR2## (where R.sup.1 is alkyl, R.sup.2 is alkyl or alkoxy or R.sup.1 +R.sup.2 form an alkylene chain) in the presence of an alkali metal hydroxide, alkali metal alcoholate, alkali metal bicarbonate or alkali metal carbonate as the base, or the corresponding anion II directly, with an alkylating agent III ##STR3## (where R.sup.3 is unsubstituted or substituted alkyl or unsubstituted or substituted phenyl) to give an oximino derivative IV ##STR4## said derivative is cleaved by means of a mineral acid or a strong organic acid to give the salt of I and, if desired, the latter is converted by means of a base into the free compound I. The hydroxylamine ethers I are intermediates for crop protection agents and drugs.
摘要:
Biphenylamides of the general formula I ##STR1## and their salts (A= ##STR2## R.sup.1 =F; R.sup.2 =H, halogen, alkyl, CF.sub.3, alkoxy, alkylthio; R.sup.3 =Cl, CF.sub.3 ; R.sup.4 =H, CH.sub.3 ; R.sup.5 =Cl, CH.sub.3, CHF.sub.2, CF.sub.3 ;R.sup.6 =CH.sub.3, CHF.sub.2, CF.sub.3), and compositions comprising I, the preparation of I and of the compositions, and of the use of both of them for controlling harmful fungi.
摘要:
Preparation of O-(2-hydroxyalkyl)oximes I ##STR1## (R.sup.1 and R.sup.2 =alkyl or R.sup.1 and R.sup.2 and the C atom which carries them=5- to 7-membered cycloalkyl), by catalytically hydrogenating an O-(2,3-epoxyalkyl)oxime of the general formula II ##STR2## using hydrogen. The products I are suitable as intermediates for herbicides.
摘要:
The use of nicotinic anilide derivatives of the general formula ##STR1## where the substituents have the following meanings: R.sup.1 halogen, methyl, trifluoromethyl, methoxy, methylthio, methylsulfinyl, methylsulfonylR.sup.2 unsubstituted or halogen-substituted alkyl, unsubstituted or halogen-substituted alkenyl, alkynyl, unsubstituted or halogen-substituted alkoxy, unsubstituted or halogen-substituted alkenyloxy, alkynyloxy, cycloalkyl, cycloalkenyl, cycloalkyloxy, cycloalkenyloxyfor combating Botrytis, and nicotinic anilides of the formula I.
摘要:
Unsaturated cyclohexenone oxime ethers I ##STR1## (Q=H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.ident.C-- or --CH=CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 -X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- andR.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译:不饱和环己烯酮肟醚I(Q = H,烷基羰基,苯甲酰基,碱金属或碱土金属离子,取代或未取代的铵离子,鏻离子,锍离子,氧锍离子,当量的过渡金属阳离子; W = -C = C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基,环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基,吡啶基或R9-X取代的 具有X = O,S,-SO - , - SO 2 - 和R 9 =烷基的苯基,具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H,烷基; R 4 = H,卤素 ,烷基; R5 = H,烷基或R3 + R4,R3 + R5或R4 + R5一起形成C 2 -C 4 - 亚烷基或C 2 -C 4 - 亚烯基; R 6 = H,烷基,未取代的或ph 烯基,烷氧基烷基,烷硫基烷基,取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基)适合作为除草剂。
摘要:
Abstract of the Disclosure: .alpha.-Arylacrylic acid derivatives of the general formula I ##STR1## where X is ethylene or ethenylene;Y is a direct bond or oxygen;R.sup.1 is an unsubstituted or substituted mononuclear or dinuclear aromatic or heteroaromatic system;R.sup.2 is cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio;n is 1 or 2, and the radicals may be different if n is 2, and(c m is 0, 1 or 2, and the radicals may be different if m is 2,with the proviso that R.sup.1 is not phenyl when n is 1 and m is 0, their preparation, insecticides and fungicides containing them and methods for their use.
摘要翻译:公开的摘要:通式Ⅰ的α-丙烯酸衍生物(I)其中X是亚乙基或亚乙烯基; Y是直接键或氧; R1是未取代或取代的单核或双核芳族或杂芳族体系; R 2是氰基,硝基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基或卤代烷硫基; n为1或2,如果n为2,则基团可以不同,(cm为0,1或2,如果m为2,则基团可以不同,条件是当n为1时R1不为苯基) m为0,其制备方法,含有杀虫剂和杀真菌剂及其使用方法。
摘要:
Unsaturated cyclohexenone oxime ethers I ##STR1## (Q.dbd.H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.tbd.C-- or --CH.dbd.CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 -X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- and R.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译:不饱和环己烯酮肟醚I(Q = H,烷基羰基,苯甲酰基,碱金属或碱土金属离子,取代或未取代的铵离子,鏻离子,锍离子,氧锍离子,当量的过渡金属阳离子; W = -C 3BOND C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基,环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基,吡啶基或R9-X取代的 具有X = O,S,-SO - , - SO 2 - 和R 9 =烷基的苯基,具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H,烷基; R 4 = H,卤素 ,烷基; R 5 = H,烷基或R 3 + R 4,R 3 + R 5或R 4 + R 5一起形成C 2 -C 4亚烷基或C 2 -C 4亚烯基; R 6 = H, 或苯基取代的卤代烷基,烯基,烷氧基烷基,烷硫基烷基,取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基)适合作为除草剂。
摘要:
.alpha.-arylacrylic acid derivatives of the general formula I ##STR1## where X is ethylene or ethenylene; Y is a direct bond or oxygen;R.sup.1 is a mononuclear or dinuclear aromatic system substituted by C.sub.1 -C.sub.4 -alkyl, their preparation, insecticides and fungicides containing them and methods for their use.
摘要:
Unsaturated cyclohexenone oxime ethers I ##STR1## (Q=H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.tbd.C-- or --CH.dbd.CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 --X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- andR.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译:不饱和环己烯酮肟醚I(Q = H,烷基羰基,苯甲酰基,碱金属或碱土金属离子,取代或未取代的铵离子,鏻离子,锍离子,氧锍离子,当量的过渡金属阳离子; W = -C 3BOND C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基,环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基,吡啶基或R9-X取代的 具有X = O,S,-SO - , - SO 2 - 和R 9 =烷基的苯基,具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H,烷基; R 4 = H,卤素 ,烷基; R 5 = H,烷基或R 3 + R 4,R 3 + R 5或R 4 + R 5一起形成C 2 -C 4亚烷基或C 2 -C 4亚烯基; R 6 = H, 或苯基取代的卤代烷基,烯基,烷氧基烷基,烷硫基烷基,取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基)适合作为除草剂。