Coal liquefaction process using low grade crude oil
    1.
    发明授权
    Coal liquefaction process using low grade crude oil 失效
    采用低档原油的煤液化工艺

    公开(公告)号:US4541916A

    公开(公告)日:1985-09-17

    申请号:US662357

    申请日:1984-10-18

    IPC分类号: C10G1/04 C10G1/00 C10G47/00

    CPC分类号: C10G1/042

    摘要: A process for converting coal to liquid hydrocarbonaceous products involving a liquefaction reaction in the presence of a coal derived recycle slurry and a non-coal derived solvent comprising a hydrocarbonaceous oil or distillation bottom residue thereof intrinsically contaminated with greater than 300 ppm total of vanadium and nickel. The liquefaction reaction is performed under hydrogen pressure (approximately 500-4000 psi) and under elevated temperature (approximately 300.degree.-500.degree. C.) using a weight ratio of non-coal derived solvent to coal of about 1/1 or less. The conversion of coal to liquids is greatly enhanced by the use of such a non-coal derived solvent under these conditions.

    摘要翻译: 在煤衍生的再循环浆料和非煤衍生的溶剂的存在下,将煤转化为液化烃产物的方法,该方法包括含烃油或蒸馏塔底残余物,其本身被大于总共含有的钒和镍总量的300ppm污染 。 液化反应在氢气压力(约500-4000psi)和升高的温度(约300-500℃)下进行,使用非煤衍生的溶剂与煤的重量比约为1/1以下。 在这些条件下,通过使用这种非煤衍生的溶剂,大大提高了煤到液体的转化。

    Nitrogen oxide reduction system
    5.
    发明授权
    Nitrogen oxide reduction system 失效
    氮氧化物还原系统

    公开(公告)号:US3972831A

    公开(公告)日:1976-08-03

    申请号:US409263

    申请日:1973-10-24

    IPC分类号: B01D53/92 B01J23/46 B01J21/02

    CPC分类号: B01D53/927 B01J23/462

    摘要: A system is proposed for the purification of exhaust gases from internal combustion engines, preferably the reduction of nitrogen oxides in exhaust gases from internal combustion engines in which nitrogen is selectively formed as substantially the only nitrogen-containing product. The exhaust gas is contacted at an elevated temperature with a noble metal in a reducing atmosphere, wherein nitrogen oxides are selectively converted to nitrogen as substantially the only nitrogen containing product, and/or is contacted with a noble metal in an oxidizing atmosphere, wherein carbon monoxide and unburned hydrocarbons are converted to carbon dioxide and water, said noble metal being distended on a microporous glass body. In a preferred embodiment the exhaust gas is contacted at an elevated temperature in a reducing atmosphere with ruthenium supported on a microporous glass body comprising a leached, phase-separated alkali borosilicate.

    摘要翻译: 提出了一种用于净化来自内燃机的废气的系统,优选地将来自内部选择性地形成氮的内燃机的废气中的氮氧化物还原为基本上唯一的含氮产物。 废气在升高的温度下与还原气氛中的贵金属接触,其中氮氧化物选择性地转化为氮气,基本上仅含有氮的产物,和/或在氧化气氛中与贵金属接触,其中碳 一氧化碳和未燃碳氢化合物被转化为二氧化碳和水,所述贵金属膨胀在微孔玻璃体上。 在优选的实施方案中,废气在还原气氛中在升高的温度下与负载在包含沥滤的相分离的碱金属硼硅酸盐的微孔玻璃体上的钌接触。

    Catalyst for conversion of synthesis gas to diesel fuel and process for
preparation of such catalyst
    6.
    发明授权
    Catalyst for conversion of synthesis gas to diesel fuel and process for preparation of such catalyst 失效
    将合成气转化为柴油的催化剂及其制备方法

    公开(公告)号:US4717702A

    公开(公告)日:1988-01-05

    申请号:US876458

    申请日:1986-06-20

    摘要: A catalyst for the conversion of synthesis gas comprising cobalt on a high surface area, high purity, low acidity alumina support of gamma-alumina, eta-alumina or mixtures thereof, whereby the catalyst is prepared by (A) impregnation of the alumina support with a non-aqueous, organic solvent impregnation solution of cobalt nitrate containing sufficient amounts of a Group IIIB or IVB metal salt to provide said catalyst with from about 0.05 to about 100 parts by weight of a Group IIIB or IVB metal oxide per 100 parts by weight cobalt, (B) reduction of the impregnated alumina support by heating, in the presence of hydrogen, at a heating rate of from about 0.5.degree. to about 5.degree. C. per minute to a maximum temperature in the range of 180.degree. to about 220.degree. C. for a hold time of 6 to about 24 hours and thereafter heating the impregnated alumina support in the presence of hydrogen while heating up to a maximum hold temperature of from about 250.degree. to about 400.degree. C. for a hold time of 6 to about 65 hours.

    摘要翻译: 用于在高表面积上转化包含钴的合成气的催化剂,γ-氧化铝,η-氧化铝或其混合物的高纯度,低酸度氧化铝载体,由此通过(A)将氧化铝载体浸渍 含有足够量的IIIB或IVB族金属盐的硝酸钴的非水性有机溶剂浸渍溶液,以使所述催化剂每100重量份提供约0.05至约100重量份的IIIB或IVB族金属氧化物 钴,(B)在氢存在下,以每分钟约0.5℃至约5℃的加热速率加热浸渍的氧化铝载体的还原,至180℃至约220℃的最高温度 保持时间为6至约24小时,然后在氢气存在下加热浸渍的氧化铝载体,同时加热至约250℃至约400℃的最大保持温度,保持时间为6 t 约65小时。

    Process for conversion of naphtha to ethylene
    9.
    发明授权
    Process for conversion of naphtha to ethylene 失效
    石脑油转化为乙烯的方法

    公开(公告)号:US4179474A

    公开(公告)日:1979-12-18

    申请号:US863404

    申请日:1977-12-22

    IPC分类号: C10G65/12 C07C5/04

    摘要: A catalytically hydrogenated naphtha stream containing less than 10 ppm by weight of sulfur is pyrolyzed without added hydrogen to a product including ethylene. Selectivity to ethylene is increased by adding a sulfur compound to increase the sulfur content to above 20 ppm by weight based on hydrogenated naphtha. Addition of the sulfur compound increases the quality of hydrogenated naphtha as a pyrolysis feedstock nearly to that of a C.sub.2 to C.sub.5 paraffin stream.

    摘要翻译: 含有小于10ppm(重量)硫的催化氢化石脑油流在不加入氢气的情况下被热分解到包括乙烯的产物中。 通过添加硫化合物来增加对乙烯的选择性,以使硫含量基于氢化石脑油提高到20ppm以上。 硫化合物的添加使作为热解原料的氢化石脑油的质量接近于C2至C5石蜡流的质量。