摘要:
A process for converting coal to liquid hydrocarbonaceous products involving a liquefaction reaction in the presence of a coal derived recycle slurry and a non-coal derived solvent comprising a hydrocarbonaceous oil or distillation bottom residue thereof intrinsically contaminated with greater than 300 ppm total of vanadium and nickel. The liquefaction reaction is performed under hydrogen pressure (approximately 500-4000 psi) and under elevated temperature (approximately 300.degree.-500.degree. C.) using a weight ratio of non-coal derived solvent to coal of about 1/1 or less. The conversion of coal to liquids is greatly enhanced by the use of such a non-coal derived solvent under these conditions.
摘要:
Synthesis gas is converted to diesel fuel and a high octane gasoline in two stages. In the first stage the synthesis gas is converted to straight chain paraffins mainly boiling in the diesel fuel boiling range utilizing a catalyst consisting essentially of cobalt, preferably promoted with a Group IIIB or IVB metal oxide, on a support of gamma-alumina, eta-alumina or mixtures thereof. A straight chain paraffin portion of the effluent in the C.sub.5 -C.sub.9 range is converted in a second stage to a highly aromatic and branched chain paraffinic gasoline using a platinum group metal catalyst.
摘要:
Synthesis gas is converted to a gasoline boiling range product high in branched chain paraffins and olefins utilizing a catalyst consisting essentially of (A) silicalite and (B) cobalt, preferably promoted with a Group IIIB or IVB metal oxide on an alumina support of gamma-alumina, eta-alumina or mixtures thereof.
摘要:
Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a supported cobalt-ruthenium catalyst in which the cobalt to ruthenium molar ratio is greater than about 200:1. The catalyst is preferably prepared by using a non-aqueous impregnation solution and using an activation procedure involving reduction, oxidation and reduction.
摘要:
A system is proposed for the purification of exhaust gases from internal combustion engines, preferably the reduction of nitrogen oxides in exhaust gases from internal combustion engines in which nitrogen is selectively formed as substantially the only nitrogen-containing product. The exhaust gas is contacted at an elevated temperature with a noble metal in a reducing atmosphere, wherein nitrogen oxides are selectively converted to nitrogen as substantially the only nitrogen containing product, and/or is contacted with a noble metal in an oxidizing atmosphere, wherein carbon monoxide and unburned hydrocarbons are converted to carbon dioxide and water, said noble metal being distended on a microporous glass body. In a preferred embodiment the exhaust gas is contacted at an elevated temperature in a reducing atmosphere with ruthenium supported on a microporous glass body comprising a leached, phase-separated alkali borosilicate.
摘要:
A catalyst for the conversion of synthesis gas comprising cobalt on a high surface area, high purity, low acidity alumina support of gamma-alumina, eta-alumina or mixtures thereof, whereby the catalyst is prepared by (A) impregnation of the alumina support with a non-aqueous, organic solvent impregnation solution of cobalt nitrate containing sufficient amounts of a Group IIIB or IVB metal salt to provide said catalyst with from about 0.05 to about 100 parts by weight of a Group IIIB or IVB metal oxide per 100 parts by weight cobalt, (B) reduction of the impregnated alumina support by heating, in the presence of hydrogen, at a heating rate of from about 0.5.degree. to about 5.degree. C. per minute to a maximum temperature in the range of 180.degree. to about 220.degree. C. for a hold time of 6 to about 24 hours and thereafter heating the impregnated alumina support in the presence of hydrogen while heating up to a maximum hold temperature of from about 250.degree. to about 400.degree. C. for a hold time of 6 to about 65 hours.
摘要翻译:用于在高表面积上转化包含钴的合成气的催化剂,γ-氧化铝,η-氧化铝或其混合物的高纯度,低酸度氧化铝载体,由此通过(A)将氧化铝载体浸渍 含有足够量的IIIB或IVB族金属盐的硝酸钴的非水性有机溶剂浸渍溶液,以使所述催化剂每100重量份提供约0.05至约100重量份的IIIB或IVB族金属氧化物 钴,(B)在氢存在下,以每分钟约0.5℃至约5℃的加热速率加热浸渍的氧化铝载体的还原,至180℃至约220℃的最高温度 保持时间为6至约24小时,然后在氢气存在下加热浸渍的氧化铝载体,同时加热至约250℃至约400℃的最大保持温度,保持时间为6 t 约65小时。
摘要:
A two-stage process for hydrodesulfurization of a metal-containing hydrocarbon oil employing a hydrodesulfurization catalyst in each stage having an activated support prepared by drying and calcining a crystalline alumina containing 1.2 to 2.6 mols of water of hydration per mol of alumina.
摘要:
A catalyst useful in the conversion of synthesis gas to diesel fuel in a fluidized bed is prepared by contacting finely divided alumina with an aqueous impregnation solution of a cobalt salt, drying the impregnated support and thereafter contacting the support with a nonaqueous, organic impregnation solution of salts of ruthenium and a Group IIIB or IVB metal.
摘要:
A catalytically hydrogenated naphtha stream containing less than 10 ppm by weight of sulfur is pyrolyzed without added hydrogen to a product including ethylene. Selectivity to ethylene is increased by adding a sulfur compound to increase the sulfur content to above 20 ppm by weight based on hydrogenated naphtha. Addition of the sulfur compound increases the quality of hydrogenated naphtha as a pyrolysis feedstock nearly to that of a C.sub.2 to C.sub.5 paraffin stream.
摘要:
A process for preparing acrylonitrile which comprises passing a gaseous mixture comprising propylene, ammonia and molecular oxygen and an ammoxidation catalyst through a reaction zone while controlling the superficial linear gas velocity and solids feeds rate to achieve a state of fast fluidization.