Method for making diamondoid lubricant base stock by alkylation with an
olefin in the presence of a Lewis acid
    4.
    发明授权
    Method for making diamondoid lubricant base stock by alkylation with an olefin in the presence of a Lewis acid 失效
    在路易斯酸存在下用烯烃烷基化制备金刚石润滑剂基础油料的方法

    公开(公告)号:US5345020A

    公开(公告)日:1994-09-06

    申请号:US70823

    申请日:1993-06-03

    IPC分类号: C07C2/54 C07C13/28

    摘要: The invention provides a method for selectively alkylating a diamondoid compound comprising reacting at least one .alpha.-olefin containing at least six carbon atoms with at least one diamondoid compound in the presence of an acid catalyst selected from the group consisting of AlX.sub.3 and BX.sub.3 wherein X is a halogen, in the absence of added proton-donating catalyst promoter. The invention further provides a lubricant composition comprising alkyl-substituted adamantanes wherein the ratio of linear to branched alkyl substituents is at least about 4:1 and wherein the average number of alkyl substitutions per diamondoid molecule is from about 1.5 to about 4.

    摘要翻译: 本发明提供了选择性烷基化金刚石化合物的方法,包括使至少一种含有至少6个碳原子的α-烯烃与至少一种类金刚石化合物在选自AlX 3和BX 3的酸催化剂存在下反应,其中X为 在没有添加质子递送催化剂促进剂的情况下是卤素。 本发明还提供了包含烷基取代的金刚烷的润滑剂组合物,其中直链与支链烷基取代基的比例为至少约4:1,并且其中每个金刚石类分子的平均烷基取代数为约1.5至约4。

    Lubricant composition and method for increasing diamondoid incorporation
in polyalphaolefin-containing lubricant
    6.
    发明授权
    Lubricant composition and method for increasing diamondoid incorporation in polyalphaolefin-containing lubricant 失效
    润滑剂组合物和增加含聚烯烃的润滑剂中金刚石结合的方法

    公开(公告)号:US5367097A

    公开(公告)日:1994-11-22

    申请号:US70815

    申请日:1993-06-03

    IPC分类号: C10M105/02 C07C13/615

    摘要: This invention provides a method for incorporating a diamondoid compound into a lubricant stock comprising reacting at least one .alpha.-olefin containing at least six carbon atoms with at least one diamondoid compound in the presence of an acid catalyst selected from the group consisting of AlX.sub.3, BX.sub.3, and GaX.sub.3, wherein X is a halogen, together with at least one added proton-donating catalyst promoter.The invention further provides a lubricant composition comprising alkyl-substituted diamondoids wherein the ratio of linear to branched alkyl substituents is at least about 4:1 and wherein the average number of alkyl substitutions per diamondoid molecule is from about 1.5 to about 4.

    摘要翻译: 本发明提供了一种将金刚石类化合物掺入润滑剂原料中的方法,包括使至少一种含有至少6个碳原子的α-烯烃与至少一种类金刚石化合物在选自AlX 3,BX 3 和GaX 3,其中X是卤素,以及至少一种添加的质子递送催化剂促进剂。 本发明还提供了包含烷基取代的金刚石的润滑剂组合物,其中直链与支链烷基取代基的比例为至少约4:1,并且其中每个金刚石类分子的平均烷基取代数为约1.5至约4。

    Well fluids based on low viscosity synthetic hydrocarbons
    7.
    发明授权
    Well fluids based on low viscosity synthetic hydrocarbons 失效
    基于低粘度合成烃的井液

    公开(公告)号:US5691281A

    公开(公告)日:1997-11-25

    申请号:US321006

    申请日:1994-10-06

    摘要: Solid, waxy 1-olefins may be converted to low viscosity liquid products by carrying out a double bond isomerization in the presence of a solid acidic catalyst such as an acidic clay or a zeolite under mild conditions. The olefin isomer products are useful in the formulation of well fluids such as drilling muds, especially useful in offshore drilling. The preferred oils for making up the well fluids are formulated with a hydrocarbon oil blend of the low viscosity olefin isomer together with a C.sub.12 to C.sub.18 paraffinic hydrocarbon of petroleum origin and a C.sub.10 to C.sub.32 olefin such as tetradecene-1. The fluids exhibit good biodegradability and are non-toxic to marine organisms; they also meet viscosity and pour points specifications for formulation into oil based muds.

    摘要翻译: 固体蜡状1-烯烃可以在温和条件下在固体酸性催化剂如酸性粘土或沸石的存在下进行双键异构化而转化为低粘度液体产物。 烯烃异构体产物可用于诸如钻井泥浆的井液制备,特别适用于海上钻井。 用于制备井液的优选油用低粘度烯烃异构体的烃油共混物与石油来源的C 12至C 18链烷烃和诸如十四碳烯-1的C 10至C 32烯烃一起配制。 液体表现出良好的生物降解性,对海洋生物无毒; 它们也符合粘度和倾点规格,用于配制成油基泥浆。