公开(公告)号：US5635439A

公开(公告)日：1997-06-03

申请号：US331093

申请日：1994-10-28

申请人： Hideo Fukui ,  Tsuyoshi Masumoto ,  Akihisa Inoue ,  Hisamichi Kimura ,  Katsutoshi Nosaki

发明人： Hideo Fukui ,  Tsuyoshi Masumoto ,  Akihisa Inoue ,  Hisamichi Kimura ,  Katsutoshi Nosaki

IPC分类号： C01B3/22 ,  B01J23/00 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  B01J23/63 ,  B01J23/66 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J23/76 ,  B01J23/80 ,  B01J23/89 ,  B22F9/00 ,  C01B3/32 ,  C22C1/04 ,  C22C32/00 ,  B01J23/38

CPC分类号： C01B3/326 ,  B01J23/66 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B22F9/008 ,  C22C1/04 ,  C22C32/0015 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1076 ,  Y02P20/52

摘要： A catalyst for methanol reforming which consists of an alloy represented by the general formula TM, wherein T is at least one element selected from the group consisting of Ti, Zr, Hf, Y, Nb and Zn; and M is at least one element selected from the group consisting of elements (Cu, Ag and Au) belonging to group IB of the periodic table and elements (Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt) belonging to group VIII of the periodic table, said alloy having a surface comprising an oxide including the element T and, dispersed therein, fine metal particles composed of the element M. The catalyst is produced by preparing an alloy having an amorphous phase and/or a microcrystalline phase from a molten composition of TM, and subsequently heating the alloy at 50.degree. to 700.degree. C. in an oxidizing atmosphere or an atmosphere like that in which methanol reforming is performed. Using the catalyst, methanol reforming can be efficiently performed at relatively low temperatures.

摘要翻译： 一种用于甲醇重整的催化剂，其由通式TM表示的合金组成，其中T是选自Ti，Zr，Hf，Y，Nb和Zn中的至少一种元素; M是选自属于元素周期表第1B族元素（Cu，Ag和Au）的元素中的至少一种元素（Fe，Co，Ni，Ru，Rh，Pd，Os，Ir和Pt） 属于元素周期表第Ⅷ族，所述合金具有包含元素T的氧化物的表面，并分散在其中，由元素M构成的金属微粒。该催化剂是通过制备具有非晶相和/或 来自TM的熔融组合物的微晶相，随后在氧化气氛或类似于进行甲醇重整的气氛下在50℃至700℃下加热合金。 使用催化剂，可以在相对较低的温度下有效地进行甲醇重整。

公开(公告)号：US4973369A

公开(公告)日：1990-11-27

申请号：US518815

申请日：1990-05-04

申请人： Tsuyoshi Masumoto ,  Akihisa Inoue ,  Hisamichi Kimura ,  Hatsuo Hirono ,  Koichi Moriyama ,  Hideo Fukui

发明人： Tsuyoshi Masumoto ,  Akihisa Inoue ,  Hisamichi Kimura ,  Hatsuo Hirono ,  Koichi Moriyama ,  Hideo Fukui

IPC分类号： B22D11/06 ,  B01J21/06 ,  B01J23/75 ,  C22C16/00 ,  C22C19/00 ,  C22C19/07 ,  C22C45/04 ,  C22C45/10 ,  C22F1/00 ,  C22F1/10 ,  C22F1/18 ,  H01M4/90

CPC分类号： B01J23/75 ,  H01M4/90

摘要： The specification discloses an alloy catalyst for oxidation of hydrogen which is prepared by heat treating a material comprising an amorphous alloy represented by the formula: Zr.sub.x Co.sub.(100-x) (wherein 10 atomic %.ltoreq..times..ltoreq.80 atomic %), according to the following three-steps in an oxidizing atomsphere: first heat-treatment step at a temperature at which the foregoing alloy stably exists as an amorphous single phase; second heat-treatment step at a temperature at which the alloy exists as a mixed phase of a metastable phase and an amorphous phase; and third-heat treatment step at a temperature at which the alloy is entirely transformed into a crystalline phase. The alloy catalyst of the present invention is a highly active catalyst for oxidation of hydrogen and exhibits a superior catalytic efficiency especially in catalytic combustion of hydrogen and in deoxidation and dehydrogenation of a gas mixture of hydrogen and oxygen.

公开(公告)号：US5753322A

公开(公告)日：1998-05-19

申请号：US634985

申请日：1996-04-19

申请人： Tadashi Yamaguchi ,  Hideo Fukui ,  Masayuki Kobayashi ,  Nobuyuki Nakada ,  Toshio Arai

发明人： Tadashi Yamaguchi ,  Hideo Fukui ,  Masayuki Kobayashi ,  Nobuyuki Nakada ,  Toshio Arai

IPC分类号： C09D5/14 ,  C23C28/00 ,  C23C28/04 ,  A47G1/12

CPC分类号： B01J35/004 ,  B01J23/42 ,  B01J23/50 ,  B01J23/72 ,  B01J37/0219 ,  B01J37/0226 ,  B01J37/0244 ,  C09D5/14 ,  C23C28/00 ,  C23C28/04 ,  B01J21/063 ,  Y10S428/901 ,  Y10S428/907 ,  Y10T428/31678

摘要： Disclosed is an aluminum building material which comprises a substrate made of aluminum or an aluminum alloy, an anodic oxide film formed on the surface of the substrate, and a thin film containing a photocatalytically active semiconductor and deposited on the anodic oxide film. The film containing the photocatalytically active semiconductor embraces both a film formed solely of the semiconductor mentioned above and a film having fine particles of the semiconductor incorporated in or deposited on a suitable carrier such as, for example, a coating film. A fixture unit is also provided which comprises a frame member made of the aluminum building material mentioned above, a panel member having the surface thereof coated with a film containing a photocatalytically active semiconductor, and a watertight and airtight member containing fine particles of a photocatalytically active semiconductor.

摘要翻译： 公开了一种铝建筑材料，其包括由铝或铝合金制成的基板，形成在基板的表面上的阳极氧化膜，以及含有光催化活性半导体并沉积在阳极氧化膜上的薄膜。 含有光催化活性半导体的膜既包括仅由上述半导体形成的膜，也包含掺入或沉积在合适载体（例如涂膜）上的半导体微粒的膜。 还提供了一种夹具单元，其包括由上述铝建筑材料制成的框架构件，其表面涂覆有含有光催化活性半导体的膜的面板构件和包含光催化活性的细颗粒的水密气密构件 半导体。

公开(公告)号：US06210615B1

公开(公告)日：2001-04-03

申请号：US09218450

申请日：1998-12-22

申请人： Fumitaka Yoshizuru ,  Hideharu Fujimatsu ,  Hideo Fukui

发明人： Fumitaka Yoshizuru ,  Hideharu Fujimatsu ,  Hideo Fukui

IPC分类号： B29C4314

CPC分类号： B29C43/42 ,  B29C67/0044 ,  B29C2793/0009 ,  B29C2793/0081 ,  B29K2105/253 ,  B29L2031/3005 ,  B29L2031/302 ,  B60R13/04

摘要： In a method for working the end portion of a roof molding for use in an automobile, at desired position on the molding surface 32 of a pressing mold 31 that faces a cut-away portion 21 formed on the back surface of the end portion 12 of the roof molding, there is formed a pressing projecting portion 33 which extends along the width direction of the end portion 12. In a pressing operation after the end portion 12 is heated and softened, the cut-away portion 21 of the back surface of the end portion 12 is pressed and deformed by the pressing projecting portion 33 of the pressing mold 31 to thereby form a mounting and fixing projection portion 22 which projects toward at least one side in the width direction of the end portion 12.

摘要翻译： 在用于汽车的车顶成型件的端部的加工方法中，在压模31的成型面32上的形成在端部12的背面12的后表面上的切口部分21的期望位置 屋顶成型件形成有沿着端部12的宽度方向延伸的按压突出部33.在端部12被加热并软化之后的按压操作中，切割部分21的后表面 端部12被按压模具31的按压突出部33挤压和变形，从而形成朝向端部12的宽度方向的至少一侧突出的安装固定突出部22。

公开(公告)号：US5120405A

公开(公告)日：1992-06-09

申请号：US663009

申请日：1991-03-01

申请人： Seishiro Ito ,  Hideo Fukui ,  Norio Nakada ,  Hatsuo Hirono

发明人： Seishiro Ito ,  Hideo Fukui ,  Norio Nakada ,  Hatsuo Hirono

IPC分类号： C25D11/18 ,  C25D11/20 ,  C25D11/22 ,  C25D11/24

CPC分类号： C25D11/22 ,  C25D11/24

摘要： An aluminum or aluminum alloy material is subjected to anodic oxidation, then to a treatment of electrophoresis in a bath containing a hexacyanoferrate (II) or hexacyanoferrate (III), and subsequently to a treatment of immersion in a bath containing at least one metal salt selected from the group consisting of salts of Fe, Ni, Co, Cu, Zn, Cd, Ba, Tl, and Mg and at least one electrolyte selected from the group consisting of sodium sulfate, potassium sulfate, sodium chloride, and potassium chloride. Consequently, a coloring compound formed by the reaction of the aforementioned hexacyanoferrate (II) or hexacyanoferrate (III) with the aforementioned metal salt is deposited in the receding parts of micropores of an anodic oxide coating, with the result that the aluminum or aluminum alloy material is endowed with a durable color.

摘要翻译： 对铝或铝合金材料进行阳极氧化，然后在含有六氰基铁酸盐（II）或六氰基铁酸盐（III）的浴中进行电泳处理，随后在包含至少一种选择的金属盐的浴中浸渍处理 从由Fe，Ni，Co，Cu，Zn，Cd，Ba，Tl和Mg的盐组成的组中选出的至少一种电解质和选自硫酸钠，硫酸钾，氯化钠和氯化钾的至少一种电解质。 因此，通过上述六氰基铁酸盐（II）或六氰基铁酸盐（III）与上述金属盐的反应形成的着色化合物沉积在阳极氧化物涂层的微孔的后退部分中，结果是铝或铝合金材料 具有耐用的颜色。

公开(公告)号：US6114279A

公开(公告)日：2000-09-05

申请号：US50207

申请日：1998-03-30

申请人： Hideo Fukui ,  Masayuki Kobayashi ,  Tadashi Yamaguchi ,  Hironori Arakawa ,  Kiyomi Okabe ,  Kazuhiro Sayama ,  Hitoshi Kusama

发明人： Hideo Fukui ,  Masayuki Kobayashi ,  Tadashi Yamaguchi ,  Hironori Arakawa ,  Kiyomi Okabe ,  Kazuhiro Sayama ,  Hitoshi Kusama

IPC分类号： B01J23/80 ,  C07C29/154 ,  B01J23/02

CPC分类号： B01J23/80 ,  C07C29/154 ,  Y02P20/52

摘要： A catalyst for methanol synthesis and reforming which is constituted of copper, zinc, and aluminum oxides and has a structure comprising copper or copper oxide particles covered with a film of aluminum oxide and zinc oxide. The copper or copper oxide particles preferably have a particle size of 1 to 100 nm. The film of aluminum oxide and zinc oxide preferably has a thickness of 0.1 to 100 nm. The proportions of the copper, zinc, and aluminum elements are 68.0 to 86.0% by weight, 4.5 to 21.0% by weight, and 2.0 to 20.0% by weight, respectively. The foregoing highly active catalyst comprising copper, zinc, and aluminum oxides can be obtained not by a costly special technique but by the coprecipitation method, which is the most common process for catalyst production, without using any additive element.

摘要翻译： 一种用于甲醇合成和重整的催化剂，其由铜，锌和铝氧化物构成，并且具有由氧化铝和氧化锌膜覆盖的铜或氧化铜颗粒的结构。 铜或氧化铜粒子的粒径优选为1〜100nm。 氧化铝和氧化锌的膜的厚度优选为0.1〜100nm。 铜，锌，铝元素的比例分别为68.0〜86.0重量％，4.5〜21.0重量％，2.0〜20.0重量％。 包含铜，锌和氧化铝的上述高活性催化剂不能通过昂贵的特殊技术获得，而是通过共沉淀法获得，这是最常用的催化剂生产方法，而不使用任何添加元素。

公开(公告)号：US5334297A

公开(公告)日：1994-08-02

申请号：US119559

申请日：1993-09-13

申请人： Norio Nakada ,  Hideo Fukui ,  Hatsuo Hirono ,  Seishiro Ito

发明人： Norio Nakada ,  Hideo Fukui ,  Hatsuo Hirono ,  Seishiro Ito

IPC分类号： C25D11/04 ,  C25D11/20 ,  C25D11/22 ,  C25D13/04

CPC分类号： C25D11/22 ,  B60N2/4817 ,  B60N2/4847

摘要： A fast and brightly colored oxide film of aluminum which excels in durability and allows no separation of pigment is produced by using an aqueous dispersion of an organic pigment or carbon black finely divided to a size in the range between 3 and 150 nm, forming on a surface of an aluminum member an anodic oxide film containing pores larger in diameter than the ordinary pores, and causing the organic pigment or carbon black to migrate and deposit in the pores of the oxide film by means of electrophoresis. The formation of the anodic oxide film containing the pores larger in diameter than the ordinary pores is accomplished in the first method by subjecting the aluminum member to anodic oxidation at a high voltage in an aqueous solution of acid. In the second method, the anodic oxide film is subjected either to a treatment of immersion in an aqueous solution of at least one acid selected from among phosphoric acid, sulfuric acid, oxalic acid, and sulfamic acid or to a combination treatment of immersion and AC electrolysis repeated in a prescribed number of cycles in the solution, to enlarge the pores in the anodic oxide film.

摘要翻译： 通过使用细分为3〜150nm范围内的有机颜料或炭黑的水性分散体，制造耐久性优异且不会分离颜料的快速且明亮的铝氧化膜，形成在 铝构件的表面是含有直径大于普通孔的孔的阳极氧化膜，并且通过电泳使有机颜料或炭黑迁移并沉积在氧化膜的孔中。 在第一种方法中，通过使铝构件在酸性水溶液中以高电压进行阳极氧化，实现了直径大于普通孔的阳极氧化膜的形成。 在第二种方法中，将阳极氧化膜进行浸渍在选自磷酸，硫酸，草酸，氨基磺酸中的至少一种酸的水溶液中，或浸渍和AC的组合处理 在溶液中以规定数量的循环重复电解，以扩大阳极氧化膜中的孔。

公开(公告)号：US06544233B1

公开(公告)日：2003-04-08

申请号：US09690892

申请日：2000-10-18

申请人： Hideo Fukui ,  Masato Nishimura

发明人： Hideo Fukui ,  Masato Nishimura

IPC分类号： A61M500

CPC分类号： A61M5/31596 ,  A61M5/284 ,  A61M5/3202 ,  A61M2005/3118 ,  A61M2005/3132 ,  A61M2005/31506 ,  A61M2005/31508 ,  A61M2005/31598

摘要： A pre-filled syringe includes an outer cylinder having a sealed nozzle, and an inner cylinder movable forward and rearward in the outer cylinder and forming a first space between the inner cylinder and an inner front end of the outer cylinder. A first gasket is slidably accommodated in the inner cylinder in a liquid-tight state, a second gasket is accommodated slidably in the inner cylinder in a liquid-tight state and is located rearward from the first gasket to form a second space between the first and second gaskets, and a plunger is attached at a rear end of the second gasket. A third gasket is installed near the front end of the inner cylinder to be slidable in a liquid-tight state between the inner and outer cylinders. A first medicine is stored in the first space and a second medicine is stored in the second space.

摘要翻译： 预填充注射器包括具有密封喷嘴的外筒和在外筒中可前后移动的内筒，并且在内筒与外筒的内前端之间形成第一空间。 第一垫圈以液密状态可滑动地容纳在内筒中，第二垫圈以液密状态可滑动地容纳在内筒中并且位于第一垫圈的后方，以在第一和第二垫圈之间形成第二空间， 第二垫圈和柱塞附接在第二垫圈的后端。 第三垫圈安装在内筒的前端附近，以能够在内筒和外筒之间以液密状态滑动。 第一药物储存在第一空间中，第二药物存储在第二空间中。

公开(公告)号：US5217601A

公开(公告)日：1993-06-08

申请号：US894586

申请日：1992-06-05

申请人： Norio Nakada ,  Hideo Fukui ,  Hatsuo Hirono ,  Seishiro Ito

发明人： Norio Nakada ,  Hideo Fukui ,  Hatsuo Hirono ,  Seishiro Ito

IPC分类号： C25D11/22

CPC分类号： C25D11/22

摘要： Durable and clear blue color of freely controlled density can be expeditiously and efficiently impated to an anodic oxide film of aluminum by a method which comprises forming the anodic oxide film on the aluminum or aluminum alloy, then subjecting the aluminum or aluminum alloy to AC electrolysis in a bath containing an inorganic ferrous salt as a main component thereof thereby inducing deposition of iron in the pores of the oxide film, and subsequently placing the aluminum or aluminum alloy as an anode in a bath containing hexacyano iron (II) acid salt as a main component thereof and subjecting the same to DC electrolysis therein. In the alternative method, the pore-widening treatment is added next to said step of anodic oxidation. The pore-widening treatment is effected by immersing the aluminum or aluminum alloy in sulfuric acid or phosphoric acid or electrolyzing the same in phosphoric acid or a mixed solution of phosphoric acid and sulfuric acid.

摘要翻译： 通过包括在铝或铝合金上形成阳极氧化膜，然后对铝或铝合金进行交流电解的方法，可以快速且有效地将耐用且清晰的蓝色的自由控制密度照射到铝的阳极氧化膜上 含有无机亚铁盐作为主要成分的浴，由此在氧化膜的孔中引起铁的沉积，随后将铝或铝合金作为阳极置于含有六氰基铁（II）酸盐作为主体的浴中 其组分并在其中进行DC电解。 在替代方法中，在所述阳极氧化步骤旁边加入扩孔处理。 通过将铝或铝合金浸渍在硫酸或磷酸中或在磷酸或磷酸和硫酸的混合溶液中电解，进行扩孔处理。

公开(公告)号：US5110782A

公开(公告)日：1992-05-05

申请号：US507601

申请日：1990-04-10

申请人： Hatsuo Hirono ,  Koichi Moriyama ,  Hideo Fukui ,  Ikuya Matsuura

发明人： Hatsuo Hirono ,  Koichi Moriyama ,  Hideo Fukui ,  Ikuya Matsuura

IPC分类号： B01D53/94 ,  B01J23/00 ,  B01J23/89 ,  B01J37/00 ,  F23D14/18

CPC分类号： B01J37/0018 ,  B01J23/00 ,  Y10S502/525

摘要： The present invention provides a process for producing a perovskite-type oxide catalyst. The process comprises the steps of reacting an aqueous solution containing plural metal salts, such as chloride, sulfate, nitrate, etc., and an aqueous solution of a neutralizer such as alkali carbonate, alkali hydroxide, ammonia, etc., so as to cause coprecipitation of neutral salts and firing the coprecipitated salts to provide a perovskite-type oxide. At least one organic substance selected from the group consisting of cellulose, polyvinyl acetate, polyethylene, polystyrene, polypropylene, polyvinyl alcohol, starch, gelatin and saccharide is added prior to the firing step. The addition of the organic substance makes possible the attainment of a highly active perovskite-type oxide catalyst composed of very fine particles (primary particles).