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公开(公告)号：US4973369A
公开(公告)日：1990-11-27
申请号：US518815
申请日：1990-05-04
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Hatsuo Hirono , Koichi Moriyama , Hideo Fukui
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Hatsuo Hirono , Koichi Moriyama , Hideo Fukui
IPC分类号： B22D11/06 , B01J21/06 , B01J23/75 , C22C16/00 , C22C19/00 , C22C19/07 , C22C45/04 , C22C45/10 , C22F1/00 , C22F1/10 , C22F1/18 , H01M4/90
摘要： The specification discloses an alloy catalyst for oxidation of hydrogen which is prepared by heat treating a material comprising an amorphous alloy represented by the formula: Zr.sub.x Co.sub.(100-x) (wherein 10 atomic %.ltoreq..times..ltoreq.80 atomic %), according to the following three-steps in an oxidizing atomsphere: first heat-treatment step at a temperature at which the foregoing alloy stably exists as an amorphous single phase; second heat-treatment step at a temperature at which the alloy exists as a mixed phase of a metastable phase and an amorphous phase; and third-heat treatment step at a temperature at which the alloy is entirely transformed into a crystalline phase. The alloy catalyst of the present invention is a highly active catalyst for oxidation of hydrogen and exhibits a superior catalytic efficiency especially in catalytic combustion of hydrogen and in deoxidation and dehydrogenation of a gas mixture of hydrogen and oxygen.
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2.发明授权Catalyst for methanol reforming, process for producing the same and method for reforming methanol 失效用于甲醇重整的催化剂，其制备方法和甲醇重整方法
公开(公告)号：US5635439A
公开(公告)日：1997-06-03
申请号：US331093
申请日：1994-10-28
IPC分类号： C01B3/22 , B01J23/00 , B01J23/42 , B01J23/44 , B01J23/52 , B01J23/63 , B01J23/66 , B01J23/72 , B01J23/75 , B01J23/755 , B01J23/76 , B01J23/80 , B01J23/89 , B22F9/00 , C01B3/32 , C22C1/04 , C22C32/00 , B01J23/38
CPC分类号： C01B3/326 , B01J23/66 , B01J23/72 , B01J23/75 , B01J23/755 , B22F9/008 , C22C1/04 , C22C32/0015 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , Y02P20/52
摘要： A catalyst for methanol reforming which consists of an alloy represented by the general formula TM, wherein T is at least one element selected from the group consisting of Ti, Zr, Hf, Y, Nb and Zn; and M is at least one element selected from the group consisting of elements (Cu, Ag and Au) belonging to group IB of the periodic table and elements (Fe, Co, Ni, Ru, Rh, Pd, Os, Ir and Pt) belonging to group VIII of the periodic table, said alloy having a surface comprising an oxide including the element T and, dispersed therein, fine metal particles composed of the element M. The catalyst is produced by preparing an alloy having an amorphous phase and/or a microcrystalline phase from a molten composition of TM, and subsequently heating the alloy at 50.degree. to 700.degree. C. in an oxidizing atmosphere or an atmosphere like that in which methanol reforming is performed. Using the catalyst, methanol reforming can be efficiently performed at relatively low temperatures.
摘要翻译： 一种用于甲醇重整的催化剂，其由通式TM表示的合金组成，其中T是选自Ti，Zr，Hf，Y，Nb和Zn中的至少一种元素; M是选自属于元素周期表第1B族元素（Cu，Ag和Au）的元素中的至少一种元素（Fe，Co，Ni，Ru，Rh，Pd，Os，Ir和Pt） 属于元素周期表第Ⅷ族，所述合金具有包含元素T的氧化物的表面，并分散在其中，由元素M构成的金属微粒。该催化剂是通过制备具有非晶相和/或 来自TM的熔融组合物的微晶相，随后在氧化气氛或类似于进行甲醇重整的气氛下在50℃至700℃下加热合金。 使用催化剂，可以在相对较低的温度下有效地进行甲醇重整。
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公开(公告)号：US5593515A
公开(公告)日：1997-01-14
申请号：US411164
申请日：1995-03-27
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Yoshiyuki Shinohara , Yuma Horio , Kazuhiko Kita
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Hisamichi Kimura , Yoshiyuki Shinohara , Yuma Horio , Kazuhiko Kita
CPC分类号： C22C1/0416 , C22C21/00 , C22C45/08 , C22F1/04
摘要： A high strength aluminum-based alloy, which having a composition of the general formula: Al.sub.bal Q.sub.a M.sub.b X.sub.c T.sub.d, wherein Q represents at least one element selected from the group consisting of Mn, Cr, V, Mo and W; M represents at least one element selected from the group consisting of Co, Ni, Cu and Fe; X represents at least one element selected from rare earth elements including Y or Mm; T represents at least one element selected from the group consisting of Ti, Zr and Hf; and a, b, c and d represent the following atomic percentages: 1.ltoreq.a.ltoreq.7, 0>5, 0>c.ltoreq.5 and 0>d.ltoreq.2, and contains quasi-crystals in the structure thereof. The alloy of the present invention is excellent in the hardness and strength at both room temperature and a high temperature, and also in thermal resistance and ductility. In addition, it is usable as a high specific strength material having a high strength and a low specific gravity due to a small amount of addition of rare earth element or elements.
摘要翻译： 一种高强度铝基合金，其具有以下通式的组成：AlbalQaMbXcTd，其中Q表示选自Mn，Cr，V，Mo和W中的至少一种元素; M表示选自Co，Ni，Cu和Fe中的至少一种元素; X表示选自包括Y或Mm的稀土元素中的至少一种元素; T表示选自Ti，Zr和Hf中的至少一种元素; 并且a，b，c和d表示以下原子百分比：1 5,0> c 5和0> d
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公开(公告)号：US06017403A
公开(公告)日：2000-01-25
申请号：US601949
申请日：1996-02-15
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Yuma Horio
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Yuma Horio
IPC分类号： C22C21/00
CPC分类号： C22C21/00
摘要： An aluminum-based alloy having the general formula Al.sub.x L.sub.y M.sub.z (wherein L is Mn or Cr; M is Ni, Co, and/or Cu; and x, y, and z, representing a composition ratio in atomic percentages, satisfy the relationships x+y+z=100, 75.ltoreq.x.ltoreq.95, 2.ltoreq.y.ltoreq.15, and 0.5.ltoreq.z.ltoreq.10) having a metallographic structure comprising a quasi-crystalline phase possesses high strength and high rigidity. In order to enhance the ductility and toughness of the aluminum-based alloy, the atomic percentage of M may be further limited to 0.5.ltoreq.z.ltoreq.4, and more preferably to 0.5.ltoreq.z.ltoreq.3. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.
摘要翻译： 具有通式AlxLyMz（其中L是Mn或Cr; M是Ni，Co和/或Cu;和表示原子百分比的组成比的x，y和z）的铝基合金满足关系x + 具有包含准结晶相的金相组织的y + z = 100,75，或者= x，y = x，z = 100，75
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公开(公告)号：US6004407A
公开(公告)日：1999-12-21
申请号：US717468
申请日：1996-09-20
IPC分类号： H01F1/057
CPC分类号： B82Y25/00 , H01F1/0579
摘要： Hard magnetic materials of the present invention contain at least one element of Fe, Co and Ni as a main component, at least one element M of Zr, Nb, Ta and Hf, at least one rare earth element R and B. The texture of the materials has at least 70% of fine crystalline phase having an average grain size of 100 nm or less, and the residue having an amorphous phase, the fine crystalline phase mainly composed of bcc-Fe or bcc-Fe compound, Fe--B compound and/or R.sub.2 Fe.sub.14 B.sub.1.
摘要翻译： 本发明的硬磁性材料含有Fe，Co和Ni作为主要成分的至少一种元素，Zr，Nb，Ta和Hf的至少一种元素M，至少一种稀土元素R和B。 该材料具有至少70％的平均粒径为100nm以下的细晶相，残留物为非晶相，主要由bcc-Fe或bcc-Fe化合物构成的微晶相，Fe-B化合物 和/或R2Fe14B1。
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6.发明授权Fe based soft magnetic alloy, magnetic materials containing same, and magnetic apparatus using the magnetic materials 失效Fe基软磁合金，含有磁性材料的磁性材料，以及使用磁性材料的磁性装置
公开(公告)号：US5741373A
公开(公告)日：1998-04-21
申请号：US422720
申请日：1995-04-14
CPC分类号： H01F41/0226 , G11B5/127 , G11B5/147 , H01F1/15308 , H01F1/15341 , H01F1/15358 , H01F10/131 , H01F10/136
摘要： An Fe-based soft magnetic alloy having a high saturated magnetic flux density and having a composition represented by formula (I) below: (Fe.sub.1-a Q.sub.a).sub.b B.sub.x T.sub.y T'.sub.z (I) wherein Q represents at least one element selected from the group consisting of Co and Ni; T represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, with Zr and/or Hf being always included; T' represents at least one element selected from the group consisting of Cu, Ag, Au, Ni, Pd and Pt; a, b, x, y and z are real numbers satisfying relationships below: 0.ltoreq.a.ltoreq.0.05, 0.ltoreq.b.ltoreq.93 atomic %, 0.5.ltoreq.x.ltoreq.16 atomic %, 4.ltoreq.y.ltoreq.10 atomic %, 0.ltoreq.z.ltoreq.4.5 atomic % provided that when 0
摘要翻译： 具有高饱和磁通密度且具有由下式（I）表示的组成的Fe基软磁合金：（Fe1-aQa）bBxTyT'z（I）其中Q表示选自以下的至少一种元素： Co和Ni; T表示选自Ti，Zr，Hf，V，Nb，Ta，Mo和W中的至少一种元素，其中始终包括Zr和/或Hf; T'表示选自Cu，Ag，Au，Ni，Pd和Pt中的至少一种元素; a，b，x，y和z是满足以下关系的实数：0
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公开(公告)号：US5619174A
公开(公告)日：1997-04-08
申请号：US283133
申请日：1994-07-29
CPC分类号： H01F41/0226 , H01F17/062 , H01F30/16
摘要： A noise filter includes an annular magnetic core made of a soft magnetic alloy ribbon mainly made of Fe and containing B and at least one element selected from a group consisting of Ti, Zr, Hf, Nb, Ta, Mo and W, at least 50% of the soft magnetic alloy structure being composed of body-centered cubic structured fine grains having an average grain size of 30 nm or below, a casing for accommodating the magnetic core and having an insulating plate, a pair of coils separated from each other by the insulating plate, and an electronic circuit for connecting a core element made up of the magnetic core, the casing and the coils.
摘要翻译： 噪声滤波器包括由主要由Fe构成并含有B的软磁性合金带和从由Ti，Zr，Hf，Nb，Ta，Mo和W组成的组中选择的至少一种元素制成的环形磁芯，至少50 软磁合金结构的％由平均粒径为30nm以下的体心立方结构细晶粒组成，用于容纳磁芯并具有绝缘板的壳体，通过 绝缘板和用于连接由磁芯，壳体和线圈构成的芯体元件的电子电路。
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公开(公告)号：US5474624A
公开(公告)日：1995-12-12
申请号：US121715
申请日：1993-09-14
CPC分类号： C22C45/00 , H01F1/15308 , H01F1/15341
摘要： The present invention relates to a method of stably manufacturing a Fe-base soft magnetic alloy having steps of subjecting an amorphous alloy mainly composed of Fe to heat treatment in which the amorphous alloy is heated to 400.degree. to 750.degree. C. at a heating rate of 1.0.degree. C./minute or higher so that at least 50% or more of the structure of the amorphous alloy is made of fine crystalline grains formed into a body-centered cubic structure and having an average grain size of crystal of 30 nm or smaller as to have a high magnetic permeability and saturation magnetic flux density.
摘要翻译： 本发明涉及一种稳定制造Fe基软磁性合金的方法，其特征在于，将以Fe为主成分的非晶态合金进行加热处理的加热处理的加热速度为400〜750℃ 为1.0℃/分钟以上，使非晶合金的结构的至少50％以上由细心晶体形成为体心立方结构，平均结晶粒径为30nm， 具有较高的磁导率和饱和磁通密度。
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公开(公告)号：US5423969A
公开(公告)日：1995-06-13
申请号：US217009
申请日：1994-03-23
CPC分类号： C23F13/14
摘要： The present invention provides a sacrificial electrode material which consists of a single phase amorphous structure or a structure consisting of an amorphous phase and a crystalline solid solution phase and provides electrochemical corrosion protection to metallic articles exposed to an aqueous electrolytic solution. The electrode material is prepared by rapidly quenching a magnesium-based alloy material from the liquid phase or vapor phase thereof, the magnesium-based alloy material consisting the general formula: Mg.sub.bal X1.sub.a X2.sub.b or Mg.sub.bal X1.sub.a, wherein X1 is at least one element selected from the group consisting of Al, Zn, Ga, Ca and In; X2 is at least one element selected from the group consisting of Mm (misch metal), Y and rare earth metal elements; a and b are, in atomic percentages, 5.0.ltoreq.a.ltoreq.35.0 and 3.0.ltoreq.b.ltoreq.25.0, respectively. The magnesium-based alloy material may further contain one or more transition metal elements in their total contents not exceeding 1.0 atomic %.
摘要翻译： 本发明提供一种牺牲电极材料，其由单相无定形结构或由非晶相和结晶固溶体相组成的结构组成，并且对暴露于水性电解液的金属制品提供电化学腐蚀保护。 通过从其液相或气相快速淬火镁基合金材料制备电极材料，镁基合金材料由以下通式组成：MgbalX1aX2b或MgbalX1a，其中X1是选自以下的至少一种元素： 的Al，Zn，Ga，Ca和In; X2是选自由Mm（混合稀土金属），Y和稀土金属元素组成的组中的至少一种元素; a和b分别为原子百分比为5.0
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公开(公告)号：US5423923A
公开(公告)日：1995-06-13
申请号：US315620
申请日：1994-09-30
申请人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
发明人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
IPC分类号： C23C14/00 , C23C14/06 , C23C14/22 , C23C14/24 , C23C14/32 , C23C14/34 , C22C14/00 , C22C1/00 , C22C29/00
CPC分类号： C23C14/0021 , C23C14/0641 , C23C14/0688 , Y10T428/12486 , Y10T428/12576
摘要： Deposition of a hard film of Ti-Si-N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at % .ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti-Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.
摘要翻译： 通过使用具有TiaSib组成的蒸发源（其中“a”和“b”表示分别落在75的范围内的原子百分比），将Ti-Si-N复合材料的硬膜沉积在基底上 at％
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