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公开(公告)号：US06531527B2
公开(公告)日：2003-03-11
申请号：US09881107
申请日：2001-06-15
IPC分类号： C08K500
摘要： A production process for a viscosity-stabilizer-containing natural rubber comprising a step of adding a viscosity stabilizer liquid diluted with a solvent to a natural rubber, and a viscosity-stabilizer-containing natural rubber latex to which added is a viscosity stabilizer dissolved in an aliphatic chain compound, and a viscosity-stabilizer-containing natural rubber obtained by adding a viscosity stabilizer liquid diluted with a solvent to a natural rubber after it was coagulated.
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2.发明授权High aromatic oil and rubber composition and oil extended synthetic rubber using the same 失效高芳烃油和橡胶组合物和油扩展合成橡胶使用相同
公开(公告)号：US6103808A
公开(公告)日：2000-08-15
申请号：US930351
申请日：1997-09-30
申请人： Takatsugu Hashimoto
发明人： Takatsugu Hashimoto
CPC分类号： C08K5/01
摘要： The high aromatic oil provided in the present invention is characterized by that a glass transition point is -45 to -20.degree. C. and an aromatic component measured by Clay-Gel method accounts for 55 to 90% by weight and that a polycyclic aromatic compound measured by IP 346 method accounts for less than 3% by weight based on the whole components of hydrocarbons contained in the oil.This high aromatic oil can suitably be used for various rubber compositions such as tires, rubber vibration insulators and fenders, oil extended synthetic rubbers, printing inks and writing inks.
摘要翻译： PCT No.PCT / JP97 / 02244 Sec。 371日期：1997年9月30日 102（e）1997年9月30日PCT PCT 1997年6月27日PCT公布。 公开号WO97 / 35462 日期1997年10月2日本发明提供的高芳族化油的特征在于玻璃化转变温度为-45〜-20℃，通过粘土凝胶法测定的芳香族成分为55〜90重量％， 通过IP 346法测定的多环芳族化合物占油中所含烃的全部组分的重量小于3重量％。 这种高芳香性油可适用于各种橡胶组合物，例如轮胎，橡胶振动绝缘子和挡泥板，油扩展合成橡胶，印刷油墨和书写油墨。
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公开(公告)号：US5341862A
公开(公告)日：1994-08-30
申请号：US974519
申请日：1992-11-12
申请人： Takatsugu Hashimoto , Keizo Akutagawa , Kazuo Yagawa , Makoto Tanaka , Junichi Yamagishi , Kazuo Hachiya
发明人： Takatsugu Hashimoto , Keizo Akutagawa , Kazuo Yagawa , Makoto Tanaka , Junichi Yamagishi , Kazuo Hachiya
CPC分类号： B60C11/00 , B60C1/00 , B60C1/0016 , B60C11/1346 , Y10T152/10495
摘要： In a flame-retardant rubber tire comprising an outer rubber body portion consisting essentially of a tread rubber layer, a sidewall rubber layer extending inward from each side edge of the tread rubber layer toward the vicinity of a bead portion in radial direction and a rubber chafer layer arranged in the vicinity of the bead portion, a flame-retardant rubber composition having an oxygen index of not less than 19.8 but not more than 27.5 is disposed so as to amount at least 20% by weight of the tread rubber layer. Such rubber tires are used in electric vehicles, automobiles, airplanes and the like and have excellent self-extinguishing property and flame-delaying property without damaging other rubber properties.
摘要翻译： 在一种阻燃橡胶轮胎中，该橡胶轮胎包括基本上由胎面橡胶层组成的外部橡胶本体部分，从胎面橡胶层的每个侧边缘朝向径向方向的胎圈部分附近向内延伸的侧壁橡胶层和橡胶胎圈包布 布置在胎圈部附近的层，设置氧指数为19.8以上且27.5以下的阻燃性橡胶组合物，其量为胎面橡胶层的至少20重量％。 这种橡胶轮胎用于电动汽车，汽车，飞机等，具有优异的自熄性和阻燃性，而不损害其它橡胶性能。
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4.发明授权Method for incorporating metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids in polymers 失效（ALPHA），（BETA） - 乙烯基不饱和羧酸在聚合物中的金属盐的方法
公开(公告)号：US5096943A
公开(公告)日：1992-03-17
申请号：US509277
申请日：1990-04-16
摘要： A method for incorporating metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids into polymers and improving the cured physical properties of vulcanizable rubber compositions based on such polymers. The method includes the steps of preparing a polymer cement in a suitable organic solvent, forming a suspension of the metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in a suitable aliphatic hydrocarbon solvent miscible with the organic solvent, mixing the polymer cement and the suspension together and thereafter removing the solvents to provide the metal salt uniformly dispersed within the polymer.
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公开(公告)号：US4889677A
公开(公告)日：1989-12-26
申请号：US200963
申请日：1988-06-01
IPC分类号： B29C33/02 , B29C33/64 , B29C35/02 , B29D30/00 , B29D30/06 , B29K21/00 , B29K105/24 , B29L30/00
CPC分类号： B29D30/0662 , B29C33/64
摘要： A method of molding and vulcanizing more than 40 rubber products successively by using a curing bladder, which has been treated at the surface thereof with a silicone composition including:(a) 100 parts by weight of a polyorganosiloxane composed mainly of polydimethylsiloxane with a viscosity at 25.degree. C. of from 3,000 to 5,000,000 cst,(b) from 30 to 300 parts by weight of a polymethylhydrogensiloxane with a viscosity at 25.degree. C. of from 10 to 70 cst,(c) from 2 to 25 parts by weight of a finely powderous silica, and,(d) from 0 to 30 parts by weight of an organic acid salt of one or more of metals selected from the group consisting of zinc, magnesium, manganese and cobalt.
摘要翻译： 一种通过使用已经在其表面处理了硅氧烷组合物的固化囊来连续成型和硫化40多种橡胶制品的方法，所述硅氧烷组合物包括：（a）100重量份主要由聚二甲基硅氧烷组成的聚有机硅氧烷， 25℃，3,000至5,000,000cst，（b）30至300重量份的在25℃下的粘度为10至70cst的聚甲基氢硅氧烷，（c）2至25重量份的 细粉状二氧化硅，和（d）0〜30重量份选自锌，镁，锰和钴的一种或多种金属的有机酸盐。
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公开(公告)号：US5331036A
公开(公告)日：1994-07-19
申请号：US34969
申请日：1993-03-23
CPC分类号： C08F236/10 , C08K5/01 , C08L9/06
摘要： Elastomer compositions comprising (A) ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000 and (B) oil are described. The ultra high molecular weight copolymer compositions which are also characterized as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R.degree.M and a 1,3-conjugated diene wherein R.degree. is a hydrocarbyl group, M is an alkali metal, the mole ratio of R.degree.M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1. The oil extended elastomer compositions of the present invention preferably contain large amounts of oil such as 80 parts or higher per 100 parts of copolymer.
摘要翻译： 描述了包含（A）重均分子量大于约1,000,000的1,3-共轭二烯和芳族乙烯基化合物的超高分子量共聚物组合物和（B）油的弹性体组合物。 还特征在于在四氢呋喃中的特性粘度至少为4.0的超高分子量共聚物组合物可以通过以下方法获得，该方法包括在烃溶剂中使1,3-共轭二烯和乙烯基芳族化合物在 存在包含含有至少4个碳原子的1-炔烃的反应产物的三聚1-炔烃催化剂，有机金属化合物R TM和1,3-共轭二烯，其中R DEG是烃基，M是 碱金属，R-M与1-炔炔的摩尔比为约3:1，共轭二烯与1-炔烃的摩尔比为约2:1至约30:1。 本发明的油延伸弹性体组合物优选含有大量的油，例如每100份共聚物为80份或更高。
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7.发明授权Anhydrous metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids and related methods 失效（ALPHA），（BETA） - 乙烯基不饱和羧酸的非金属金属盐及相关方法
公开(公告)号：US5202363A
公开(公告)日：1993-04-13
申请号：US509278
申请日：1990-04-16
IPC分类号： C07C51/41 , C07C57/03 , C07C57/04 , C07F1/08 , C07F3/06 , C07F15/02 , C08K5/04 , C08K5/09 , C08K5/098 , C08L21/00
摘要： A reinforcing agent for vulcanizable rubber compounds comprises an anhydrous metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid having a crystalline structure consisting essentially of plates and fibers. Vulcanizable rubber compounds containing such reinforcing agents have improved physical properties over rubber compounds containing conventional metal carboxylic acid salts. Methods for the preparation of such anhydrous metal salts and methods for the reinforcement of vulcanizable rubber compounds therewith are also provided.
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8.发明授权Anhydrous metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids and related methods 失效α，β-烯属不饱和羧酸的无水金属盐及相关方法
公开(公告)号：US5137976A
公开(公告)日：1992-08-11
申请号：US801040
申请日：1991-12-03
摘要： A reinforcing agent for vulcanizable rubber compounds comprises an anhydrous metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid having a crystalline structure consisting essentially of plates and fibers. Vulcanizable rubber compounds containing such reinforcing agents have improved physical properties over rubber compounds containing conventional metal carboxylic acid salts. Methods for the preparation of such anhydrous metal salts and methods for the reinforcement of vulcanizable rubber compounds therewith are also provided.
摘要翻译： 用于可硫化橡胶化合物的增强剂包括具有基本上由板和纤维组成的晶体结构的α，β-烯键式不饱和羧酸的无水金属盐。 含有这种增强剂的可硫化橡胶化合物相对于含有常规金属羧酸盐的橡胶化合物具有改善的物理性能。 还提供了制备这种无水金属盐的方法和用于增强可硫化橡胶化合物的方法。
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公开(公告)号：US5587417A
公开(公告)日：1996-12-24
申请号：US403720
申请日：1995-03-14
CPC分类号： C08K3/04 , B60C1/0016 , C08K5/09
摘要： A rubber composition for a tire tread which is provided by the present invention can be obtained by blending 100 parts by weight of a natural rubber and/or a diene synthetic rubber with40 to 100 parts by weight of a carbon black having characteristic values of a cetyltriammonium bromide adsorption specific surface area (CTAB) being 90 to 220 m.sup.2 /g and a 24M4DBP absorption value being 90 to 140 ml/100 g, and0.1 to 20 parts by weight of an organic unsaturated fatty acid having two or more carbon double bonds in its molecule which includes 10% by weight or more of a conjugated diene acid having at least one pair of two carbon double bonds in a conjugated relation in its molecule.This rubber composition for a tire tread can be suitably used for a pneumatic tire, particularly a pneumatic tire for heavy load having an excellent wear resistance.
摘要翻译： PCT No.PCT / JP93 / 00971 Sec。 371日期：1995年3月14日 102（e）1995年3月14日PCT PCT 1993年7月14日PCT公布。 出版物WO93 / 日本特开1993年10月14日由本发明提供的轮胎胎面用橡胶组合物可以通过将100重量份的天然橡胶和/或二烯合成橡胶与40〜100重量份的炭黑 十六烷基三甲基溴化铵吸附比表面积（CTAB）的特征值为90〜220m2 / g，24M4DBP吸收值为90〜140ml / 100g，0.1〜20重量份具有2个 或更多的碳双键，其包含10重量％以上的分子中具有共轭关系的至少一对双碳双键的共轭二烯酸。 用于轮胎胎面的这种橡胶组合物可以适用于充气轮胎，特别是具有优异耐磨性的重载充气轮胎。
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公开(公告)号：US5531256A
公开(公告)日：1996-07-02
申请号：US230774
申请日：1994-04-21
申请人： Takatsugu Hashimoto , Keizo Akutagawa , Kazuo Yagawa , Makoto Tanaka , Junichi Yamagishi , Kazuo Hachiya
发明人： Takatsugu Hashimoto , Keizo Akutagawa , Kazuo Yagawa , Makoto Tanaka , Junichi Yamagishi , Kazuo Hachiya
CPC分类号： B60C11/00 , B60C1/00 , B60C1/0016 , B60C11/1346 , Y10T152/10828
摘要： In a flame-retardant rubber tire comprising an outer rubber body portion consisting essentially of a tread rubber layer, a sidewall rubber layer extending inward from each side edge of the tread rubber layer toward the vicinity of a bead portion in radial direction and a rubber chafer layer arranged in the vicinity of the bead portion, a flame-retardant rubber composition having an oxygen index of not less than 19.8 but not more than 27.5 is disposed so as to amount at least 20% by weight of the tread rubber layer. Such rubber tires are used in electric vehicles, automobiles, airplanes and the like and have excellent self-extinguishing property and flame-delaying property without damaging other rubber properties.
摘要翻译： 在一种阻燃橡胶轮胎中，该橡胶轮胎包括基本上由胎面橡胶层组成的外部橡胶本体部分，从胎面橡胶层的每个侧边缘朝向径向方向的胎圈部分附近向内延伸的侧壁橡胶层和橡胶胎圈包布 布置在胎圈部附近的层，设置氧指数为19.8以上且27.5以下的阻燃性橡胶组合物，其量为胎面橡胶层的至少20重量％。 这种橡胶轮胎用于电动汽车，汽车，飞机等，具有优异的自熄性和阻燃性，而不损害其它橡胶性能。
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