公开(公告)号：US5760120A

公开(公告)日：1998-06-02

申请号：US544481

申请日：1995-10-18

申请人： Hiroyuki Itoh ,  Yukiko Ito ,  Masaaki Mawatari ,  Hisao Nagai ,  Kazuo Miyamoto ,  Mitsuru Kawakita

发明人： Hiroyuki Itoh ,  Yukiko Ito ,  Masaaki Mawatari ,  Hisao Nagai ,  Kazuo Miyamoto ,  Mitsuru Kawakita

IPC分类号： C08K3/22 ,  B41M5/26 ,  C08K3/00 ,  C08L25/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/10 ,  C08L33/18 ,  C08L33/24 ,  C08L35/00 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08J5/10 ,  C08K3/18

CPC分类号： C08K3/0075 ,  B41M5/267 ,  C08L55/02

摘要： A laser marking resin composition excellent in appearance of molded article and impact resistance which comprises: (A) 100 parts by weight of a rubber-reinforced vinyl resin consisting of: (A-1) 1 to 100% by weight of a rubber-reinforced resin having a grafting degree of 5 to 150% by weight obtained by polymerizing, in the presence of (a) 5 to 70% by weight of a rubbery polymer, (b) 95 to 30% by weight of at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (a)+(b)=100% by weight, and (A-2) 99 to 0% by weight of a polymer obtained by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (A-1)+(A-2)=100% by weight, the matrix resin in the component (A) having an intrinsic viscosity �.eta.! of 0.1 to 1.5 dl/g as measured in methyl ethyl ketone at 30.degree. C., and (B) 0.01 to 30 parts by weight of at least one compound selected from the group consisting of (B-1) titanium black, (B-2) black iron oxide, (B-3) yellow iron oxide and (B-4) carbon black.

摘要翻译： 一种模塑制品的外观和耐冲击性优异的激光标记树脂组合物，包括：（A）100重量份由以下组成的橡胶增强乙烯基树脂组成：（A-1）1至100重量％的橡胶增强 在（a）5〜70重量％的橡胶状聚合物的存在下，通过聚合得到的接枝度为5〜150重量％的树脂，（b）95〜30重量％的至少一种选自 由（a）+（b）= 100重量％和（A-2）组成的组成的芳香族乙烯基化合物，乙烯基氰化合物，（甲基）丙烯酸酯，马来酸酐和马来酰亚胺化合物， 通过聚合至少一种选自芳族乙烯基化合物，乙烯基氰化合物，（甲基）丙烯酸酯，马来酸酐和马来酰亚胺化合物的单体而获得的聚合物的99至0重量％，条件是（ A-1）+（A-2）= 100重量％时，成分（A）中的基质树脂的特性粘度η 在甲基乙基酮中在30℃下测量为0.1至1.5dl / g，和（B）0.01至30重量份的至少一种选自（B-1）钛黑，（B -2）黑色氧化铁，（B-3）黄色氧化铁和（B-4）炭黑。

公开(公告)号：US5302647A

公开(公告)日：1994-04-12

申请号：US728223

申请日：1991-07-12

申请人： Masanori Suzuki ,  Hiroyuki Itoh ,  Masaaki Mawatari ,  Tateki Furuyama

发明人： Masanori Suzuki ,  Hiroyuki Itoh ,  Masaaki Mawatari ,  Tateki Furuyama

IPC分类号： C08K5/00 ,  C08K5/523 ,  C09K21/14 ,  C08K3/28 ,  C08K3/32

CPC分类号： C09K21/14 ,  C08K5/0066 ,  C08K5/523

摘要： A flame retardant resin composition which includes the following component (A) and component (B) blended in the ratio (A):(B)=100:1-40 parts by weight. Component (A) is a thermoplastic resin including 0-70% by weight of a rubber component and 100-30% by weight of a polymer component formed from monomers comprising a methylated aromatic vinyl monomer and an hydroxylated aromatic vinyl monomer and, optionally, an aromatic vinyl monomer other than the above monomers, a cyanated vinyl monomer, a (meth)acrylic acid ester monomer, maleic anhydride, and a maleimide monomer; graft ratio of the thermoplastic resin being 10-150% when the rubber component is used. Component (B) is a flame retarder.

摘要翻译： 一种阻燃树脂组合物，其包含以（A）：（B）的比例共混的以下组分（A）和组分（B）= 100：1-40重量份。 组分（A）是包含0-70重量％的橡胶组分和100-30重量％的由包含甲基化芳族乙烯基单体和羟基化芳族乙烯基单体的单体形成的聚合物组分的热塑性树脂，任选地， 芳族乙烯基单体，上述单体，氰化乙烯基单体，（甲基）丙烯酸酯单体，马来酸酐和马来酰亚胺单体; 当使用橡胶组分时，热塑性树脂的接枝率为10-150％。 组分（B）是阻燃剂。

公开(公告)号：US20130138223A1

公开(公告)日：2013-05-30

申请号：US13817168

申请日：2011-08-12

申请人： Masaaki Mawatari ,  Iwao Noda

发明人： Masaaki Mawatari ,  Iwao Noda

IPC分类号： A61F2/28

CPC分类号： A61F2/28 ,  A61L27/32 ,  A61L27/54 ,  A61L2300/104 ,  A61L2300/404 ,  A61L2430/02 ,  A61L2430/12 ,  A61L2430/24

摘要： Provided is a bioimplant superior in antimicrobial action and safety in the body. The bioimplant according to the present invention comprises a base material of metal, ceramic, or plastic and a thermal spraying film of a calcium phosphate-based material formed at least partially thereon and the silver concentration in the thermal spraying film is 0.02 wt % to 3.00 wt %.

摘要翻译： 提供了一种在体内抗菌作用和安全性方面优异的生物植物。 根据本发明的生物植入物包括金属，陶瓷或塑料的基材和至少部分形成在其上的磷酸钙基材料的热喷涂膜，并且热喷涂膜中的银浓度为0.02重量％至3.00 重量％。

公开(公告)号：US06743849B2

公开(公告)日：2004-06-01

申请号：US09886256

申请日：2001-06-22

申请人： Masaaki Mawatari ,  Kenji Mitamura

发明人： Masaaki Mawatari ,  Kenji Mitamura

IPC分类号： C08L7700

CPC分类号： C08L77/00 ,  C08G69/26 ,  C08L77/06

摘要： The invention provides a thermoplastic resin composition having excellent blister resistance, which does not cause blister on the surfaces of resinous parts by passing through a reflowing oven when the resin composition is used as a resin material forming the resinous parts subjected to the surface-mount technology system, particularly, a thermoplastic resin composition high in mechanical strength such as flexural strength, weld strength and tensile elongation and excellent in moldability and friction property. The resin composition contains a polyamide resin component composed of 5 to 95% by weight of the following component (A) and 95 to 5% by weight of the following component (B): Component (A): a polyamide resin obtained by polycondensing diamine(s) including at least tetramethylenediamine with dicarboxylic acid(s) including at least adipic acid; and Component (B): a polyamide resin obtained by polycondensing diamine(s) including at least one of 1,9-nonanediamine and 2-methyl-1,8-octanediamine with dicarboxylic acid(s) including at least terephthalic acid.

摘要翻译： 本发明提供一种具有优异的耐起泡性的热塑性树脂组合物，当树脂组合物用作形成经表面安装技术的树脂部分的树脂材料时，通过回流炉不会引起树脂部件表面的起泡 特别是具有抗弯强度，焊接强度，拉伸伸长率等机械强度高，成型性和摩擦性优异的热塑性树脂组合物。 树脂组合物含有由以下组分（A）5至95重量％和以下组分（B）95至5重量％组成的聚酰胺树脂组分：组分（A）：通过缩聚二胺 包括至少包含至少四甲基二胺与至少包含己二酸的二羧酸; 和组分（B）：通过将包含1,9-壬二胺和2-甲基-1,8-辛二胺中的至少一种的二胺与至少包含对苯二甲酸的二羧酸缩聚得到的聚酰胺树脂。

公开(公告)号：US08084538B2

公开(公告)日：2011-12-27

申请号：US12359472

申请日：2009-01-26

申请人： Masaaki Mawatari ,  Tatsuya Toneri

发明人： Masaaki Mawatari ,  Tatsuya Toneri

IPC分类号： C08L67/04 ,  C08L77/00 ,  C08L83/04

CPC分类号： C08L67/02 ,  C08L25/04 ,  C08L33/00 ,  C08L59/00 ,  C08L67/025 ,  C08L69/00 ,  C08L71/12 ,  C08L75/08 ,  C08L77/00 ,  C08L87/005 ,  C08L2666/02 ,  C08L67/00

摘要： The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B1) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass. In the preferred embodiment of the present invention, the thermoplastic polymer composition further comprises a specific amount of at least one polymer selected from the group consisting of (C1) a polyester-based resin, (C2) a polyamide-based resin, (C3) an acrylic resin, (C4) a polycarbonate-based resin, (C5) a polyacetal-based resin, (C6) a polyphenylene ether-based resin, (C7) a polyolefin-based resin and (C8) a styrene-based resin.

摘要翻译： 本发明提供能够表现出优异的耐冲击性，耐久性和去静电性能的热塑性聚合物组合物。 本发明涉及一种热塑性聚合物组合物，其包含（A）50〜95质量％的脂肪族聚酯类树脂和（B）5〜50质量％的嵌段共聚物，所述嵌段共聚物包含（B1）硬链段， 选自聚酰胺，聚酯，聚烯烃和聚氨酯的至少一种聚合物和（B2）具有醚键的软链段，条件是组分（A）和（B）的总量 ）为100质量％。 在本发明的优选实施方案中，热塑性聚合物组合物还包含特定量的至少一种选自（C1）聚酯类树脂，（C2）聚酰胺类树脂，（C3） 丙烯酸树脂，（C4）聚碳酸酯类树脂，（C5）聚缩醛类树脂，（C6）聚苯醚系树脂，（C7）聚烯烃类树脂和（C8）苯乙烯类树脂。

公开(公告)号：US20070208114A1

公开(公告)日：2007-09-06

申请号：US11628536

申请日：2005-06-03

申请人： Masaaki Mawatari ,  Sung-Ho Lee ,  Young-Ho Choi

发明人： Masaaki Mawatari ,  Sung-Ho Lee ,  Young-Ho Choi

IPC分类号： C08K5/34 ,  C08K9/04

CPC分类号： C08K5/0066 ,  C08F279/02 ,  C08K3/04 ,  C08K3/346 ,  C08K5/34928 ,  C08K5/5419 ,  C08L51/04 ,  C08L71/02 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/02

摘要： The present invention provides a flame retardant resin composition comprising the following component (A), component (B), component (C) and component (D), in which 0.1 to 50 parts by mass of the component (B), 0.001 to 30 parts by mass of the component (C) and 0.1 to 50 parts by mass of the component (D) are blended with 100 parts by mass of the component (A). Component (A): A rubber-modified styrene resin obtained by (co)polymerizing an aromatic vinyl compound or an aromatic vinyl compound and another vinyl monomer copolymerizable with the aromatic vinyl compound in a presence of a rubber-like polymer; Component (B): A thermally expandable graphite; Component (C): A layered clay material modified by a water-soluble polymer; and Component (D): At least one selected from the group consisting of silicone compounds, boron oxides, aminotriazine sulfate compounds and aminotriazine compounds. The resin composition is excellent in flame retardance and impact resistance.

摘要翻译： 本发明提供一种阻燃性树脂组合物，其包含以下成分（A），成分（B），成分（C）和成分（D），其中，成分（B）为0.1〜50质量份 （C）成分质量份和成分（D）0.1〜50质量份与100质量份成分（A）共混。 组分（A）：在橡胶状聚合物的存在下，通过（共）聚合芳族乙烯基化合物或芳香族乙烯基化合物和可与芳族乙烯基化合物共聚的乙烯基单体得到的橡胶改性苯乙烯树脂; 组分（B）：热膨胀石墨; 组分（C）：由水溶性聚合物改性的层状粘土材料; 和组分（D）：选自硅氧烷化合物，氧化硼，氨基三嗪硫酸盐化合物和氨基三嗪化合物中的至少一种。 树脂组合物的阻燃性和耐冲击性优异。

公开(公告)号：US5216074A

公开(公告)日：1993-06-01

申请号：US552303

申请日：1990-07-13

申请人： Takateru Imai ,  Masanobu Nagano ,  Masaaki Mawatari ,  Toshio Teramoto ,  Minoru Hasegawa

发明人： Takateru Imai ,  Masanobu Nagano ,  Masaaki Mawatari ,  Toshio Teramoto ,  Minoru Hasegawa

IPC分类号： C08L21/00 ,  C08L51/00 ,  C08L53/00 ,  C08L53/02 ,  C08L67/02

CPC分类号： C08L53/005 ,  C08C19/02 ,  C08L21/00 ,  C08L51/00 ,  C08L51/006 ,  C08L53/025 ,  C08L67/02 ,  C08L9/00 ,  C08L53/02 ,  C08L77/00 ,  C08L9/06

摘要： A thermoplastic elastomer composition comprising 99-1 parts by weight of (i) a hydrogenated diene polymer which is a hydrogenation product of a straight or branched chain block copolymer consisting of (C) a polybutadiene block segment having a 1,2-vinyl content of not more than 20% and (D) a block segment which is a polybutadiene or an alkenyl aromatic compound-butadiene copolymer, the butadiene portion of which has a 1,2-vinyl content of 25-95% and 1-99 parts by weight of (ii) at least one of a thermoplastic resin or a rubbery polymer.

公开(公告)号：US4742115A

公开(公告)日：1988-05-03

申请号：US762828

申请日：1985-08-06

申请人： Masaaki Mawatari ,  Syuji Tsuchikawa ,  Shinichi Kimura ,  Nobuyuki Katsuki ,  Mitsuo Abe

发明人： Masaaki Mawatari ,  Syuji Tsuchikawa ,  Shinichi Kimura ,  Nobuyuki Katsuki ,  Mitsuo Abe

IPC分类号： C08L25/12 ,  C08L51/04 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L71/00 ,  C08L71/12 ,  C08L77/00 ,  C08L81/00 ,  C08L81/02 ,  C08L81/06 ,  C08L71/04

CPC分类号： C08L25/12 ,  C08L51/04 ,  C08L71/123 ,  C08L2205/02 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L71/00 ,  C08L71/12 ,  C08L77/00 ,  C08L81/00 ,  C08L81/02 ,  C08L81/06 ,  Y10S525/905

摘要： A heat resistant thermoplastic resin composition comprising (a) 5 to 99% by weight of a poly(phenylene ether), (b) 95 to 1% by weight of a thermoplastic resin which is obtained by polymerizing in the absence of a rubber-like polymer a resin constituent mixture comprising an aromatic alkenyl compound, an alkenyl cyanide compound, and, if necessary, other alkenyl monomers copolymerizable with said monomers, and (c) up to 94% by weight of other styrenic resins, said thermoplastic resin (b) comprising (A) 1-50% by weight of a polymer having an alkenyl cyanide compound content of 1% by weight or more but less than 10% by weight, (B) 1-70% by weight of a polymer having an alkenyl cyanide compound content of 10% by weight or more but less than 20% by weight, (C) 5-90% by weight of a polymer having an alkenyl cyanide compound content of 20% by weight or more but less than 40% by weight, and (D) up to 70% by weight of a polymer having an alkenyl cyanide compound content of 40% by weight or more, and having a total alkenyl cyanide compound content of 10 to 40% by weight and an intrinsic viscosity of preferably 0.1- 1.5 dl/g as measured in methyl ethyl ketone at 30.degree. C. The above thermoplastic resin composition is excellent in not only heat resistance but also impact resistance, thermal stability, painting, and surface gloss of molded article.

摘要翻译： 一种耐热性热塑性树脂组合物，其包含（a）5至99重量％的聚（苯醚），（b）95至1重量％的热塑性树脂，其通过在不存在橡胶状的情况下聚合而获得 聚合物包含芳族烯基化合物，链烯基氰化物化合物和必要时可与所述单体共聚的其它链烯基单体的树脂组合物混合物，和（c）最多94重量％的其它苯乙烯类树脂，所述热塑性树脂（b） 包含（A）1-50重量％的链烯基氰化合物含量为1重量％以上但小于10重量％的聚合物，（B）1-70重量％的具有链烯基氰的聚合物 化合物含量为10重量％以上但小于20重量％，（C）5-氰基氰化合物含量为20重量％以上但小于40重量％的聚合物的5-90重量％ 和（D）至多70重量％的链烯基氰化合物含量为40重量％以上的聚合物 ，并且在30℃下，在甲基乙基酮中测定的全部链烯基氰化合物含量为10〜40重量％，特性粘度优选为0.1〜1.5dl / g。上述热塑性树脂组合物不仅具有优异的热 耐冲击性，也具有耐冲击性，热稳定性，喷涂性和表面光泽度。

公开(公告)号：US08653188B2

公开(公告)日：2014-02-18

申请号：US12593397

申请日：2008-05-08

申请人： Tatsuya Toneri ,  Masaaki Mawatari

发明人： Tatsuya Toneri ,  Masaaki Mawatari

IPC分类号： C08L51/06 ,  C08L67/00 ,  C08L67/04

CPC分类号： C08L55/02 ,  C08F297/02 ,  C08F297/04 ,  C08L25/04 ,  C08L25/12 ,  C08L25/14 ,  C08L51/04 ,  C08L67/02 ,  C08L67/04 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

摘要： The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load.The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.The above (BI) is a graft copolymer obtained by polymerizing vinyl-based monomers (b2) comprising an aromatic vinyl compound and another vinyl compound copolymerizable therewith in the presence of rubber polymer (b1), the above (BII) is a polymer of vinyl-based monomers (b2), and the above (BIII) is a mixture of said (BI) and (BII).

摘要翻译： 本发明的目的是提供耐冲击性，断裂形态和刚性优异的热塑性聚合物组合物，并且具有降低环境负荷的可能性。 热塑性树脂组合物含有15〜85质量％的包含以下（AI）和（AII）成分的脂肪族聚酯系树脂（A）和15〜85质量％的苯乙烯系树脂（B） 至少一种选自下列（BI）至（BIII）组。 上述（AI）是具有由脂肪族二醇和/或脂环族二醇和脂肪族二羧酸（包括其衍生物）和/或作为重复单元的脂环族二羧酸（包括其衍生物）形成的单元的脂肪族聚酯类树脂， 上述（AII）是乳酸单元含量不小于70mol％的聚乳酸类脂肪族聚酯树脂。 上述（BI）是通过在橡胶聚合物（b1）的存在下使包含芳族乙烯基化合物和可与其共聚的其它乙烯基化合物的乙烯基类单体（b2）聚合而获得的接枝共聚物，上述（BII）是乙烯基 （b2）和上述（BIII）是所述（BI）和（BII）的混合物。

公开(公告)号：US20100152384A1

公开(公告)日：2010-06-17

申请号：US12593397

申请日：2008-05-08

申请人： Tatsuya Toneri ,  Masaaki Mawatari

发明人： Tatsuya Toneri ,  Masaaki Mawatari

IPC分类号： C08L51/06 ,  C08L77/00

CPC分类号： C08L55/02 ,  C08F297/02 ,  C08F297/04 ,  C08L25/04 ,  C08L25/12 ,  C08L25/14 ,  C08L51/04 ,  C08L67/02 ,  C08L67/04 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

摘要： The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load.The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.The above (BI) is a graft copolymer obtained by polymerizing vinyl-based monomers (b2) comprising an aromatic vinyl compound and another vinyl compound copolymerizable therewith in the presence of rubber polymer (b1), the above (BII) is a polymer of vinyl-based monomers (b2), and the above (BIII) is a mixture of said (BI) and (BII).

摘要翻译： 本发明的目的是提供耐冲击性，断裂形态和刚性优异的热塑性聚合物组合物，并且具有降低环境负荷的可能性。 热塑性树脂组合物含有15〜85质量％的包含以下（AI）和（AII）成分的脂肪族聚酯系树脂（A）和15〜85质量％的苯乙烯系树脂（B） 至少一种选自下列（BI）至（BIII）组。 上述（AI）是具有由脂肪族二醇和/或脂环族二醇和脂肪族二羧酸（包括其衍生物）和/或作为重复单元的脂环族二羧酸（包括其衍生物）形成的单元的脂肪族聚酯类树脂， 上述（AII）是乳酸单元含量不小于70mol％的聚乳酸类脂肪族聚酯树脂。 上述（BI）是通过在橡胶聚合物（b1）的存在下使包含芳族乙烯基化合物和可与其共聚的其它乙烯基化合物的乙烯基类单体（b2）聚合而获得的接枝共聚物，上述（BII）是乙烯基 （b2）和上述（BIII）是所述（BI）和（BII）的混合物。