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    Thermoplastic polymer composition and molded product
    2.
    发明授权
    Thermoplastic polymer composition and molded product 有权
    热塑性聚合物组合物和模制产品

    公开(公告)号：US08084538B2

    公开(公告)日：2011-12-27

    申请号：US12359472

    申请日：2009-01-26

    申请人： Masaaki Mawatari ,  Tatsuya Toneri

    发明人： Masaaki Mawatari ,  Tatsuya Toneri

    IPC分类号： C08L67/04 ,  C08L77/00 ,  C08L83/04

    CPC分类号： C08L67/02 ,  C08L25/04 ,  C08L33/00 ,  C08L59/00 ,  C08L67/025 ,  C08L69/00 ,  C08L71/12 ,  C08L75/08 ,  C08L77/00 ,  C08L87/005 ,  C08L2666/02 ,  C08L67/00

    摘要： The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B1) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass. In the preferred embodiment of the present invention, the thermoplastic polymer composition further comprises a specific amount of at least one polymer selected from the group consisting of (C1) a polyester-based resin, (C2) a polyamide-based resin, (C3) an acrylic resin, (C4) a polycarbonate-based resin, (C5) a polyacetal-based resin, (C6) a polyphenylene ether-based resin, (C7) a polyolefin-based resin and (C8) a styrene-based resin.

    摘要翻译： 本发明提供能够表现出优异的耐冲击性，耐久性和去静电性能的热塑性聚合物组合物。 本发明涉及一种热塑性聚合物组合物，其包含（A）50〜95质量％的脂肪族聚酯类树脂和（B）5〜50质量％的嵌段共聚物，所述嵌段共聚物包含（B1）硬链段， 选自聚酰胺，聚酯，聚烯烃和聚氨酯的至少一种聚合物和（B2）具有醚键的软链段，条件是组分（A）和（B）的总量 ）为100质量％。 在本发明的优选实施方案中，热塑性聚合物组合物还包含特定量的至少一种选自（C1）聚酯类树脂，（C2）聚酰胺类树脂，（C3） 丙烯酸树脂，（C4）聚碳酸酯类树脂，（C5）聚缩醛类树脂，（C6）聚苯醚系树脂，（C7）聚烯烃类树脂和（C8）苯乙烯类树脂。

    THERMOPLASTIC POLYMER COMPOSITION AND MOLDED PRODUCT
    4.
    发明申请
    THERMOPLASTIC POLYMER COMPOSITION AND MOLDED PRODUCT 有权
    热塑性聚合物组合物和成型产品

    公开(公告)号：US20090171023A1

    公开(公告)日：2009-07-02

    申请号：US12359472

    申请日：2009-01-26

    申请人： Masaaki Mawatari ,  Tatsuya Toneri

    发明人： Masaaki Mawatari ,  Tatsuya Toneri

    IPC分类号： C08L53/00 ,  C08L67/00

    CPC分类号： C08L67/02 ,  C08L25/04 ,  C08L33/00 ,  C08L59/00 ,  C08L67/025 ,  C08L69/00 ,  C08L71/12 ,  C08L75/08 ,  C08L77/00 ,  C08L87/005 ,  C08L2666/02 ,  C08L67/00

    摘要： The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass. In the preferred embodiment of the present invention, the thermoplastic polymer composition further comprises a specific amount of at least one polymer selected from the group consisting of (C1) a polyester-based resin, (C2) a polyamide-based resin, (C3) an acrylic resin, (C4) a polycarbonate-based resin, (C5) a polyacetal-based resin, (C6) a polyphenylene ether-based resin, (C7) a polyolefin-based resin and (C8) a styrene-based resin.

    摘要翻译： 本发明提供能够表现出优异的耐冲击性，耐久性和去静电性能的热塑性聚合物组合物。 本发明涉及一种热塑性聚合物组合物，其包含（A）50〜95质量％的脂肪族聚酯类树脂和（B）5〜50质量％的嵌段共聚物，所述嵌段共聚物包含（B）硬链段， 选自聚酰胺，聚酯，聚烯烃和聚氨酯的至少一种聚合物和（B2）具有醚键的软链段，条件是组分（A）和（B）的总量 ）为100质量％。 在本发明的优选实施方案中，热塑性聚合物组合物还包含特定量的至少一种选自（C1）聚酯类树脂，（C2）聚酰胺类树脂，（C3） 丙烯酸树脂，（C4）聚碳酸酯类树脂，（C5）聚缩醛类树脂，（C6）聚苯醚系树脂，（C7）聚烯烃类树脂和（C8）苯乙烯类树脂。

    Thermoplastic resin composition and resin molded product
    5.
    发明授权
    Thermoplastic resin composition and resin molded product 失效
    热塑性树脂组合物和树脂模塑制品

    公开(公告)号：US08653188B2

    公开(公告)日：2014-02-18

    申请号：US12593397

    申请日：2008-05-08

    申请人： Tatsuya Toneri ,  Masaaki Mawatari

    发明人： Tatsuya Toneri ,  Masaaki Mawatari

    IPC分类号： C08L51/06 ,  C08L67/00 ,  C08L67/04

    CPC分类号： C08L55/02 ,  C08F297/02 ,  C08F297/04 ,  C08L25/04 ,  C08L25/12 ,  C08L25/14 ,  C08L51/04 ,  C08L67/02 ,  C08L67/04 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load.The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.The above (BI) is a graft copolymer obtained by polymerizing vinyl-based monomers (b2) comprising an aromatic vinyl compound and another vinyl compound copolymerizable therewith in the presence of rubber polymer (b1), the above (BII) is a polymer of vinyl-based monomers (b2), and the above (BIII) is a mixture of said (BI) and (BII).

    摘要翻译： 本发明的目的是提供耐冲击性，断裂形态和刚性优异的热塑性聚合物组合物，并且具有降低环境负荷的可能性。 热塑性树脂组合物含有15〜85质量％的包含以下（AI）和（AII）成分的脂肪族聚酯系树脂（A）和15〜85质量％的苯乙烯系树脂（B） 至少一种选自下列（BI）至（BIII）组。 上述（AI）是具有由脂肪族二醇和/或脂环族二醇和脂肪族二羧酸（包括其衍生物）和/或作为重复单元的脂环族二羧酸（包括其衍生物）形成的单元的脂肪族聚酯类树脂， 上述（AII）是乳酸单元含量不小于70mol％的聚乳酸类脂肪族聚酯树脂。 上述（BI）是通过在橡胶聚合物（b1）的存在下使包含芳族乙烯基化合物和可与其共聚的其它乙烯基化合物的乙烯基类单体（b2）聚合而获得的接枝共聚物，上述（BII）是乙烯基 （b2）和上述（BIII）是所述（BI）和（BII）的混合物。

    THERMOPLASTIC RESIN COMPOSITION AND RESIN MOLDED PRODUCT
    6.
    发明申请
    THERMOPLASTIC RESIN COMPOSITION AND RESIN MOLDED PRODUCT 失效
    热塑性树脂组合物和树脂模制产品

    公开(公告)号：US20100152384A1

    公开(公告)日：2010-06-17

    申请号：US12593397

    申请日：2008-05-08

    申请人： Tatsuya Toneri ,  Masaaki Mawatari

    发明人： Tatsuya Toneri ,  Masaaki Mawatari

    IPC分类号： C08L51/06 ,  C08L77/00

    CPC分类号： C08L55/02 ,  C08F297/02 ,  C08F297/04 ,  C08L25/04 ,  C08L25/12 ,  C08L25/14 ,  C08L51/04 ,  C08L67/02 ,  C08L67/04 ,  C08L2205/02 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

    摘要： The object of the present invention is to provide a thermoplastic polymer composition which is excellent in the impact resistance, a fracture morphology and rigidity, as well as has a possibility of the effect for reducing environmental load.The thermoplastic resin composition comprises 15 to 85% by mass of aliphatic polyester-based resin (A) comprising the following (AI) and (AII) components, and 15 to 85% by mass of styrene-based resin (B) which is at least one selected from the group consisting of the following (BI) to (BIII). The above (AI) is an aliphatic polyester-based resin having units formed from an aliphatic diol and/or an alicyclic diol and an aliphatic dicarboxylic acid (including derivatives thereof) and/or an alicyclic dicarboxylic (including derivatives thereof) as repeating units, and the above (AII) is a polylactic acid-based aliphatic polyester resin having not less than 70 mol % of lactic acid unit content.The above (BI) is a graft copolymer obtained by polymerizing vinyl-based monomers (b2) comprising an aromatic vinyl compound and another vinyl compound copolymerizable therewith in the presence of rubber polymer (b1), the above (BII) is a polymer of vinyl-based monomers (b2), and the above (BIII) is a mixture of said (BI) and (BII).

    摘要翻译： 本发明的目的是提供耐冲击性，断裂形态和刚性优异的热塑性聚合物组合物，并且具有降低环境负荷的可能性。 热塑性树脂组合物含有15〜85质量％的包含以下（AI）和（AII）成分的脂肪族聚酯系树脂（A）和15〜85质量％的苯乙烯系树脂（B） 至少一种选自下列（BI）至（BIII）组。 上述（AI）是具有由脂肪族二醇和/或脂环族二醇和脂肪族二羧酸（包括其衍生物）和/或作为重复单元的脂环族二羧酸（包括其衍生物）形成的单元的脂肪族聚酯类树脂， 上述（AII）是乳酸单元含量不小于70mol％的聚乳酸类脂肪族聚酯树脂。 上述（BI）是通过在橡胶聚合物（b1）的存在下使包含芳族乙烯基化合物和可与其共聚的其它乙烯基化合物的乙烯基类单体（b2）聚合而获得的接枝共聚物，上述（BII）是乙烯基 （b2）和上述（BIII）是所述（BI）和（BII）的混合物。

    THERMOPLASTIC RESIN COMPOSITION AND RESIN MOLDED PRODUCT
    7.
    发明申请
    THERMOPLASTIC RESIN COMPOSITION AND RESIN MOLDED PRODUCT 审中-公开
    热塑性树脂组合物和树脂模制产品

    公开(公告)号：US20100105836A1

    公开(公告)日：2010-04-29

    申请号：US12442732

    申请日：2007-09-27

    申请人： Masaaki Mawatari ,  Tatsuya Toneri

    发明人： Masaaki Mawatari ,  Tatsuya Toneri

    IPC分类号： C08L53/02

    CPC分类号： C08L53/02 ,  C08L23/02 ,  C08L23/142 ,  C08L51/04 ,  C08L51/06 ,  C08L53/00 ,  C08L53/025 ,  C08L67/00 ,  C08L67/02 ,  C08L2666/24 ,  C08L2666/18 ,  C08L2666/06 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/02

    摘要： The present invention provides a thermoplastic resin composition excellent in impact resistance, delamination resistance and surface appearanceThe present invention relates to a thermoplastic resin composition comprising: 5 to 95% by mass of an aliphatic polyester (A), 4 to 94% by mass of an olefin-based resin (B) and 1 to 40% by mass of an aromatic vinyl-based polymer (C) where the total amount of component (A), component (B) and component (C) is 100% by mass, the aromatic vinyl-based polymer (C) being at least one selected from: an aromatic vinyl-based polymer (C1) which is an elastomer comprising a block copolymer comprising a polymer block mainly comprising an aromatic vinyl compound and a polymer block mainly comprising a conjugated diene compound, an aromatic vinyl-based polymer (C2) which is an elastomer obtained by hydrogenation of the aromatic vinyl-based polymer (C1), and an aromatic vinyl-based polymer (C3) which is a graft copolymer obtained by polymerizing a vinyl-based monomer containing an aromatic vinyl compound in the presence of an olefin-based polymer.

    摘要翻译： 本发明提供耐冲击性，耐分层性和表面外观优异的热塑性树脂组合物。本发明涉及一种热塑性树脂组合物，其特征在于，含有5〜95质量％的脂肪族聚酯（A），4〜94质量％ 烯烃类树脂（B）和1〜40质量％的成分（A），成分（B）和成分（C）的总量为100质量％的芳香族乙烯基系聚合物（C） 所述芳族乙烯基类聚合物（C）为选自以下的至少一种：作为弹性体的芳香族乙烯基系聚合物（C1），所述弹性体含有包含主要包含芳族乙烯基化合物的聚合物嵌段的嵌段共聚物和主要包含芳香族乙烯基聚合物的聚合物嵌段 共轭二烯化合物，作为通过芳香族乙烯基类聚合物（C1）氢化得到的弹性体的芳香族乙烯基系聚合物（C2）和作为通过使芳香族乙烯基系聚合物（C1）聚合而得到的接枝共聚物的芳香族乙烯基类聚合物（C3） 基于乙烯基的m 在烯烃类聚合物存在下，含有芳香族乙烯基化合物的端基单体。

    Sulfonyloxime compound, and radiation sensitive acid generator, positive type radiation sensitive resin composition and negative type radiation sensitive resin composition using same
    9.
    发明授权
    Sulfonyloxime compound, and radiation sensitive acid generator, positive type radiation sensitive resin composition and negative type radiation sensitive resin composition using same 有权
    磺酰肟化合物和辐射敏感酸产生剂，正型辐射敏感树脂组合物和负型辐射敏感树脂组合物使用

    公开(公告)号：US06824954B2

    公开(公告)日：2004-11-30

    申请号：US10226348

    申请日：2002-08-23

    申请人： Eiji Yoneda ,  Tatsuya Toneri ,  Yong Wang ,  Tsutomu Shimokawa

    发明人： Eiji Yoneda ,  Tatsuya Toneri ,  Yong Wang ,  Tsutomu Shimokawa

    IPC分类号： G03F7039

    CPC分类号： G03F7/0382 ,  G03F7/0045 ,  G03F7/0392 ,  Y10S430/115 ,  Y10S430/12 ,  Y10S430/122

    摘要： A sulfonyloxime compound is provided which is represented by a general formula (1): wherein, R1 represents a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group; R2 represents an alkyl group, an aryl group, or a heteroaryl group; X represents a halogen atom; Y represents —R3, a —CO—R3 group, —COO—R3 group, —CONR3R4 group, —S—R3 group, —SO—R3 group, —SO2—R3 group, a —CN group or a —NO2 group, and R3 and R4 within the Y group each represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group, although any two of R1, R2 and R3 may also be bonded together to form a cyclic structure, and furthermore dimers of a compound represented by the general formula (1) in which R1, R2 or Y groups from separate molecules are bonded together to form a single bivalent group, are also possible. This compound is very useful as a radiation sensitive acid generator which is sensitive to activated radiation such as far ultraviolet radiation or electron beams and the like, and displays superior heat stability and storage stability. Furthermore, chemically amplified positive type or negative type radiation sensitive resin compositions incorporating such a radiation sensitive acid generator are also provided.

    摘要翻译： 提供由通式（1）表示的磺酰肟化合物：其中，R 1表示氢原子，烷基，芳基或杂芳基; R 2表示烷基，芳基或杂芳基; X表示卤原子; Y表示-R 3，-CO-R 3基团，-COO-R 3基团，-CONR 3 R 4基团，-SR 3基团，-SO-R 3基团， 3个基团，-SO 2 -R 3基团，-CN基团或-NO 2基团，Y基团中的R 3和R 4各自表示氢原子，烷基，芳基 或杂芳基，尽管R 1，R 2和R 3中的任何两个也可以键合在一起形成环状结构，此外由通式（1）表示的化合物的二聚体在 来自分离的分子的R 1，R 2或Y基团结合在一起形成单个二价基团也是可能的。 该化合物作为辐射敏感的酸产生剂是非常有用的，其对诸如远紫外线辐射或电子束等的活化辐射敏感，并且显示出优异的热稳定性和储存稳定性。 此外，还提供了掺入这种辐射敏感性酸发生剂的化学放大阳性或负型辐射敏感性树脂组合物。