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公开(公告)号：US09504980B2
公开(公告)日：2016-11-29
申请号：US13637243
申请日：2011-03-14
IPC分类号： C08L33/20 , B01J13/14 , C08J9/32 , B01J13/18 , C08F283/10
CPC分类号： B01J13/14 , B01J13/185 , C08F283/10 , C08J9/32 , C08J2201/024 , C08J2203/22 , C08J2300/22 , C08F220/44 , C08F220/06
摘要： The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.
摘要翻译： 本发明提供一种热膨胀性微胶囊，其即使在高温下也保持高膨胀率且几乎不会发生爆裂和收缩，使用该热膨胀性微胶囊制造的可发泡热塑性树脂母料和发泡成型体， 热膨胀微胶囊。 热膨胀性微胶囊包含作为核心试剂的外壳中含有的挥发性膨胀剂，由聚合物形成的壳，含有热固性树脂的壳和可通过聚合含有腈型单体和单体的单体组合物得到的聚合物 具有羧基，所述热固性树脂不具有自由基聚合性双键和至少两个与每个分子具有羧基反应的官能团。
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2.发明申请THERMALLY EXPANDABLE MICROCAPSULE AND PROCESS FOR PRODUCTION OF THERMALLY EXPANDABLE MICROCAPSULE 审中-公开热膨胀微生物的热膨胀微生物和生产方法公开(公告)号：US20130085192A1
公开(公告)日：2013-04-04
申请号：US13637462
申请日：2011-03-03
CPC分类号： C08L33/26 , B01J13/14 , C08F220/44 , C08F220/56 , C08L33/20
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing methacrylic monomer and an amide group-containing methacrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing methacrylic monomer and an ester group-containing methacrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, a weight ratio of the monomer A and the monomer B being 5:5 to 9:1, and the monomer mixture containing methacrylonitrile and methacrylic acid in a total amount of not more than 70% by weight of the monomer mixture.
摘要翻译： 本发明提供耐热性和耐久性优异的热膨胀性微胶囊。 本发明是一种热可膨胀微胶囊，其包含含有共聚物的壳和包含在壳中的作为核心试剂的挥发性液体，该共聚物可通过含有单体A和单体B的单体混合物的聚合获得， 单体A是选自含腈基的甲基丙烯酸单体和含酰胺基的甲基丙烯酸单体中的至少一种，单体B是选自含羧基的甲基丙烯酸单体和 含有酯基的甲基丙烯酸单体，单体A和单体B的总量占单体混合物的70重量％以上，单体A和单体B的重量比为5:5〜9:1 ，并且含有甲基丙烯腈和甲基丙烯酸的单体混合物的总量不超过单体混合物的70重量％。
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公开(公告)号：US20130303639A1
公开(公告)日：2013-11-14
申请号：US13976629
申请日：2011-12-28
IPC分类号： C08L63/00
CPC分类号： C08L63/00 , C08G59/40 , C08J9/32 , C08J2203/22 , C08J2205/052 , C08J2300/22 , C08J2300/26 , C08J2353/02 , C08J2423/06 , C08J2463/00
摘要： The present invention provides a resin composition for foam molding which can achieve high expansion ratio and can significantly improve tactile impression and vibration damping properties of the foam molding to be obtained.The present invention relates to a resin composition for foam molding comprising: a thermally expandable microcapsule that includes a shell containing an epoxy resin and a core agent that is a volatile expansion agent encapsulated by the shell; a thermoplastic resin; and a curable compound having two or more functional groups each selected from the group consisting of a carboxy group, a hydroxy group, an amino group, an amido group, and an acid anhydride group in each molecule.
摘要翻译： 本发明提供一种发泡成型用树脂组合物，其能够实现高膨胀率，能够显着提高要获得的发泡成型体的触感和振动阻尼性。 泡沫塑料用树脂组合物技术领域本发明涉及发泡成型用树脂组合物，其特征在于，包括含有环氧树脂的外壳和由壳包封的挥发性膨胀剂的芯剂的热膨胀性微胶囊， 热塑性树脂; 以及在各分子中具有选自羧基，羟基，氨基，酰胺基和酸酐基的两个以上官能团的固化性化合物。
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4.发明申请THERMALLY EXPANDABLE MICROCAPSULE, METHOD FOR PRODUCING THERMALLY EXPANDABLE MICROCAPSULE, FOAMABLE MASTERBATCH, AND FOAM MOLDED ARTICLE 有权热膨胀微生物，生产热膨胀微球的方法，可泡沫主板和泡沫塑料制品公开(公告)号：US20130065976A1
公开(公告)日：2013-03-14
申请号：US13637216
申请日：2011-03-03
CPC分类号： B01J13/14 , C08F220/44 , C08F220/56
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability and exhibits an excellent foaming property in a wide temperature range from low temperatures to high temperatures. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing acrylic monomer and an amide group-containing acrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing acrylic monomer and an ester group-containing acrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, and a weight ratio of the monomer A and the monomer B being 5:5 to 9:1.
摘要翻译： 本发明提供耐热性和耐久性优异的热膨胀性微胶囊，并且在从低温到高温的宽温度范围内具有优异的发泡性。 本发明是一种热可膨胀微胶囊，其包含含有共聚物的壳和包含在壳中的作为核心试剂的挥发性液体，该共聚物可通过含有单体A和单体B的单体混合物的聚合获得， 单体A是选自含有腈基的丙烯酸类单体和含酰胺基的丙烯酸类单体中的至少一种，单体B是选自含羧基的丙烯酸类单体和 含有酯基的丙烯酸类单体，单体A和单体B的总量占单体混合物的70重量％以上，单体A和单体B的重量比为5：5〜9： 1。
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公开(公告)号：US09776157B2
公开(公告)日：2017-10-03
申请号：US13637216
申请日：2011-03-03
IPC分类号： C08L33/08 , C08J9/16 , C08L33/26 , C08L33/02 , C08L33/10 , C08L33/20 , B01J13/14 , C08F220/44 , C08F220/56
CPC分类号： B01J13/14 , C08F220/44 , C08F220/56
摘要： The present invention provides a thermally expandable microcapsule that is excellent in heat resistance and durability and exhibits an excellent foaming property in a wide temperature range from low temperatures to high temperatures. The present invention is a thermally expandable microcapsule, which comprises a shell containing a copolymer, and a volatile liquid as a core agent included in the shell, the copolymer being obtainable by polymerization of a monomer mixture containing a monomer A and a monomer B, the monomer A being at least one selected from the group consisting of a nitrile group-containing acrylic monomer and an amide group-containing acrylic monomer, the monomer B being at least one selected from the group consisting of a carboxyl group-containing acrylic monomer and an ester group-containing acrylic monomer, a total amount of the monomer A and the monomer B accounting for 70% by weight or more of the monomer mixture, and a weight ratio of the monomer A and the monomer B being 5:5 to 9:1.
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公开(公告)号：US20130184362A1
公开(公告)日：2013-07-18
申请号：US13820800
申请日：2011-09-01
IPC分类号： C08J9/228
CPC分类号： C08J9/228 , C08J9/0066 , C08J9/06 , C08J9/32 , C08J2201/024 , C08J2203/02 , C08J2203/04 , C08J2203/10 , C08J2203/22 , C08J2300/22 , C08J2323/06
摘要： The present invention aims to provide a foamable resin composition which enables foam molding at high expansion ratios and reduction of open cells. The present invention also aims to provide a foam molded body produced from the foamable resin composition. The present invention is a foamable resin composition including a thermoplastic resin, thermal expansion microcapsules, and a chemical foaming agent, wherein Ts is not lower than 120° C., Tmax is not lower than 190° C., and Ts-Tc is not lower than −30° C. and not higher than 6° C., where Ts denotes a foaming starting temperature of the thermal expansion microcapsules, Tmax denotes a maximum foaming temperature of the thermal expansion microcapsules, and Tc denotes a decomposition temperature of the chemical foaming agent.
摘要翻译： 本发明的目的在于提供一种发泡性树脂组合物，其能够以高膨胀率进行发泡成型并使开孔减少。 本发明的目的还在于提供一种由发泡性树脂组合物制成的发泡成型体。 本发明是一种发泡性树脂组合物，其包含热塑性树脂，热膨胀微胶囊和化学发泡剂，其中Ts不低于120℃，Tmax不低于190℃，Ts-Tc不为 低于-30℃且不高于6℃，其中Ts表示热膨胀微胶囊的发泡起始温度，Tmax表示热膨胀微胶囊的最大发泡温度，Tc表示化学品的分解温度 发泡剂。
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公开(公告)号：US20130065975A1
公开(公告)日：2013-03-14
申请号：US13637243
申请日：2011-03-14
IPC分类号： C08L33/20
CPC分类号： B01J13/14 , B01J13/185 , C08F283/10 , C08J9/32 , C08J2201/024 , C08J2203/22 , C08J2300/22 , C08F220/44 , C08F220/06
摘要： The present invention provides a thermally expandable microcapsule that maintains a high expansion ratio and hardly bursts and shrinks even at a high temperature, a foamable thermoplastic resin masterbatch and a foam molded product that are produced using the thermally expandable microcapsule, and a method for producing the thermally expandable microcapsule. The thermally expandable microcapsule comprises a volatile expansion agent included in a shell as a core agent and the shell formed of a polymer, the shell containing a thermosetting resin and a polymer obtainable by polymerization of a monomer composition containing a nitrile-type monomer and a monomer having a carboxyl group, and the thermosetting resin having no radical-polymerizable double bond and at least two functional groups reactive with a carboxyl group per molecule.
摘要翻译： 本发明提供一种热膨胀性微胶囊，其即使在高温下也保持高膨胀率且几乎不会发生爆裂和收缩，使用该热膨胀性微胶囊制造的可发泡热塑性树脂母料和发泡成型体， 热膨胀微胶囊。 热膨胀性微胶囊包含作为核心试剂的外壳中含有的挥发性膨胀剂，由聚合物形成的壳，含有热固性树脂的壳和可通过聚合含有腈型单体和单体的单体组合物得到的聚合物 具有羧基，所述热固性树脂不具有自由基聚合性双键和至少两个与每个分子具有羧基反应的官能团。
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8.发明授权Modified conjugated diene rubber, method for producing same, and rubber composition 有权改性共轭二烯橡胶，其制造方法和橡胶组合物公开(公告)号：US09434792B2
公开(公告)日：2016-09-06
申请号：US14114123
申请日：2012-04-17
申请人： Hiroyuki Morita , Masahiro Shibata , Ryoji Tanaka
发明人： Hiroyuki Morita , Masahiro Shibata , Ryoji Tanaka
CPC分类号： C08C19/25 , B60C1/00 , B60C1/0016 , C08C19/44 , C08K3/04 , C08K3/36 , C08L9/00 , C08L15/00 , C08L91/00
摘要： A method containing a step of reacting a conjugated diene polymer having an alkali metal or alkaline earth metal active end with a hydrocarbyloxysilane compound having one or more of each of the following functional groups I and II in its molecule to obtain a modified conjugated diene polymer containing a functional group II, and a step of mixing the modified conjugated diene polymer and a compound such as organic acid. A modified conjugated diene rubber which can be used as a raw material of a cross-linked rubber which can be used in tire treads and the like and can enhance low fuel consumption performance is provided. The functional group I is a hydrocarbyloxysilyl group. The functional group II is a nitrogen-containing group in which both of two hydrogen atoms of a primary amino group are substituted with protective groups.
摘要翻译： 一种方法，包括使具有碱金属或碱土金属活性末端的共轭二烯聚合物与其分子中具有以下官能团I和II中的一个或多个的烃氧基硅烷化合物反应以获得包含以下官能团的改性共轭二烯聚合物的步骤： 官能团II和混合改性共轭二烯聚合物和有机酸等化合物的工序。 提供了可用作轮胎胎面等中可用于提高低燃料消耗性能的交联橡胶的原料的改性共轭二烯橡胶。 官能团I是烃氧基甲硅烷基。 官能团II是其中伯氨基的两个氢原子都被保护基团取代的含氮基团。
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公开(公告)号：US08986568B2
公开(公告)日：2015-03-24
申请号：US13637559
申请日：2011-03-31
申请人： Hiroyuki Morita , Yoshihiko Minachi , Takahiro Mori , Tatsuya Kato , Nobuhiro Suto , Naoto Oji
发明人： Hiroyuki Morita , Yoshihiko Minachi , Takahiro Mori , Tatsuya Kato , Nobuhiro Suto , Naoto Oji
CPC分类号： C22C33/0278 , B22F3/225 , B22F2998/10 , H01F1/11 , H01F7/021 , H01F41/0266 , B22F9/04 , B22F3/1021
摘要： The present invention aims to ensure strength of a thin-walled sintered magnet. A sintered magnet is a ferrite sintered magnet made by sintering a magnetic material. A magnetic powder mixture obtained by mixing magnetic powder with a binder resin is injection-molded into a mold with a magnetic field applied thereto to produce a molded body, which is then sintered to produce the sintered magnet. The sintered magnet has a thickness of 3.5 mm or less in the position of center of gravity thereof. The sintered magnet has a surface roughness Rz of 0.1 μm or more and 2.5 μm or less. The surface roughness Rz is a 10 point average roughness.
摘要翻译： 本发明旨在确保薄壁烧结磁体的强度。 烧结磁体是通过烧结磁性材料制成的铁氧体烧结磁体。 将磁粉与粘合剂树脂混合得到的磁性粉末混合物注射成型为具有施加磁场的模具，制成成形体，然后烧结而制成烧结磁体。 该烧结磁体的重心位置的厚度为3.5mm以下。 烧结磁体的表面粗糙度Rz为0.1μm以上且2.5μm以下。 表面粗糙度Rz为10点平均粗糙度。
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公开(公告)号：US20090292936A1
公开(公告)日：2009-11-26
申请号：US12470296
申请日：2009-05-21
IPC分类号： G06F1/26
摘要： A microcomputer includes: a CPU executing a predetermined calculation process; and a PWM timer generating a PWM pulse. The PWM timer includes a RAM for storing a duty value of the PWM pulse and a PWM controller for generating the PWM pulse. The PWM controller includes a PWM counter for counting up from a predetermined value as an initial value. The PWM pulse has an unit waveform, which is generated based on comparison between the duty value of the RAM and an output value of the PWM counter. The RAM outputs a new duty value at every comparison without functioning the CPU so that the duty value of the PWM pulse is changed in chronological order.
摘要翻译： 微型计算机包括：执行预定计算处理的CPU; 以及产生PWM脉冲的PWM定时器。 PWM定时器包括用于存储PWM脉冲的占空比值的RAM和用于产生PWM脉冲的PWM控制器。 PWM控制器包括用于从预定值向上计数作为初始值的PWM计数器。 PWM脉冲具有基于RAM的占空比与PWM计数器的输出值之间的比较而产生的单位波形。 RAM在每次比较时都会输出一个新的占空比值，而不会使CPU运行，从而PWM脉冲的占空比按时间顺序改变。
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