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    Multilayer structure having a layer based on polyamide and on HDPE
    1.
    发明申请
    Multilayer structure having a layer based on polyamide and on HDPE 审中-公开
    具有基于聚酰胺和HDPE层的多层结构

    公开(公告)号：US20060008604A1

    公开(公告)日：2006-01-12

    申请号：US11154422

    申请日：2005-06-16

    申请人： Jean-Jacques Flat ,  Gaelle Bellet ,  Benoit Brule ,  Philippe Blondel

    发明人： Jean-Jacques Flat ,  Gaelle Bellet ,  Benoit Brule ,  Philippe Blondel

    IPC分类号： B65D1/00

    CPC分类号： B32B27/32 ,  Y10T428/1341 ,  Y10T428/1383

    摘要： The present invention relates to a structure successively comprising: a first layer of high density polyethylene (HDPE), a tie layer, a second layer of EVOH or of a blend based on EVOH, optionally a tie layer, a third layer of a blend comprising, by weight, the total being 100%: 50 to 90% of polyamide (A) having a conversion temperature of at most 230° C., 1 to 30% of high density polyethylene (HDPE), 5 to 30% of an impact modifier chosen from elastomers and very low density polyethylenes, at least one of the HDPE and of the impact modifier being functionalized, in all or part, the layers being coextrudable. The present invention also relates to devices for the transfer or storage of fluids and more particularly to pipes, tanks, conduits, bottles and containers composed of the above structure in which the layer of the blend of polyamide (A) and of HDPE is in direct contact with the fluid present or transported

    摘要翻译： 本发明涉及一种结构，其连续包括：第一层高密度聚乙烯（HDPE），粘结层，第二层EVOH或基于EVOH的共混物，任选的粘结层，第三层共混物，包括 ，总重量为100％：转化温度为230℃以下的聚酰胺（A）为50〜90％，高密度聚乙烯（HDPE）为1〜30％，冲击强度为5〜30％ 选自弹性体和非常低密度聚乙烯的改性剂，HDPE和抗冲改性剂中的至少一种在全部或部分中被共同挤出。 本发明还涉及用于转移或储存流体的装置，更具体地涉及由上述结构组成的管，罐，导管，瓶和容器，其中聚酰胺（A）和HDPE的共混物层直接 与存在或运输的液体接触

    POLYAMIDE-BASED ANTISTATIC MULTILAYER TUBE FOR TRANSFERRING FLUIDS
    2.
    发明申请
    POLYAMIDE-BASED ANTISTATIC MULTILAYER TUBE FOR TRANSFERRING FLUIDS 审中-公开
    用于转移流体的基于聚酰胺的抗静电多层管

    公开(公告)号：US20090314375A1

    公开(公告)日：2009-12-24

    申请号：US12090756

    申请日：2006-10-17

    申请人： Jean-Jacques Flat ,  Gaelle Bellet ,  Nicolas Amouroux ,  Benoit Brule

    发明人： Jean-Jacques Flat ,  Gaelle Bellet ,  Nicolas Amouroux ,  Benoit Brule

    IPC分类号： F16L11/127

    CPC分类号： B32B27/32 ,  B32B1/08 ,  B32B27/08 ,  B32B27/306 ,  B32B27/34 ,  B32B2270/00 ,  B32B2597/00 ,  F16L11/045 ,  F16L2011/047

    摘要： The present invention relates to a multilayer tube comprising, in succession in its radial direction from the outside inwards: a nylon-11 or nylon-12 polyamide outer layer (1); a tie layer (2); an optional EVOH layer (3); an optional layer (4) made of PA-6 or a PA-6/polyolefin blend having a PA-6 matrix and polyolefin dispersed phase; an inner layer (5) based on PA-6 in contact with the transported fluid, comprising by weight, the total being 100%: 40 to 65% (advantageously 45 to 60%) of PA-6, 1 to 20% (advantageously 5 to 15%) of HDPE, 10 to 30% (advantageously 15 to 25%) of at least one polymer P1 chosen from impact modifiers and polyethylenes, either or both of the HDPE and the P1 being completely or partly functionalized and 5 to 30% (advantageously 15 to 30% and preferably 17 to 24%) of an electrically conductive material. The tube of the present invention has a very low permeability to petrol, particularly to hydrocarbons and to their additives, in particular alcohols such as methanol and ethanol or else ethers such as MTBE or ETBE. These tubes also have a very good resistance to fuels and lubricating oils for engines.This tube has very good mechanical properties at low temperature or at high temperature. The invention also relates to the use of these tubes for transporting petrol.

    摘要翻译： 本发明涉及一种多层管，其从外向内径向连续地包括：尼龙11或尼龙-12聚酰胺外层（1）; 连结层（2）; 可选的EVOH层（3）; 由PA-6制成的任选的层（4）或具有PA-6基体和聚烯烃分散相的PA-6 /聚烯烃共混物; 基于与所输送的流体接触的PA-6的内层（5），其包含重量百分比为100％：PA-6的40至65％（有利地为45至60％），1至20％ 5至15％）的HDPE，10至30％（有利地为15至25％）的选自抗冲改性剂和聚乙烯的至少一种聚合物P1，HDPE和P1中的任一种或两者完全或部分官能化，并且5至30 ％（有利地为15〜30％，优选为17〜24％）的导电性材料。 本发明的管具有非常低的汽油渗透性，特别是对烃及其添加剂，特别是醇如甲醇和乙醇，或醚如MTBE或ETBE的渗透性极低。 这些管也对发动机的燃料和润滑油具有非常好的抵抗力。 该管在低温或高温下具有非常好的机械性能。 本发明还涉及这些管用于运输汽油的用途。

    Polyamide and polyolefin blends with a polyamide matrix and containing nanofillers
    7.
    发明申请
    Polyamide and polyolefin blends with a polyamide matrix and containing nanofillers 失效
    聚酰胺和聚烯烃共混物与聚酰胺基质并含有纳米填料

    公开(公告)号：US20060100375A1

    公开(公告)日：2006-05-11

    申请号：US11301153

    申请日：2005-12-12

    申请人： Jean-Jacques Flat ,  Benoit Barriere ,  Benoit Brule

    发明人： Jean-Jacques Flat ,  Benoit Barriere ,  Benoit Brule

    IPC分类号： C08L77/00 ,  C08K9/04 ,  C08F8/30 ,  C08K3/34

    CPC分类号： C08L77/02 ,  B29C37/0075 ,  B32B27/20 ,  B32B27/34 ,  C08L23/0815 ,  C08L23/10 ,  C08L51/06 ,  C08L77/00 ,  C08L77/06 ,  C08L2205/08 ,  C08L2666/20 ,  C08L2666/06 ,  C08L2666/24

    摘要： The present invention relates to polyamide (A) and polyolefin (B) blends containing nanofillers in which the polyamide forms the matrix. These blends can also be referred to as “polyamide (A), polyolefin (B) and nanofiller blends in which the polyamide forms the matrix”. The invention also relates to structures with barrier properties comprising at least one layer of these blends and optionally at least one layer of another material. These structures are a barrier to numerous fluids, and in particular to oxygen, to styrene, to fumigation fluids, to pentane and to air conditioning fluids. These structures can be made into bottles, reservoirs, containers, pipes and vessels of all sorts. They can also be converted to films which are used to make packagings.

    摘要翻译： 本发明涉及含有纳米填料的聚酰胺（A）和聚烯烃（B）共混物，其中聚酰胺形成基质。 这些共混物也可以称为“聚酰胺（A），聚烯烃（B）和纳米填料共混物，其中聚酰胺形成基体”）。 本发明还涉及具有阻挡性质的结构，其包含至少一层这些共混物和任选的至少一层其它材料。 这些结构是许多流体，特别是氧气，苯乙烯，熏蒸流体，戊烷和空调流体的障碍。 这些结构可以制成各种瓶子，水箱，容器，管道和各种容器。 它们也可以转换成用于制造包装的胶片。

    Flexible high thermomechanical stress-resistant and fireproof halogen-free thermoplastic compositions
    8.
    发明授权
    Flexible high thermomechanical stress-resistant and fireproof halogen-free thermoplastic compositions 有权
    柔软的高机械耐热和耐火无卤素热塑性组合物

    公开(公告)号：US07897673B2

    公开(公告)日：2011-03-01

    申请号：US12303174

    申请日：2007-06-01

    申请人： Jean-Jacques Flat ,  Philippe Blondel ,  David Meslet

    发明人： Jean-Jacques Flat ,  Philippe Blondel ,  David Meslet

    IPC分类号： C08K3/32 ,  C08K3/34

    CPC分类号： C09K21/12 ,  C08G81/028 ,  C08L23/02 ,  C09D5/18 ,  C09K21/04 ,  H01B7/295 ,  H01R13/527 ,  C08L2666/20

    摘要： The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves. Said compositions are particularly useful for making electric cables, electric components, for molding electrotechnical housings, or for making coating layers or thermal protection sleeves for fluid transfer lines in the automotive industry.

    摘要翻译： 本发明涉及柔性高的热机械应力阻力和阻燃无卤热塑性组合物，其包含由树干和平均至少一个聚酰胺接枝物组成的聚酰胺嵌段共聚物共聚物，其中移植物通过残留物 具有能够在胺末端与聚酰胺反应的功能的不饱和单体（X），不饱和单体残基（X）通过从其双键接枝或共聚而结合在树干上。 本发明的特征在于，所述组合物包含混合物：50至70wt。 ％的聚酰胺嵌段共聚物，25〜35重量％ 选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂的百分比为约2重量％ ％的沸石或水分子分子筛。 所述组合物特别可用于制造用于汽车工业中的流体输送线的电缆，用于模制电工技术外壳的电气部件或用于制造涂层或热保护套管。

    Polyamide- and polyolefin-based fire-retarded compositions
    9.
    发明授权
    Polyamide- and polyolefin-based fire-retarded compositions 失效
    聚酰胺和聚烯烃类阻燃组合物

    公开(公告)号：US07235604B2

    公开(公告)日：2007-06-26

    申请号：US10602005

    申请日：2003-06-24

    申请人： Philippe Blondel ,  Benoît Brule ,  Nicolas Frenois ,  Jean-Jacques Flat

    发明人： Philippe Blondel ,  Benoît Brule ,  Nicolas Frenois ,  Jean-Jacques Flat

    IPC分类号： C08K5/523

    CPC分类号： C08L77/00 ,  C08L23/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/10 ,  C08L51/06 ,  C08L77/02 ,  C08L77/06 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/84 ,  C08L51/00 ,  C08L23/00

    摘要： The present invention relates to fire-retarded compositions comprising, by weight, the total being 100 parts: 50 to 75 parts of a blend of a polyamide (A) and a polyolefin (B), 25 to 50 parts of a blend comprising: 0.1 to 48.8 parts of a fire retardant, 0.1 to 30 parts of a phosphorus-containing plasticizer, 0.1 to 10 parts of a zeolite, the total of these three products being between 25 and 50. These compositions have a V0 or V1 classification according to the UL94-VB test when a fire test is carried out on test specimens 1.6 mm in thickness. They have many advantages, in particular the elongation at break measured according to ISO R 527-1B exceeds 100%. As regards the impact strength, they have a non-brittle behaviour in multiaxial impact at room temperature according to ISO 6603-2 (at a rate of 7.7 m/s). They retain at least 50% of their mechanical properties after ageing for seven days at 120° C. in hot air. These compositions are useful for insulating and protecting electrical cables and optical fibres and for moulding electrical cases and connectors.

    摘要翻译： 本发明涉及阻燃组合物，其包含总重量为100份：50至75份聚酰胺（A）和聚烯烃（B）的共混物，25至50份共混物，其包含：0.1 至48.8份阻燃剂，0.1至30份含磷增塑剂，0.1至10份沸石，这三种产品的总量在25-50之间。这些组合物具有根据本发明的V0或V1分类 对在1.6mm厚的试样进行耐火试验时，进行UL94-VB试验。 它们具有许多优点，特别是根据ISO R 527-1B测量的断裂伸长率超过100％。 关于冲击强度，根据ISO 6603-2（以7.7m / s的速率）在室温下在多轴冲击中具有非脆性。 它们在120℃下在热空气中老化7天后，保持其机械性能的至少50％。 这些组合物可用于绝缘和保护电缆和光纤以及用于模制电气外壳和连接器。