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公开(公告)号：US07799962B2
公开(公告)日：2010-09-21
申请号：US12208011
申请日：2008-09-10
申请人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose′ Guadalupe Santiesteban , Lei Zhang
发明人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose′ Guadalupe Santiesteban , Lei Zhang
IPC分类号： C07C2/68
CPC分类号： C07C2/864 , B01J29/40 , B01J29/44 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2521/10 , C07C2523/42 , C07C2523/46 , C07C2527/14 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08 , C07C15/00
摘要： This invention relates to a process for the selective alkylation of toluene and/or benzene with an oxygen-containing alkylation agent. In particular, the process uses a selectivated molecular sieve which has been modified by the addition of a hydrogenation component, wherein at least one of the following conditions is met: (a) the selectivated molecular sieve has an alpha value of less than 100 prior to the addition of the hydrogenation component, or (b) the selectivated and hydrogenated catalyst has an alpha value of less than 100. The process of this invention provides high selectivity for the alkylated product while reducing catalyst degradation.
摘要翻译： 本发明涉及用含氧烷基化剂选择性烷基化甲苯和/或苯的方法。 特别地，该方法使用已经通过加入氢化组分进行了改性的选择性分子筛，其中符合以下条件中的至少一个：（a）选择性分子筛之前的α值小于100， 氢化组分的添加，或（b）选择和氢化的催化剂具有小于100的α值。本发明的方法在减少催化剂降解的同时，对烷基化产物提供高选择性。
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公开(公告)号：US20090012338A1
公开(公告)日：2009-01-08
申请号：US12208011
申请日：2008-09-10
申请人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose' Guadalupe Santiesteban , Lei Zhang
发明人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose' Guadalupe Santiesteban , Lei Zhang
IPC分类号： C07C2/64
CPC分类号： C07C2/864 , B01J29/40 , B01J29/44 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2521/10 , C07C2523/42 , C07C2523/46 , C07C2527/14 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08 , C07C15/00
摘要： This invention relates to a process for the selective alkylation of toluene and/or benzene with an oxygen-containing alkylation agent. In particular, the process uses a selectivated molecular sieve which has been modified by the addition of a hydrogenation component, wherein at least one of the following conditions is met: (a) the selectivated molecular sieve has an alpha value of less than 100 prior to the addition of the hydrogenation component, or (b) the selectivated and hydrogenated catalyst has an alpha value of less than 100. The process of this invention provides high selectivity for the alkylated product while reducing catalyst degradation.
摘要翻译： 本发明涉及用含氧烷基化剂选择性烷基化甲苯和/或苯的方法。 特别地，该方法使用已经通过加入氢化组分进行了改性的选择性分子筛，其中符合以下条件中的至少一个：（a）选择性分子筛之前的α值小于100， 氢化组分的添加，或（b）选择和氢化的催化剂具有小于100的α值。本发明的方法在减少催化剂降解的同时，对烷基化产物提供高选择性。
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公开(公告)号：US07453018B2
公开(公告)日：2008-11-18
申请号：US10987324
申请日：2004-11-12
申请人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose′ Guadalupe Santiesteban , Lei Zhang
发明人： Jihad Mohammed Dakka , John Scott Buchanan , Robert Andrew Crane , Christine Nicole Elia , Xiaobing Feng , Larry Lee Iaccino , Gary David Mohr , Brenda Anne Raich , Jose′ Guadalupe Santiesteban , Lei Zhang
IPC分类号： C07C2/66
CPC分类号： C07C2/864 , B01J29/40 , B01J29/44 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2521/10 , C07C2523/42 , C07C2523/46 , C07C2527/14 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08 , C07C15/00
摘要： This invention relates to a process for the selective alkylation of toluene and/or benzene with an oxygen-containing alkylation agent. In particular, the process uses a selectivated molecular sieve which has been modified by the addition of a hydrogenation component, wherein at least one of the following conditions is met: (a) the selectivated molecular sieve has an alpha value of less than 100 prior to the addition of the hydrogenation component, or (b) the selectivated and hydrogenated catalyst has an alpha value of less than 100. The process of this invention provides high selectivity for the alkylated product while reducing catalyst degradation.
摘要翻译： 本发明涉及用含氧烷基化剂选择性烷基化甲苯和/或苯的方法。 特别地，该方法使用已经通过加入氢化组分进行了改性的选择性分子筛，其中符合以下条件中的至少一个：（a）选择性分子筛之前的α值小于100， 氢化组分的添加，或（b）选择和氢化的催化剂具有小于100的α值。本发明的方法在减少催化剂降解的同时，对烷基化产物提供高选择性。
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4.发明申请METHODS FOR PRODUCING BASESTOCKS FROM RENEWABLE SOURCES USING DEWAXING CATALYST 审中-公开使用漂白催化剂从可再生来源生产基质的方法公开(公告)号：US20140275688A1
公开(公告)日：2014-09-18
申请号：US14196035
申请日：2014-03-04
申请人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partridge , Kun Wang , Lei Zhang , Christine Nicole Elia , Jenna Lynn Walp
发明人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partridge , Kun Wang , Lei Zhang , Christine Nicole Elia , Jenna Lynn Walp
IPC分类号： C10G3/00
CPC分类号： C10G3/50 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , Y02P30/20
摘要： Provided are methods for producing a lube base stock and/or a fuel from a feedstock of biological origin, the method including: contacting the feedstock in the presence of a catalyst to produce a lube base stock and/or a fuel, wherein the catalyst comprises: a zeolite component selected from a zeolite having 10-member ring pores, a zeolite having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component.
摘要翻译： 提供了从生物来源的原料生产润滑油基础油料和/或燃料的方法，该方法包括：在催化剂存在下使原料接触以制备润滑油基础油料和/或燃料，其中催化剂包含 ：选自具有10元环孔的沸石的沸石成分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co，Mo的氢化成分 ，W，Rh，Re，Ru，Ir及其混合物，以及水热稳定的粘合剂组分。
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公开(公告)号：US09433936B2
公开(公告)日：2016-09-06
申请号：US14196019
申请日：2014-03-04
申请人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partidge , Kun Wang , Lei Zhang , Christine Nicole Elia
发明人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partidge , Kun Wang , Lei Zhang , Christine Nicole Elia
IPC分类号： B01J29/06 , B01J29/76 , B01J29/12 , B01J29/74 , B01J29/14 , B01J29/44 , B01J29/46 , B01J29/78 , C10G45/64 , C10G45/02 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/62 , C10G3/00 , B01J37/00
CPC分类号： B01J29/7661 , B01J29/12 , B01J29/126 , B01J29/14 , B01J29/44 , B01J29/46 , B01J29/7415 , B01J29/7461 , B01J29/7492 , B01J29/7615 , B01J29/7815 , B01J29/7861 , B01J37/0009 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G3/44 , C10G3/47 , C10G3/48 , C10G3/50 , C10G45/02 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , Y02P30/20
摘要： Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.
摘要翻译： 提供的催化剂包括：选自具有10元环孔的沸石的沸石组分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co的氢化组分 ，Mo，W，Rh，Re，Ru，Ir及其混合物，以及选自氧化钽，氧化钨，氧化钼，氧化钒，氧化镁，氧化钙，氧化钇，氧化镧，铈的水热稳定的粘合剂成分 氧化物，氧化铌，钨酸氧化锆，钴钼氧化物，钴硫化钼，镍钼氧化物，镍钼硫化物，镍钨氧化物，镍硫化钨，钴钨氧化物，硫化钴硫化物，镍钼钨氧化物和镍钼硫化钨， 钴钼氧化钨和钴钼硫化钨，其中沸石与水热稳定粘合剂的重量比为85:15至25:75。
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公开(公告)号：US20100187156A1
公开(公告)日：2010-07-29
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
IPC分类号： C10G69/02
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译： 提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。 在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。
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公开(公告)号：US20140274664A1
公开(公告)日：2014-09-18
申请号：US14196019
申请日：2014-03-04
申请人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partidge , Kun Wang , Lei Zhang , Christine Nicole Elia
发明人： Scott J. Weigel , Joseph Emmanuel Gatt , Darryl Donald Lacy , Randall D. Partidge , Kun Wang , Lei Zhang , Christine Nicole Elia
CPC分类号： B01J29/7661 , B01J29/12 , B01J29/126 , B01J29/14 , B01J29/44 , B01J29/46 , B01J29/7415 , B01J29/7461 , B01J29/7492 , B01J29/7615 , B01J29/7815 , B01J29/7861 , B01J37/0009 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G3/44 , C10G3/47 , C10G3/48 , C10G3/50 , C10G45/02 , C10G45/06 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , Y02P30/20
摘要： Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.
摘要翻译： 提供的催化剂包括：选自具有10元环孔的沸石的沸石组分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co的氢化组分 ，Mo，W，Rh，Re，Ru，Ir及其混合物，以及选自氧化钽，氧化钨，氧化钼，氧化钒，氧化镁，氧化钙，氧化钇，氧化镧，铈的水热稳定的粘合剂成分 氧化物，氧化铌，钨酸氧化锆，钴钼氧化物，钴硫化钼，镍钼氧化物，镍钼硫化物，镍钨氧化物，镍硫化钨，钴氧化钨，钴硫化钨，镍钼钨氧化物和镍钼硫化钨， 钴钼氧化钨和钴钼硫化钨，其中沸石与水热稳定粘合剂的重量比为85:15至25:75。
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公开(公告)号：US08366908B2
公开(公告)日：2013-02-05
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译： 提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。 在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。 可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。
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公开(公告)号：US07524990B2
公开(公告)日：2009-04-28
申请号：US10587207
申请日：2005-02-01
申请人： Michael Siskin , Alan Roy Katritzky , Kostyantyn Mykolayevich Kirichenko , Adeana Richelle Bishop , Christine Nicole Elia
发明人： Michael Siskin , Alan Roy Katritzky , Kostyantyn Mykolayevich Kirichenko , Adeana Richelle Bishop , Christine Nicole Elia
IPC分类号： C07C209/22
CPC分类号： C07C213/02 , C07C45/89 , C07C49/88 , C07C217/08
摘要： Severely sterically hindered secondary aminoether alcohols are prepared by reacting organic carboxylic, organic carboxylic acid halides, acid anhydrides or a ketene with an alkyl, alkaryl or alkylhalo sulfonate to yield a sulfonic-carboxylic anhydride compound which is then reacted with a dioxane to cleave the ring of the dioxane, yielding a cleavage product which cleavage product is then aminated with an alkylamine and hydrolyzed with base to yield the severely sterically hindered secondary aminoether alcohol.
摘要翻译： 通过使有机羧酸，有机羧酸卤化物，酸酐或烯酮与烷基，烷基芳基或烷基卤代磺酸反应制得极度空间位阻的仲氨基醚醇，得到磺酸羧酸酐化合物，然后与二恶烷反应以切割环 的二恶烷，产生裂解产物，然后将裂解产物用烷基胺胺化并用碱水解，得到严重空间位阻的仲氨基醚醇。
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10.发明授权公开(公告)号：US07351865B2
公开(公告)日：2008-04-01
申请号：US10587199
申请日：2005-02-01
申请人： Michael Siskin , Alan Roy Katritzky , Kostyantyn Mykolayevich Kirichenko , Adeana Richelle Bishop , Christine Nicole Elia
发明人： Michael Siskin , Alan Roy Katritzky , Kostyantyn Mykolayevich Kirichenko , Adeana Richelle Bishop , Christine Nicole Elia
IPC分类号： C07C209/00 , C07D213/00 , C07D213/02 , C07D213/08
CPC分类号： C07C213/08 , C07C217/08
摘要： Severely sterically hindered secondary aminoether alcohols are prepared by reacting acid anhydrides or organic carboxylic acid halides with SO3 to yield a sulfonic carboxylic anhydride compound which is then reacted with a dioxane to cleave the ring of the dioxane yielding a cleavage product which is then aminated with an alkylamine and hydrolyzed with a base to yield the severely sterically hindered secondary aminoether alcohol.
摘要翻译： 通过使酸酐或有机羧酸卤化物与SO 3 3反应制备严格的空间位阻的仲氨基醚醇，得到磺酸酐化合物，然后与二恶烷反应以切割二烷环，产生 裂解产物然后用烷基胺胺化并用碱水解，得到严重位阻的仲氨基醚醇。
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