公开(公告)号：US08815970B2

公开(公告)日：2014-08-26

申请号：US13241165

申请日：2011-09-22

申请人： Jing-Zhong Hwang ,  Guei-Jia Chang ,  Jhong-Jheng Lin ,  Cheng-Wei Tsai ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen ,  Kan-Nan Chen

发明人： Jing-Zhong Hwang ,  Guei-Jia Chang ,  Jhong-Jheng Lin ,  Cheng-Wei Tsai ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen ,  Kan-Nan Chen

IPC分类号： A61K31/355 ,  C08J3/28 ,  C08G71/04 ,  D06M15/564

CPC分类号： B05D3/067 ,  B05D1/18 ,  C08G71/04 ,  D06M10/001 ,  D06M10/10 ,  D06M15/564

摘要： A method of preparing polyurethane prepolymer does not require using a toxic isocyanate monomer (manufactured by harmful phosgene) as a raw material. Epoxy resin and carbon dioxide are used as major raw materials to form cyclic carbonates to be reacted with a functional group oligomer, and then amino groups in a hydrophilic (ether group) or hydrophobic (siloxane group) diamine polymer are used for performing a ring-opening polymerization, and the microwave irradiation is used in the ring-opening polymerization to efficiently synthesize the amino-terminated PU prepolymer, and then an acrylic group at an end is added to manufacture an UV cross-linking PU (UV-PU) oligomer which can be coated onto a fabric surface, and the fabric is dried by UV radiation for a surface treatment to form a washing-resisted long lasting hydrophilic or hydrophobic PU fabric.

摘要翻译： 制备聚氨酯预聚物的方法不需要使用有毒的异氰酸酯单体（由有害光气制造）作为原料。 使用环氧树脂和二氧化碳作为与官能团低聚物反应的环状碳酸酯的主要原料，然后使用亲水（醚基）或疏水（硅氧烷基）二胺聚合物中的氨基进行环 - 开环聚合，并且在开环聚合中使用微波照射以有效合成氨基封端的PU预聚物，然后加入末端的丙烯酸基以制备UV交联PU（UV-PU）低聚物，其中 可以涂布在织物表面上，并且织物通过UV辐射干燥以进行表面处理以形成耐洗涤的持久的亲水或疏水PU织物。

公开(公告)号：US08053488B2

公开(公告)日：2011-11-08

申请号：US11969877

申请日：2008-01-04

申请人： Jing-Zhong Hwang ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen

发明人： Jing-Zhong Hwang ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen

IPC分类号： C08F2/50 ,  C08G18/10 ,  B32B27/16 ,  B32B27/40

CPC分类号： C08G18/672 ,  C08G18/0823 ,  C08G18/0828 ,  C08G18/12 ,  C08G18/3855 ,  C08G18/6685 ,  C08G18/6692 ,  C08G18/755 ,  C08J3/28 ,  C08J2375/04 ,  C09D175/04 ,  C09D175/16 ,  Y10T428/31551 ,  C08G18/305

摘要： An ambient temperature curable hydrophilic PU oligomer includes a PU pre-polymer having a hydrophilic center group and a curable terminated group. The ambient temperature curable hydrophilic PU oligomer includes the moisture-curable hydrophilic PU oligomer such as isocyanate-terminated PU pre-polymer and free-radical curable hydrophlic PU oligomer. The isocyanate-terminated PU pre-polymer is synthesized by mixing at least one multi-isocyanate, at least one polyol and one or more diol monomer with hydrophilic group. The acrylate-terminated PU oligomer is synthesized by adding 2-hydroxyethyl methacrylate (HEMA) into the isocyanate-terminated hydrophilic PU pre-polymer. Either acrylate- or isocyanate-terminated PU oligomer can be applied on a textile or a glass surface with a thin-layer coating technology. The curing reactions of these hydrophilic thin-layer coatings are carried out with moisture or UV-radiation, respectively, at ambient temperature. These moisture-cured or UV-radiation cured hydrophilic PU coating has water-resistant properties and the hydrophilic characters remain unchanged.

摘要翻译： 环境温度可固化的亲水PU低聚物包括具有亲水中心基团和可固化封端基团的PU预聚物。 环境温度可固化的亲水PU低聚物包括可湿固化的亲水PU低聚物，例如异氰酸酯封端的PU预聚物和可自由基固化的亲水PU低聚物。 通过将至少一种多异氰酸酯，至少一种多元醇和一种或多种二醇单体与亲水基团混合来合成异氰酸酯封端的PU预聚物。 通过向异氰酸酯封端的亲水PU预聚物中加入甲基丙烯酸2-羟乙酯（HEMA）来合成丙烯酸酯封端的PU低聚物。 丙烯酸酯或异氰酸酯封端的PU低聚物可以用薄层涂布技术涂覆在织物或玻璃表面上。 这些亲水性薄层涂层的固化反应分别在环境温度下用水分或UV辐射进行。 这些湿固化或UV辐射固化的亲水PU涂层具有防水性能，亲水性能保持不变。

公开(公告)号：US20080194723A1

公开(公告)日：2008-08-14

申请号：US11969877

申请日：2008-01-04

申请人： Jing-Zhong HWANG ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen

发明人： Jing-Zhong HWANG ,  Shih-Chieh Wang ,  Po-Cheng Chen ,  Kan-Nan Chen

IPC分类号： C08F2/46 ,  C08G18/02 ,  C08J3/28

CPC分类号： C08G18/672 ,  C08G18/0823 ,  C08G18/0828 ,  C08G18/12 ,  C08G18/3855 ,  C08G18/6685 ,  C08G18/6692 ,  C08G18/755 ,  C08J3/28 ,  C08J2375/04 ,  C09D175/04 ,  C09D175/16 ,  Y10T428/31551 ,  C08G18/305

摘要： An ambient temperature curable hydrophilic PU oligomer includes a PU pre-polymer having a hydrophilic center group and a curable terminated group. The ambient temperature curable hydrophilic PU oligomer includes the moisture-curable hydrophilic PU oligomer such as isocyanate-terminated PU pre-polymer and free-radical curable hydrophlic PU oligomer. The isocyanate-terminated PU pre-polymer is synthesized by mixing at least one multi-isocyanate, at least one polyol and one or more diol monomer with hydrophilic group. The acrylate-terminated PU oligomer is synthesized by adding 2-hydroxyethyl methacrylate (HEMA) into the isocyanate-terminated hydrophilic PU pre-polymer. Either acrylate- or isocyanate-terminated PU oligomer can be applied on a textile or a glass surface with a thin-layer coating technology. The curing reactions of these hydrophilic thin-layer coatings are carried out with moisture or UV-radiation, respectively, at ambient temperature. These moisture-cured or UV-radiation cured hydrophilic PU coating has water-resistant properties and the hydrophilic characters remain unchanged.

摘要翻译： 环境温度可固化的亲水PU低聚物包括具有亲水中心基团和可固化封端基团的PU预聚物。 环境温度可固化的亲水PU低聚物包括可湿固化的亲水PU低聚物，例如异氰酸酯封端的PU预聚物和可自由基固化的亲水PU低聚物。 通过将至少一种多异氰酸酯，至少一种多元醇和一种或多种二醇单体与亲水基团混合来合成异氰酸酯封端的PU预聚物。 通过向异氰酸酯封端的亲水PU预聚物中加入甲基丙烯酸2-羟乙酯（HEMA）来合成丙烯酸酯封端的PU低聚物。 丙烯酸酯或异氰酸酯封端的PU低聚物可以用薄层涂布技术涂覆在织物或玻璃表面上。 这些亲水性薄层涂层的固化反应分别在环境温度下用水分或UV辐射进行。 这些湿固化或UV辐射固化的亲水PU涂层具有防水性能，亲水性能保持不变。

公开(公告)号：US20070299211A1

公开(公告)日：2007-12-27

申请号：US11478676

申请日：2006-07-03

申请人： Po-Cheng Chen ,  Shih-Chieh Wang ,  Chia-Yu Huang ,  Kan-Nan Chen

发明人： Po-Cheng Chen ,  Shih-Chieh Wang ,  Chia-Yu Huang ,  Kan-Nan Chen

IPC分类号： C08F120/02

CPC分类号： C08G73/02 ,  C08L79/02

摘要： Self-polymerization of mono-aziridine (or azetidine) and multi-aziridine (or azetidine) containing compounds with vinyl group containing organic acid, such as acrylic acid (AA), 2-methylenesuccinic acid, 2,3-dimethylenesuccinic acid and etc, at ambient temperature results in the new type of cross-linked and linear type copolymers, respectively.The polymerization of multi-functional aziridine (or azetidine) containing compounds with vinyl group containing organic acid results in the formation of high cross-linked polymers. The self-polymerization takes place at ambient temperature and the resultants, cross-linked polymeric networked materials, are solvent insoluble and potential for adhesive, composite matrix and other applications. These insoluble materials are hydrolyzed in an acidic or basic condition to form the water soluble β-amino acids.A linear poly(β-aminoester) is obtained from the self-polymerization of vinyl group containing organic acid with mono-aziridine (or azetidine) containing compound at ambient temperature. poly(β-aminoester) is applicable for gene transfer, controlled drug release and other applications. This self-polymerization process offers a convenient route for preparing poly(β-aminoesters).

摘要翻译： 含有丙烯酸（AA），2-甲基琥珀酸，2,3-二甲基琥珀酸等有机酸的含有乙烯基的单氮杂环丁烷（或氮杂环丁烷）和多氮丙啶（或氮杂环丁烷） 在环境温度下分别导致了新型的交联和线型共聚物。 含有含乙烯基的有机酸的含多官能氮丙啶（或氮杂环丁烷）化合物的聚合导致形成高交联聚合物。 自聚合在环境温度下进行，并且所得的交联聚合物网络材料是溶剂不溶性的，并且具有粘合剂，复合基质和其它应用的潜力。 这些不溶物质在酸性或碱性条件下水解以形成水溶性β-氨基酸。 由含乙烯基的有机酸与单氮丙啶（或氮杂环丁烷）化合物在环境温度下的自聚合得到线性聚（β-氨基酯）。 聚（β-氨基酯）适用于基因转移，受控药物释放和其他应用。 这种自聚合方法提供了制备聚（β-氨基酯）的方便途径。

公开(公告)号：US20120108741A1

公开(公告)日：2012-05-03

申请号：US13281729

申请日：2011-10-26

申请人： Rei-Xin Wu ,  Jing-Zhong Hwang ,  Wei-Hung Chen ,  Kan-Nan Chen

发明人： Rei-Xin Wu ,  Jing-Zhong Hwang ,  Wei-Hung Chen ,  Kan-Nan Chen

IPC分类号： C09D175/04

CPC分类号： C09D175/04 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/4854 ,  C08G18/6692 ,  C08G18/2885

摘要： An ambient-temperature self-curable fluorine containing aqueous-based polyurethane dispersion, a method of manufacturing the same and its modified coated film applications are provided. The ambient-temperature self-curable fluorine containing aqueous-based PU dispersion includes water, an ambient temperature cross-linking agent and a fluorine containing PU resin dispersed in water phase. The fluorine containing PU resin includes A includes octa-fluoropentanol, hexafluoroisopropanol, trifluoroethanol, tetrafluoropropanol or trifluoroethylamine.Treated fabric with the self-cured fluorine containing aqueous-based PU resin and it becomes a long-lasting water-repellent and stain-proof.

摘要翻译： 提供环境温度可自固化含氟水性聚氨酯分散体，其制造方法及其改性涂膜用途。 环境温度可固化含氟水性PU分散液包括水，环境温度交联剂和分散在水相中的含氟PU树脂。 含氟PU树脂包括A包括八氟代戊醇，六氟异丙醇，三氟乙醇，四氟丙醇或三氟乙胺。 经处理的含自来水含氟水性PU树脂的织物，具有长久的防水防污性能。

公开(公告)号：US6077960A

公开(公告)日：2000-06-20

申请号：US440245

申请日：1999-11-15

申请人： Hao-Jan Ling ,  Kan-Nan Chen ,  Jian-Zei Lai ,  Yun-Shan Lin

发明人： Hao-Jan Ling ,  Kan-Nan Chen ,  Jian-Zei Lai ,  Yun-Shan Lin

IPC分类号： C07D403/14 ,  C08G18/02 ,  C08G18/08 ,  C08G18/12 ,  C08G18/28 ,  C08G18/80

CPC分类号： C07D403/14 ,  C08G18/027 ,  C08G18/0823 ,  C08G18/12 ,  C08G18/2865

摘要： A novel uretedione derivative used as a curing agent for aqueous-based polyurethane and a process for producing the same are disclosed. The uretedione derivative contains uretedione and aziridine functional groups which are active toward the amino and the carboxy groups of hydrolyzed polyurethane in an aqueous phase.

摘要翻译： 公开了一种用作水基聚氨酯固化剂的新型脲二酮衍生物及其制备方法。 脲二酮衍生物含有在水相中对水解的聚氨酯的氨基和羧基具有活性的脲二酮和氮丙啶官能团。

公开(公告)号：US20090065732A1

公开(公告)日：2009-03-12

申请号：US11853140

申请日：2007-09-11

申请人： Jen-Taut Yeh ,  Li-Chun Yu ,  Kan-Nan Chen ,  Han-Hsing Hsiung

发明人： Jen-Taut Yeh ,  Li-Chun Yu ,  Kan-Nan Chen ,  Han-Hsing Hsiung

IPC分类号： C04B35/18

CPC分类号： A61L9/22 ,  A01N59/00 ,  A61L2/23 ,  B01J20/10 ,  B01J20/20 ,  B01J20/26 ,  B01J20/28026 ,  B01J2220/42 ,  B01J2220/46 ,  C04B26/02 ,  C04B2103/0076 ,  C04B2103/0097 ,  C04B2111/2092 ,  C04B14/022 ,  C04B14/04 ,  C04B16/06 ,  C04B38/10 ,  A01N2300/00 ,  A01N25/00 ,  A01N25/12 ,  A01N65/40 ,  A01N65/44

摘要： A composite powder with a high efficiency of releasing anions, and its attached substance and manufacturing method. The composite powder is made by mixing tourmaline powder and carbon-series powder in an optimal ratio, and the composite powder is blended with an attached substance (such as polymer foaming materials or chemical fiber materials) to form a product, such that the synergy of the composite powder results in high piezoelectricity, thermoelectricity and related physical properties to achieve the multifunctional effects of releasing anions, removing odors and suppressing germs.

摘要翻译： 具有高效释放阴离子的复合粉末及其附着物和制造方法。 该复合粉末通过以最佳比例混合电气石粉末和碳系粉末而制成，并将复合粉末与附着物质（如聚合物发泡材料或化学纤维材料）混合以形成产品，使得 复合粉末导致高压电性，热电性和相关物理性能，达到释放阴离子的多功能效果，去除异味和抑制细菌。

公开(公告)号：US06291554B1

公开(公告)日：2001-09-18

申请号：US09430055

申请日：1999-10-29

申请人： Tsorng-Wen Chen ,  Jen-Taut Yeh ,  Kan-Nan Chen ,  Yun-Shan Lin

发明人： Tsorng-Wen Chen ,  Jen-Taut Yeh ,  Kan-Nan Chen ,  Yun-Shan Lin

IPC分类号： C08K320

CPC分类号： C08L63/00 ,  C08G59/42 ,  C08G59/4207 ,  C08G59/4284 ,  C08L79/02 ,  C08L2666/04

摘要： Disclosed is an anionic, self-emulsified aqueous epoxy resin dispersion prepared through the semi-esterification reaction between a dicarboxylic acid anhydride and the secondary hydroxy group of an epoxy resin, followed by neutralization of the carboxylic acid thus introduced into the epoxy resin with a tertiary amine and then adding only water, without the need of any emulsifier, to the resulting hydrophilic amine salt of the carboxylic acid. The stable aqueous epoxy resin contains both carboxyl and epoxy groups which are reactive functional groups. Also disclosed is a “single-pack” curable aqueous epoxy resin system “cross-linkable” at normal temperature prepared by adding a compound containing polyaziridine as a cross-linking agent into the aqueous epoxy resin dispersion. Upon drying, the liberated carboxyl group in the aqueous epoxy resin reacts with the polyaziridine to form an amino ester via a ring opening reaction. The amino group further reacts with the epoxy group of the epoxy resin to run another cross linking reaction to complete a “double cross-linking”. The novel double cross-linking process according to the present invention also can be used in a hybrid resin obtained by blending the aqueous epoxy resin dispersion and other carboxyl- or epoxy-containing aqueous resins, to cure the hybrid resin.

摘要翻译： 公开了通过二羧酸酐和环氧树脂的仲羟基之间的半酯化反应制备的阴离子，自乳化的水性环氧树脂分散体，然后将由此引入到环氧树脂中的羧酸中和 然后仅向所得羧酸的亲水胺盐中加入水，而不需要任何乳化剂。 稳定的水性环氧树脂含有作为反应性官能团的羧基和环氧基团。 还公开了通过将含有作为交联剂的聚氮丙啶的化合物添加到水性环氧树脂分散体中而制备的在常温下“可交联”的“单组分”可固化水性环氧树脂体系。 干燥后，水性环氧树脂中的游离羧基与聚氮丙啶反应，通过开环反应形成氨基酯。 氨基还与环氧树脂的环氧基进行反应，进行另一个交联反应，从而完成“双重交联”。 根据本发明的新型双交联方法也可以用于通过混合水性环氧树脂分散体和其它含羧基或环氧基的含水树脂而获得的杂化树脂，以固化杂化树脂。

公开(公告)号：US08038735B2

公开(公告)日：2011-10-18

申请号：US12550558

申请日：2009-08-31

申请人： Jen-Taut Yeh ,  Kan-Nan Chen ,  Chi-Hui Tsou ,  Jing-Wen Tang

发明人： Jen-Taut Yeh ,  Kan-Nan Chen ,  Chi-Hui Tsou ,  Jing-Wen Tang

IPC分类号： D06P3/06 ,  D06P3/10

CPC分类号： D01F6/90 ,  D01F1/10 ,  D01F6/04 ,  D01F6/60 ,  D06P1/445 ,  D06P3/241 ,  D06P3/248 ,  D06P3/791 ,  D06P3/798 ,  Y10S8/924

摘要： In a deep dyeing process of a polyamide (PA) including Nylon 4, Nylon 6, Nylon 46, Nylon 66, Nylon 7, Nylon 8, Nylon 9, Nylon 610, Nylon 1010, Nylon 11, Nylon 12, Nylon 13, Nylon 612, Nylon 9T, Nylon 13, MC Nylon, Nylon MXD6, and all polyamide derivatives, and a polyolefin (PO) including ethylene copolymer, propylene copolymer and their derivatives, a compatibilizer precursor is used for modifying the polyamide and polyolefin of an amino, hydroxyl or epoxy group containing chemical, and then a reactive dye and/or an acid dye is used for dyeing the polyamide and polyolefin, so that the dyed polyamide and polyolefin have excellent dye fastness, light fastness, rubbing fastness, washing fastness and low-temperature dyeability to overcome the shortcomings of conventional nylon fibers including a poor dyeing effect, a non-level dyeing quality, a high dyeing temperature (100° C. to 120° C.) and a high cost.

摘要翻译： 在包括尼龙4，尼龙6，尼龙46，尼龙66，尼龙7，尼龙8，尼龙9，尼龙610，尼龙1010，尼龙11，尼龙12，尼龙13，尼龙612的聚酰胺（PA）的深度染色过程中 ，尼龙9T，尼龙13，MC尼龙，尼龙MXD6和所有聚酰胺衍生物，以及包含乙烯共聚物，丙烯共聚物及其衍生物的聚烯烃（PO），相容剂前体用于改性聚酰胺和聚烯烃的氨基，羟基 或含环氧基的化学物质，然后使用活性染料和/或酸性染料染色聚酰胺和聚烯烃，使得染色的聚酰胺和聚烯烃具有优异的耐色牢度，耐光性，耐摩擦牢度，耐洗牢度和低温 可染性能克服常规尼龙纤维的缺点，包括染色效果差，染色质量差，染色温度高（100〜120℃），成本高。

公开(公告)号：US20110047719A1

公开(公告)日：2011-03-03

申请号：US12550558

申请日：2009-08-31

申请人： Jen-Taut YEH ,  Kan-Nan Chen ,  Chi-Hui Tsou ,  Jing-Wen Tang

发明人： Jen-Taut YEH ,  Kan-Nan Chen ,  Chi-Hui Tsou ,  Jing-Wen Tang

IPC分类号： D06P7/00

CPC分类号： D01F6/90 ,  D01F1/10 ,  D01F6/04 ,  D01F6/60 ,  D06P1/445 ,  D06P3/241 ,  D06P3/248 ,  D06P3/791 ,  D06P3/798 ,  Y10S8/924

摘要： In a deep dyeing process of a polyamide (PA) including Nylon 4, Nylon 6, Nylon 46, Nylon 66, Nylon 7, Nylon 8, Nylon 9, Nylon 610, Nylon 1010, Nylon 11, Nylon 12, Nylon 13, Nylon 612, Nylon 9T, Nylon 13, MC Nylon, Nylon MXD6, and all polyamide derivatives, and a polyolefin (PO) including ethylene copolymer, propylene copolymer and their derivatives, a compatibilizer precursor is used for modifying the polyamide and polyolefin of an amino, hydroxyl or epoxy group containing chemical, and then a reactive dye and/or an acid dye is used for dyeing the polyamide and polyolefin, so that the dyed polyamide and polyolefin have excellent dye fastness, light fastness, rubbing fastness, washing fastness and low-temperature dyeability to overcome the shortcomings of conventional nylon fibers including a poor dyeing effect, a non-level dyeing quality, a high dyeing temperature (100° C. to 120° C.) and a high cost.

摘要翻译： 在包括尼龙4，尼龙6，尼龙46，尼龙66，尼龙7，尼龙8，尼龙9，尼龙610，尼龙1010，尼龙11，尼龙12，尼龙13，尼龙612的聚酰胺（PA）的深度染色过程中 ，尼龙9T，尼龙13，MC尼龙，尼龙MXD6和所有聚酰胺衍生物，以及包含乙烯共聚物，丙烯共聚物及其衍生物的聚烯烃（PO），相容剂前体用于改性聚酰胺和聚烯烃的氨基，羟基 或含环氧基的化学物质，然后使用活性染料和/或酸性染料染色聚酰胺和聚烯烃，使得染色的聚酰胺和聚烯烃具有优异的耐色牢度，耐光性，耐摩擦牢度，耐洗牢度和低温 可染性能克服常规尼龙纤维的缺点，包括染色效果差，染色质量差，染色温度高（100〜120℃），成本高。