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    Process for the production of polyurethanes
    3.
    发明授权
    Process for the production of polyurethanes 失效
    聚氨酯生产工艺

    公开(公告)号：US4644016A

    公开(公告)日：1987-02-17

    申请号：US761278

    申请日：1985-08-01

    申请人： Werner Rasshofer ,  Hans-Albrecht Freitag

    发明人： Werner Rasshofer ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/18 ,  C08G18/14 ,  C08G18/20

    CPC分类号： C08G18/1866

    摘要： Polyurethanes are made by reacting a polyisocyanate with a compound containing at least two isocyanate-reactive hydrogen atoms having a molecular weight of from 400 to 10,000 in the presence of a catalyst containing tertiary amino groups. The required catalyst corresponds to the formula ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 represent a specified group or radical. A blowing agent and/or stabilizer and/or chain extending agent and/or other additives commonly used in the production of polyurethanes may optionally be included in the reaction mixture. The catalyst employed in the process is particularly advantageous in that it does not have a noticeable amine odor.

    摘要翻译： 聚氨酯通过使多异氰酸酯与含有至少两个分子量为400至10,000的异氰酸酯反应性氢原子的化合物在含有叔氨基的催化剂存在下反应而制备。 所需的催化剂对应于其中R，R 1，R 2，R 3，R 4，R 5，R 6和R 7表示指定基团或基团的式“IMAGE”。 在制备聚氨酯中通常使用的发泡剂和/或稳定剂和/或增链剂和/或其它添加剂可任选地包括在反应混合物中。 在该方法中使用的催化剂特别有利的是它不具有明显的胺气味。

    Upholstered seat having an air-permeable covering and a cold foam core
    5.
    发明授权
    Upholstered seat having an air-permeable covering and a cold foam core 失效
    软垫座具有透气性覆盖物和冷泡芯

    公开(公告)号：US4618532A

    公开(公告)日：1986-10-21

    申请号：US641118

    申请日：1984-08-15

    申请人： Robert Volland ,  Hans-Albrecht Freitag ,  Johannes Seesing ,  Herbert Bergmann

    发明人： Robert Volland ,  Hans-Albrecht Freitag ,  Johannes Seesing ,  Herbert Bergmann

    IPC分类号： B32B5/18 ,  A47C7/18 ,  A47C27/00 ,  B29C39/10 ,  B29C44/12 ,  B29C44/16 ,  B29K105/04 ,  B29L31/58 ,  B32B5/24 ,  B68G7/06 ,  B68G11/04 ,  B32B3/26

    CPC分类号： B29C44/16 ,  A47C7/18 ,  B29C44/1261 ,  B29L2031/58 ,  B29L2031/751 ,  Y10T428/233 ,  Y10T428/239 ,  Y10T428/249953 ,  Y10T428/24996 ,  Y10T428/249976

    摘要： The present invention is directed to an upholstered seat consisting of an in situ foam core based on a cold foam formulation and an air-permeable covering and to a process for integrally producing an upholstered seat with improved standards of comfort by back foaming a covering material in a mold, characterized in that, in a split mold of which the dividing plane preferably extends in the vicinity of the actual seat surface, a sealed foam-impermeable covering material is applied to the internal contour of the mold and that part of the covering material which forms the actual seat surface is clamped in the dividing plane of the mold, the entire mold cavity is filled with foam by metering the foam in correspondingly large quantities, after which the sealing layer around the fully reacted foam core, where it consists of an air-impermeable material, is destroyed by a mechanical treatment, such as needle punching, flexing, compression, knocking, or by solvents to at least such an extent that it becomes permeable to air.

    摘要翻译： 本发明涉及一种软垫座椅，其由基于冷泡沫配方的原位泡沫芯和透气性覆盖物组成，并且涉及一种通过使覆盖材料反向发泡来改善舒适度的整体制造软垫座椅的方法 模具，其特征在于，在分割平面优选在实际座面附近延伸的分割模具中，将密封的不透泡覆盖材料施加到模具的内部轮廓，并且该部分覆盖材料 形成实际的座面的模具被夹紧在模具的分割平面中，整个模腔通过相当大量地计量泡沫填充泡沫，此后，完全反应的泡沫芯周围的密封层由 不透气材料通过机械处理如针刺，弯曲，压缩，敲击或通过溶剂破坏至少至少这样的程度 它变得透气。

    Process for the production of polyurethanes using morpholine compounds as catalysts
    6.
    发明授权
    Process for the production of polyurethanes using morpholine compounds as catalysts 失效
    使用吗啉化合物作为催化剂生产聚氨酯的方法

    公开(公告)号：US4379861A

    公开(公告)日：1983-04-12

    申请号：US325539

    申请日：1981-11-27

    申请人： Peter Haas ,  Hans-Albrecht Freitag

    发明人： Peter Haas ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/00 ,  C07D295/12 ,  C08G18/18 ,  C08G18/20 ,  C08J9/02 ,  C08G18/14

    CPC分类号： C08G18/2081 ,  C08G18/2018

    摘要： The invention relates to a process for the preparation of foamed or unfoamed polyurethanes by the reaction of compounds with molecular weights of 400 to 10,000 having at least two isocyanate-reactive hydrogen atoms with polyisocyanates in the presence of catalysts containing tertiary amino groups and optionally in the presence of chain-lengthening agents of molecular weight 32 to 400, foam stabilizers, water and/or organic blowing agents and optionally other auxiliary agents and additives, characterized in that the catalysts are morpholine derivatives of the general formula ##STR1## wherein X is an integer from 3 to 6 andR.sup.1 and R.sup.2 are identical or different and(a) represent a C.sub.1 -C.sub.6 -alkyl or C.sub.6 -C.sub.10 -cycloalkyl group or(b) form a heterocyclic ring containing 4-7 C-atoms, which heterocyclic ring may contain hetero groups in addition to the N-atom and wherein the additional hetero groups may be substituted by a C.sub.1 -C.sub.3 alkyl, or(c) together denote a group of the formula ##STR2## in which n and m are identical or different numbers from 2 to 4, preferably 2, or(d) represent ##STR3##

    摘要翻译： 本发明涉及一种制备泡沫或未发泡的聚氨酯的方法，其通过在含有叔氨基的催化剂存在下，通过使分子量为400至10,000的化合物与多异氰酸酯反应而具有至少两个异氰酸酯反应性氢原子与任选在 存在分子量为32至400的链延长剂，泡沫稳定剂，水和/或有机发泡剂和任选的其它助剂和添加剂，其特征在于催化剂是通式为“IMAGE”的吗啉衍生物，其中X为 3至6的整数，R 1和R 2相同或不同，（a）表示C 1 -C 6烷基或C 6 -C 10 - 环烷基或（b）形成含有4-7个C原子的杂环，该杂环 可以含有除了N-原子以外的杂基，其中另外的杂基可以被C 1 -C 3烷基取代，或者（c）一起表示式“IMAGE”的基团，其中n 和m是相同或不同的数2至4，优选2，或（d）表示

    Process for the production of optionally cellular polyurethanes
    8.
    发明授权
    Process for the production of optionally cellular polyurethanes 失效
    用于生产任选的细胞聚氨酯的方法

    公开(公告)号：US4510269A

    公开(公告)日：1985-04-09

    申请号：US638160

    申请日：1984-08-06

    申请人： Richard Kopp ,  Hans-Albrecht Freitag

    发明人： Richard Kopp ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/00 ,  C08G18/16 ,  C08G18/18 ,  C08G18/14

    CPC分类号： C08G18/1833 ,  C08G18/1825

    摘要： A process for the production of an optionally cellular polyurethane by reacting at least one compound having at least two hydrogen atoms which are reactive with isocyanate groups and have a molecular weight of from about 400 to 10,000 with polyisocyanates in the presence of a poly(dialkylaminoalkyl)ether catalyst corresponding to the formula ##STR1## wherein A represents a straight-chain or branched-chain (x+1)-valent, optionally substituted C.sub.2 -C.sub.6 alkyl radical,x represents an integer of 1 to 4 andR.sup.1 -R.sup.4 represent the same or different C.sub.1 -C.sub.4 alkyl radicals, which optionally form a heterocyclic radical with N.

    摘要翻译： 通过使至少两种具有至少两个与异氰酸酯基团反应的氢原子和具有约400至10,000的分子量的化合物与聚异氰酸酯在聚（二烷基氨基烷基）基团的存在下反应生产任选的细胞聚氨酯的方法， 其中A代表直链或支链（x + 1）价任选取代的C 2 -C 6烷基，x代表1至4的整数，并且R 1 -R 4代表 相同或不同的C1-C4烷基，其任选地与N.形成杂环基。

    Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure
    9.
    发明授权
    Polyisocyanate compositions containing reversibly blocked catalysts and addition products of sulfonyl isocyanates with catalysts having a tin(II)- or tin(IV)-carboxylate structure 失效
    含有可逆封闭的催化剂的多异氰酸酯组合物和具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂的磺酰基异氰酸酯的加成产物

    公开(公告)号：US4824595A

    公开(公告)日：1989-04-25

    申请号：US633732

    申请日：1984-07-23

    申请人： Roland Richter ,  Hanns P. Muller ,  Rudolf Hombach ,  Manfred Dollhausen ,  Geza Avar ,  Hans-Albrecht Freitag

    发明人： Roland Richter ,  Hanns P. Muller ,  Rudolf Hombach ,  Manfred Dollhausen ,  Geza Avar ,  Hans-Albrecht Freitag

    IPC分类号： C08G18/00 ,  C08G18/16 ,  C08G18/24 ,  C08G18/72 ,  C09K3/00

    CPC分类号： C08G18/72 ,  C08G18/16 ,  C08G18/24

    摘要： The present invention relates to polyisocyanate compositions containing reversibly blocked catalysts for the isocyanate addition reaction, characterized in that they contain(a) at least one organic polyisocyanate,(b) at least one addition product dissolved or dispersed in the polyisocyanate compositions, of a sulfonyl isocyanate with a tertiary amine and/or with a catalyst having a tin(II)- or tin(IV)-carboxylate structure as the reversibly blocked catalyst.The present invention also relates to a process for producing these polyisocyanate compositions and to the use of new polyisocyanate compositions as reactants for compounds containing isocyanate-reactive groups for the production of isocyanate addition products such as polyurethane plastics using a one-component or two-component principle. The present invention finally relates to the latent polyurethane catalysts prepared from a sulfonyl isocyanate and a tin(II)- or tin(IV)-carboxylate.

    摘要翻译： 本发明涉及含有用于异氰酸酯加成反应的可逆封闭的催化剂的多异氰酸酯组合物，其特征在于它们含有（a）至少一种有机多异氰酸酯，（b）至少一种溶解或分散在多异氰酸酯组合物中的加成产物， 异氰酸酯与叔胺和/或具有锡（II） - 或锡（IV） - 羧酸盐结构的催化剂作为可逆阻挡的催化剂。 本发明还涉及一种制备这些多异氰酸酯组合物的方法，以及使用新的多异氰酸酯组合物作为含有异氰酸酯反应性基团的化合物的反应物，用于生产异氰酸酯加成产物如聚氨酯塑料，其使用单组分或双组分 原理。 本发明最终涉及由磺酰基异氰酸酯和锡（II） - 或锡（IV） - 羧酸酯制备的潜在聚氨酯催化剂。

    Process for the production of optionally foamed polyurethanes which are combined or fabricated with another material
    10.
    发明授权
    Process for the production of optionally foamed polyurethanes which are combined or fabricated with another material 失效
    用于生产任选发泡的聚氨酯的方法，其与另一种材料组合或制造

    公开(公告)号：US4761307A

    公开(公告)日：1988-08-02

    申请号：US817222

    申请日：1986-01-08

    申请人： Peter Haas ,  Hans-Albrecht Freitag ,  Geza Avar

    发明人： Peter Haas ,  Hans-Albrecht Freitag ,  Geza Avar

    IPC分类号： C08G18/00 ,  C08G18/18 ,  C08G18/20 ,  C08J9/02 ,  B05D5/00 ,  B05D3/02 ,  B32B5/18

    CPC分类号： C08G18/1825 ,  C08G18/2081

    摘要： The present invention is directed to a process for the production of optionally foamed polyurethanes which are combined or fabricated with another material, comprising reacting compounds with molecular weights from 400 to 10,000 containing at least 2 isocyanate reactive hydrogen atoms with polyisocyanates in the presence of catalysts containing tertiary amino groups and combining or fabricating the resulting polyurethane with another material, characterized in that the catalysts used are diffusion resistant aminoalkanols corresponding to the general formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or a C.sub.1 -C.sub.6 alkyl group,R.sup.5, R.sup.6, R.sup.7 and R.sup.8 may be identical or different and represent a C.sub.1 -C.sub.6 alkyl group or together form a C.sub.2 -C.sub.6 alkylene group which may contain hetero atoms such as O or NR (R=C.sub.1 -C.sub.4 alkyl), and n and m may be identical or different and represent integers from 1 to 6.

    摘要翻译： 本发明涉及生产任选发泡的聚氨酯的方法，其与另一种材料组合或制造，包括在含有至少2个异氰酸酯反应性氢原子的化合物中含有至少2个异氰酸酯反应性氢原子的化合物与多异氰酸酯反应，所述催化剂含有 叔氨基，并且将所得聚氨酯与另一种材料组合或制造，其特征在于所用的催化剂是对应于通式为“IMAGE”的扩散阻力氨基链烷醇，其中R 1，R 2，R 3和R 4可以相同或不同，表示氢或 C1-C6烷基，R5，R6，R7和R8可以相同或不同，表示C1-C6烷基或一起形成可含有杂原子如O或NR的C 2 -C 6亚烷基（R = C1- C4烷基），n和m可以相同或不同，表示1〜6的整数。