摘要:
Higher molecular weight linear α-olefins are produced by the oligomerization of ethylene using certain iron complexes of 2,6-diacylpyridinedimimines or 2,6-pyridinedicarboxaldehydedimines as catalysts. These iron complexes are more sterically hindered than those heretofore used. The resulting α-olefins are useful as comonomers in olefin polymerizations.
摘要:
An ethylene oligomerization catalyst that oligmerizes ethylene to a series of α-olefins and that has a Schulz-Flory constant of about 0.75 to 0.995 produces a stream of α-olefins. This stream is then added to a vessel containing ethylene and a copolymerization catalyst that copolymerizes ethylene and α-olefins. The resulting branched polyethylene often has good processing properties. The good processing is presumably due to the presence of “long chain branching”. Such polymers are useful for films and other packaging materials, and for molding resins for molding parts such as industrial, automotive or electrical parts.
摘要:
A polymerization to form a branched polyolefin, in which polymerization an ethylene copolymerization catalyst and an ethylene oligomerization catalyst form a series of ethylene oligomers that are α-olefins are both present, gives an improved polyethylene if the oligomerization catalyst has a to relatively high Schulz-Flory constant.
摘要:
Disclosed herein are processes for making quaternary chalcogenide wafers. The process comprises heating a mixture of quaternary chalcogenide crystals and flux and then cooling the mixture to form a solidified mixture comprising ingots of quaternary chalcogenide and flux. The process also comprises isolating one or more ingots of quaternary chalcogenide from the solidified mixture and mounting at least one ingot in a polymer binder to form a quaternary chalcogenide-polymer composite. The process also comprises optionally slicing the quaternary chalcogenide-polymer composite to form one or more quaternary chalcogenide-polymer composite wafers. The quaternary chalcogenide wafers are useful for forming solar cells.
摘要:
The present invention relates to synthesis of copper zinc tin sulfide, Cu2ZnSnS4, and its corresponding selenide and telluride analogs in ionic liquids. Cu2ZnSnS4 and related compounds are useful as absorber materials in thin film solar cells.
摘要:
Disclosed herein are processes for making quaternary chalcogenide wafers. The process comprises milling quaternary chalcogenide crystals to form milled particles, and then compressing the milled particles to form a quaternary chalcogenide wafer. The quaternary chalcogenide wafers are useful for forming solar cells.
摘要:
Disclosed herein are compositions derived from a polycarboxylic acid, and an ionic liquid. The compositions can be used to prepare thermal transfer donor elements.
摘要:
Processes for making ivalent germanium and tin compounds are provided. The divalent germanium and tin compounds have been found to be efficient catalysts for the formation of polyurethanes.
摘要:
Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
摘要:
This invention relates to electroluminescent silylated pyrene compounds. It also relates to electronic devices in which the active layer includes an electroluminescent silylated pyrene compound.