摘要:
A selectivated molecular sieve, e.g., ZSM-22 or ZSM-23, is used as olefin oligomerization catalyst to provide product, e.g., octenes and dodecenes from butene, having a low degree of branching and hindered double bonds.
摘要:
In a process for preparing an alkylaromatic hydrocarbon composition an olefinic hydrocarbon mixture and an aromatic compound are contacted under alkylation conditions with an aromatic alkylation catalyst selected from a homogeneous acid catalyst and heterogeneous acid catalyst comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstroms. The olefinic hydrocarbon mixture comprises at least 5 wt % by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprising at least 20 percent by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译:在制备烷基芳族烃组合物的方法中,烯烃混合物和芳族化合物在烷基化条件下与选自均相酸催化剂的芳族烷基化催化剂和包含具有包括d的X射线衍射图的分子筛的多相酸催化剂接触 最大值为12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃。 烯烃混合物包含至少5重量%的以下经验式的单烯烃低聚物:<?in-line-formula description =“In-line Formulas”end =“lead”?> C n 其中n大于或等于10,单烯烃低聚物包含:其中n大于或等于10,其中n大于或等于10,单烯烃低聚物包含 至少20重量%的具有至少12个碳原子的烯烃,并且具有至少12个碳原子的烯烃具有平均0.8-2.0℃-1-3C 3 >每个碳链的烷基支链。 烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物,例如生物降解性和冷水和冷水性能。
摘要:
A process for producing phenol and methyl ethyl ketone comprises contacting benzene with a C4 alkylating agent under alkylation conditions with catalyst comprising zeolite beta or a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom to produce an alkylation effluent comprising sec-butylbenzene. The sec-butylbenzene is then oxidized to produce a hydroperoxide and the hydroperoxide is decomposed to produce phenol and methyl ethyl ketone.
摘要:
Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation with a molecular sieve based olefin oligomerization catalyst comprising an MWW zeolite material. Besides being more environmentally favorable in use, the MWW based zeolites offer advantages in catalyst cycle life, selectivity and product quality. After loading of the catalyst, the converted unit is operated as a fixed-bed unit by passing the C2-C4 olefinic feed to a fixed bed of the MWW zeolite condensation catalyst, typically at a temperature from 150 to 250° C., a pressure not greater than 7000 kPag, usually less than 4000 kPag and a space velocity up to 30 WHSV. The gasoline boiling range product is notable for a high level of branched chain octenes resulting in high octane quality.
摘要:
In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9− hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.
摘要:
The invention relates to a process for producing a desired dialkylbenzene isomer having a formula R2C6H4, where R is an alkyl substituent, by contacting a polyalkylbenzene compound of formula RnC6H6-n, where n is an integer between 2 and 4, with a monoalkylbenzene compound of formula RC6H5 in the presence of a molecular sieve catalyst under reaction conditions sufficient to produce said dialkybenzene isomer. The preferred molecular sieve catalysts have pores or surface cavities greater than 5.6 Angstroms in diameter and/or an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07, and 3.42±0.07 Angstrom.
摘要翻译:本发明涉及一种制备具有式R 2 C 6 H 4的所需二烷基苯异构体的方法,其中R是烷基取代基,其中n为2〜4的整数的式R n C 6 H 6-n的多烷基苯化合物与 式RC6H5在分子筛催化剂存在下,在足以产生所述二烷基苯异构体的反应条件下进行。 优选的分子筛催化剂具有直径大于5.6埃的孔或表面空腔和/或包括在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃处的d间距最大值的X射线衍射图。
摘要:
Multi-mode diode emitters are stacked in a staircase formation to provide a spatially-multiplexed output. Improved coupling efficiency is achieved by providing tilted collimated output beams that determine an effective step height of the stepped structure. Since the effective step height is dependent on the tilt angle, a variable number of emitters can be used inside packages having a same physical step height, while still attaining high coupling efficiency.
摘要:
An apparatus and accompanying methods for preventing telephone toll fraud that relies on the use of centralized voice verification to authenticate a party claiming a particular identity and requesting service, i.e. access to a telephone network. A voice verification intelligent peripheral (VVIP) (300) is interposed between, e.g., a tandem switch (40) and a voice service node (VSN) (250) both used to provide alternate automated billing service (AABS). The VVIP intercepts all call processing messages that occur between these two components and, at a pre-defined point during the processing of an AABS call, holds a call processing message, specifically a successful line information database (LIDB) query response message, until a voice verification of a caller is complete. While the message is held, the VVIP prompts the caller, who is claiming to be a subscriber, to speak a pre-defined password, obtains a voice template of the resulting speech and attempts to match this template against a template previously stored, within the VVIP, for the subscriber, during a prior enrollment process and for the same password. If the templates match and hence the identity claimed by the caller is confirmed, the VVIP simply passes the message, then being held, onward to its destination, such as the VSN, to then allow the normal processing for this call to proceed and eventually result in the call being extended through public switching network to a dialed destination number.
摘要:
Multi-mode diode emitters are stacked in a staircase formation to provide a spatially-mulitplexed output. Improved coupling efficiency is achieved by providing tilted collimated output beams that determine an effective step height of the stepped structure. Since the effective step height is dependent on the tilt angle, a variable number of emitters can be used inside packages having a same physical step height, while still attaining high coupling efficiency.
摘要:
A process for producing alkyl aromatic compounds which comprises contacting at least one aromatic compound with at least one alkylating agent or transalkylating agent possessing at least one aliphatic group having from 1 to 5 carbon atoms under alkylation or transalkylation reaction conditions and in the presence of an alkylation or transalkylation catalyst, to provide an alkylated aromatic product possessing at least one alkyl group derived from said alkylating agent or transalkylating agent, said catalyst comprising a binder-free molecular sieve having an X-ray diffraction pattern that includes the lines set forth in Table A.