Preparation of alkylaromatic hydrocarbons and alkylaryl sulfonates
    2.
    发明申请
    Preparation of alkylaromatic hydrocarbons and alkylaryl sulfonates 失效
    烷基芳烃和烷基芳基磺酸盐的制备

    公开(公告)号:US20050165264A1

    公开(公告)日:2005-07-28

    申请号:US10509508

    申请日:2003-03-28

    摘要: In a process for preparing an alkylaromatic hydrocarbon composition an olefinic hydrocarbon mixture and an aromatic compound are contacted under alkylation conditions with an aromatic alkylation catalyst selected from a homogeneous acid catalyst and heterogeneous acid catalyst comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstroms. The olefinic hydrocarbon mixture comprises at least 5 wt % by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprising at least 20 percent by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.

    摘要翻译: 在制备烷基芳族烃组合物的方法中,烯烃混合物和芳族化合物在烷基化条件下与选自均相酸催化剂的芳族烷基化催化剂和包含具有包括d的X射线衍射图的分子筛的多相酸催化剂接触 最大值为12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃。 烯烃混合物包含至少5重量%的以下经验式的单烯烃低聚物:<?in-line-formula description =“In-line Formulas”end =“lead”?> C n 其中n大于或等于10,单烯烃低聚物包含:其中n大于或等于10,其中n大于或等于10,单烯烃低聚物包含 至少20重量%的具有至少12个碳原子的烯烃,并且具有至少12个碳原子的烯烃具有平均0.8-2.0℃-1-3C 3 >每个碳链的烷基支链。 烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物,例如生物降解性和冷水和冷水性能。

    Gasoline production by olefin polymerization
    4.
    发明申请
    Gasoline production by olefin polymerization 审中-公开
    汽油生产通过烯烃聚合

    公开(公告)号:US20060194999A1

    公开(公告)日:2006-08-31

    申请号:US11362257

    申请日:2006-02-27

    IPC分类号: C07C2/68

    CPC分类号: C10G50/00 C10G2400/02

    摘要: Solid phosphoric acid (SPA) olefin oligomerization process units may be converted to operation with a more environmentally favorable solid catalyst. The SPA units in which a light olefin feed is oligomerized to form gasoline boiling range hydrocarbon product, is converted unit to operation with a molecular sieve based olefin oligomerization catalyst comprising an MWW zeolite material. Besides being more environmentally favorable in use, the MWW based zeolites offer advantages in catalyst cycle life, selectivity and product quality. After loading of the catalyst, the converted unit is operated as a fixed-bed unit by passing the C2-C4 olefinic feed to a fixed bed of the MWW zeolite condensation catalyst, typically at a temperature from 150 to 250° C., a pressure not greater than 7000 kPag, usually less than 4000 kPag and a space velocity up to 30 WHSV. The gasoline boiling range product is notable for a high level of branched chain octenes resulting in high octane quality.

    摘要翻译: 固体磷酸(SPA)烯烃低聚过程单元可以转化为具有更环保的固体催化剂的操作。 将轻烯烃进料低聚以形成汽油沸程烃产物的SPA单元通过包含MWW沸石材料的基于分子筛的烯烃低聚催化剂转化为操作。 除了在使用环境方面更有利,基于MWW的沸石提供了催化剂循环寿命,选择性和产品质量的优点。 载入催化剂后,转化的单元通过将C 2 -C 4亚烷基烯烃进料转移到MWW沸石冷凝物的固定床上作为固定床单元进行操作 催化剂,通常在150-250℃的温度下,压力不大于7000kPag,通常小于4000kPag,空速可达30WHSV。 汽油沸点范围产品对于高水平的支链辛烯是显着的,导致高辛烷值。

    Olefin oligomerization to produce hydrocarbon compositions useful as fuels
    5.
    发明申请
    Olefin oligomerization to produce hydrocarbon compositions useful as fuels 有权
    烯烃低聚产生用作燃料的烃组合物

    公开(公告)号:US20060217580A1

    公开(公告)日:2006-09-28

    申请号:US11342385

    申请日:2006-01-27

    IPC分类号: C07C2/02

    CPC分类号: C10G50/00 C09K8/32

    摘要: In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9− hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.

    摘要翻译: 在制备烃组合物的方法中,包含至少一种C 3至C 8 O烯烃的进料和富含C 9 N的烯烃循环料流 烃类与结晶分子筛催化剂接触,其结晶尺寸不大于0.05微米,在至少一个反应区域的α值为约100至约600之间,在烯烃低聚条件下,包括入口温度约为150℃ 约350℃,压力至少为2860kPa,循环至饲料重量比为约0.1至约3.0。 接触产生低聚流出物流,其被分离成至少一种富含C 9+烃的烃产物流和烯烃再循环流。

    Production of dialkylbenzenes
    6.
    发明申请
    Production of dialkylbenzenes 有权
    生产二烷基苯

    公开(公告)号:US20050075523A1

    公开(公告)日:2005-04-07

    申请号:US10946553

    申请日:2004-09-21

    IPC分类号: C07C2/00 C07C6/12 C07C15/12

    摘要: The invention relates to a process for producing a desired dialkylbenzene isomer having a formula R2C6H4, where R is an alkyl substituent, by contacting a polyalkylbenzene compound of formula RnC6H6-n, where n is an integer between 2 and 4, with a monoalkylbenzene compound of formula RC6H5 in the presence of a molecular sieve catalyst under reaction conditions sufficient to produce said dialkybenzene isomer. The preferred molecular sieve catalysts have pores or surface cavities greater than 5.6 Angstroms in diameter and/or an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07, and 3.42±0.07 Angstrom.

    摘要翻译: 本发明涉及一种制备具有式R 2 C 6 H 4的所需二烷基苯异构体的方法,其中R是烷基取代基,其中n为2〜4的整数的式R n C 6 H 6-n的多烷基苯化合物与 式RC6H5在分子筛催化剂存在下,在足以产生所述二烷基苯异构体的反应条件下进行。 优选的分子筛催化剂具有直径大于5.6埃的孔或表面空腔和/或包括在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃处的d间距最大值的X射线衍射图。

    High-brightness spatial-multiplexed multi-emitter pump with tilted collimated beam
    7.
    发明授权
    High-brightness spatial-multiplexed multi-emitter pump with tilted collimated beam 有权
    具有倾斜准直光束的高亮度空间复用多发射器泵

    公开(公告)号:US09065237B2

    公开(公告)日:2015-06-23

    申请号:US13313490

    申请日:2011-12-07

    摘要: Multi-mode diode emitters are stacked in a staircase formation to provide a spatially-multiplexed output. Improved coupling efficiency is achieved by providing tilted collimated output beams that determine an effective step height of the stepped structure. Since the effective step height is dependent on the tilt angle, a variable number of emitters can be used inside packages having a same physical step height, while still attaining high coupling efficiency.

    摘要翻译: 多模二极管发射器堆叠在阶梯形式中以提供空间复用输出。 通过提供确定阶梯式结构的有效步长的倾斜的准直输出光束来实现改进的耦合效率。 由于有效步高取决于倾斜角度,所以在具有相同物理台阶高度的包装内可以使用可变数量的发射器,同时仍然获得高耦合效率。

    Apparatus and accompanying methods for preventing toll fraud through use
of centralized caller voice verification
    8.
    发明授权
    Apparatus and accompanying methods for preventing toll fraud through use of centralized caller voice verification 失效
    通过使用集中式呼叫者语音验证来防止长途欺诈的装置和相关方法

    公开(公告)号:US5502759A

    公开(公告)日:1996-03-26

    申请号:US61115

    申请日:1993-05-13

    摘要: An apparatus and accompanying methods for preventing telephone toll fraud that relies on the use of centralized voice verification to authenticate a party claiming a particular identity and requesting service, i.e. access to a telephone network. A voice verification intelligent peripheral (VVIP) (300) is interposed between, e.g., a tandem switch (40) and a voice service node (VSN) (250) both used to provide alternate automated billing service (AABS). The VVIP intercepts all call processing messages that occur between these two components and, at a pre-defined point during the processing of an AABS call, holds a call processing message, specifically a successful line information database (LIDB) query response message, until a voice verification of a caller is complete. While the message is held, the VVIP prompts the caller, who is claiming to be a subscriber, to speak a pre-defined password, obtains a voice template of the resulting speech and attempts to match this template against a template previously stored, within the VVIP, for the subscriber, during a prior enrollment process and for the same password. If the templates match and hence the identity claimed by the caller is confirmed, the VVIP simply passes the message, then being held, onward to its destination, such as the VSN, to then allow the normal processing for this call to proceed and eventually result in the call being extended through public switching network to a dialed destination number.

    摘要翻译: 一种用于防止依赖于使用集中语音验证的电话长途欺诈的装置和相关方法来认证声称特定身份并请求服务的一方,即访问电话网络。 语音验证智能外设(VVIP)(300)被插入在例如串联交换机(40)和语音服务节点(VSN)(250)之间,两者都用于提供交替的自动计费服务(AABS)。 VVIP拦截在这两个组件之间发生的所有呼叫处理消息,并且在处理AABS呼叫期间的预定义点处保存呼叫处理消息,特别是成功的线路信息数据库(LIDB)查询响应消息,直到 呼叫者的语音验证完成。 当消息被保留时,VVIP提示呼叫者声称是订户的用户说出预先定义的密码,获得所得到的语音的语音模板,并尝试将该模板与先前存储的模板相匹配 VVIP,用于订户,在先前的注册过程和相同的密码。 如果模板匹配,因此主叫方所要求的身份被确认,则VVIP简单地传递消息,然后被保持到其目的地,例如VSN,然后允许该呼叫的正常处理进行并且最终导致 在呼叫通过公共交换网络扩展到拨打的目的地号码。

    HIGH-BRIGHTNESS SPATIAL-MULTIPLEXED MULTI-EMITTER PUMP WITH TILTED COLLIMATED BEAM
    9.
    发明申请
    HIGH-BRIGHTNESS SPATIAL-MULTIPLEXED MULTI-EMITTER PUMP WITH TILTED COLLIMATED BEAM 有权
    高亮度空间多功能多功能发射器泵与倾斜聚光束

    公开(公告)号:US20130148684A1

    公开(公告)日:2013-06-13

    申请号:US13313490

    申请日:2011-12-07

    IPC分类号: H01S5/022

    摘要: Multi-mode diode emitters are stacked in a staircase formation to provide a spatially-mulitplexed output. Improved coupling efficiency is achieved by providing tilted collimated output beams that determine an effective step height of the stepped structure. Since the effective step height is dependent on the tilt angle, a variable number of emitters can be used inside packages having a same physical step height, while still attaining high coupling efficiency.

    摘要翻译: 多模式二极管发射器堆叠在阶梯结构中以提供空间复合输出。 通过提供确定阶梯式结构的有效步长的倾斜的准直输出光束来实现改进的耦合效率。 由于有效步高取决于倾斜角度,所以在具有相同物理台阶高度的包装内可以使用可变数量的发射器,同时仍然获得高耦合效率。