公开(公告)号：US20060024222A1

公开(公告)日：2006-02-02

申请号：US11193972

申请日：2005-07-29

申请人： Josef Dachs ,  Wolfgang Schuster ,  Rolf Bank ,  Manfred Lehr

发明人： Josef Dachs ,  Wolfgang Schuster ,  Rolf Bank ,  Manfred Lehr

IPC分类号： F28D7/00 ,  C01B15/013

CPC分类号： F28F1/40 ,  B01J8/06 ,  B01J8/067 ,  B01J19/002 ,  B01J2208/00238 ,  B01J2208/0084 ,  B01J2208/00849 ,  B01J2219/00263

摘要： With a method for operating a tube bundle reactor for exothermic gas phase reactions having a tube bundle with catalyst-filled reaction tubes (2), wherein the one ends of the reaction tubes are spanned by a gas inlet hood and the other ends are spanned by a gas outlet hood and wherein around the outside of the reaction tubes a heat transfer medium flows to carry off reaction heat. An explosive gas mixture (G) is introduced into the reaction tubes (2) via the gas inlet hood and after reaction the gas mixture (G), that may still be explosive, it is led off from the reaction tubes via the gas outlet hood. A limit temperature in the reaction tubes (2) is specified that lies above the normal operating temperatures in the reaction tubes (2) but at most equals the ignition temperature of the explosive gas mixture (G) Each non-operating high temperature region (7) forming in the reaction tubes (2) whose temperature is at least equal to the limit temperature and which migrates in the respective reaction tube (2) in the longitudinal direction thereof is stopped while still in the reaction tube (2) so that the high temperature region (7) is prevented from advancing into the gas inlet hood or the gas outlet hood.

摘要翻译： 使用具有管束的放出气相反应管管式反应器的方法，其中催化剂填充的反应管（2），其中反应管的一端由气体入口罩跨过，另一端被 气体出口罩，并且其中在反应管的外部，传热介质流动以携带反应热。 爆炸性气体混合物（G）通过进气口引入反应管（2），反应后气体混合物（G）可能仍然是爆炸性的，通过气体出口罩从反应管中引出 。 规定反应管（2）中的极限温度高于反应管（2）的正常工作温度，但最多等于爆炸性气体混合物（G）的点火温度。每个非工作高温区域（7） ）在反应管（2）中形成，其温度至少等于极限温度，并且在反应管（2）的纵向方向上迁移到反应管（2）中，同时停留在反应管（2）中，使得高 温度区域（7）被阻止进入气体入口罩或气体出口罩。

公开(公告)号：US08961909B2

公开(公告)日：2015-02-24

申请号：US13823525

申请日：2011-10-12

申请人： Manfred Lehr ,  Josef Dachs ,  Franz Egner ,  Rolf Bank ,  Bernd Stürmer ,  Volkmar Frick ,  Michael Specht

发明人： Manfred Lehr ,  Josef Dachs ,  Franz Egner ,  Rolf Bank ,  Bernd Stürmer ,  Volkmar Frick ,  Michael Specht

IPC分类号： B01J8/06 ,  C10G2/00 ,  C10L3/08 ,  F28F13/08

CPC分类号： B01J8/067 ,  B01J8/065 ,  B01J2208/0023 ,  B01J2208/00238 ,  B01J2208/0053 ,  C10G2/32 ,  C10G2/341 ,  C10L3/08 ,  F28F13/08

摘要： A tube bundle reactor for carrying out catalytic gas phase reactions, particularly methanation reactions, has a bundle of catalyst-filled reaction tubes through which reaction gas flows and around which heat carrier flows during operation. In the region of the catalyst filling, the reaction tubes run through at least two heat carrier zones which are separated from one another, the first of which heat carrier zones extends over the starting region of the catalyst filling. The reaction tubes each have a first reaction tube portion with a first hydraulic diameter of the catalyst filling and, downstream thereof in flow direction of the reaction gas, at least a second reaction tube portion with a second hydraulic diameter of the catalyst filling that is greater than the first hydraulic diameter of the catalyst filling.

摘要翻译： 用于进行催化气相反应，特别是甲烷化反应的管束反应器具有一束催化剂填充的反应管，反应气体在其中流动并在运行期间使热载体流过。 在催化剂填充的区域中，反应管穿过至少两个彼此分离的热载体区，其中第一个热载体区在催化剂填充物的起始区域上延伸。 反应管各自具有第一反应管部分，其具有催化剂填充物的第一水力直径，并且在反应气体的流动方向上在其下游，至少第二反应管部分具有催化剂填充物的第二水力直径更大 比第一液压直径的催化剂填充。

公开(公告)号：US07988927B2

公开(公告)日：2011-08-02

申请号：US11782741

申请日：2007-07-25

申请人： Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

发明人： Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

IPC分类号： F28D7/00

CPC分类号： B01J8/067 ,  B01J2208/00053 ,  B01J2208/00061 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00256 ,  B01J2208/00646 ,  B01J2208/00716 ,  F28D7/16 ,  F28F27/00

摘要： A method of varying the temperature of a tube bundle reactor for catalytic gas phase reactions upon start-up and shut-down, the tube bundle reactor comprising a major reactor portion which includes a bundle of vertically disposed reactor tubes, upper and lower tubesheets tightly connected to the upper and lower ends, respectively, of the reactor tubes, and a reactor shell enclosing the tube bundle, a heat transfer medium having a melting temperature in the range of from 100° C. to 450° C. flowing around the outer surfaces of the reactor tubes during normal operation and being circulated in at least one circuit through the major reactor portion, comprising the steps: (a) varying the heat transfer medium temperature during circulation of the heat transfer medium; and (b) passing a temperature gas through the reactor tubes at least when the heat transfer medium is not yet or no longer circulated.

摘要翻译： 一种在启动和关闭时改变用于催化气相反应的管束反应器的温度的方法，所述管束反应器包括主反应器部分，其包括一束垂直设置的反应器管，上管和下管紧密连接 反应器管的上端和下端以及包围管束的反应器壳体，具有在外表面流动的熔点在100℃至450℃范围内的传热介质 的反应器管，并且通过主反应器部分在至少一个回路中循环，包括以下步骤：（a）改变传热介质循环期间的传热介质温度; 和（b）至少当传热介质尚未或不再循环时，使温度气体通过反应器管。

公开(公告)号：US20080023175A1

公开(公告)日：2008-01-31

申请号：US11782741

申请日：2007-07-25

申请人： Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

发明人： Manfred Lehr ,  Josef Dachs ,  Wolfgang Schuster

IPC分类号： B01J8/06

CPC分类号： B01J8/067 ,  B01J2208/00053 ,  B01J2208/00061 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00256 ,  B01J2208/00646 ,  B01J2208/00716 ,  F28D7/16 ,  F28F27/00

摘要： A method of varying the temperature of a tube bundle reactor for catalytic gas phase reactions upon start-up and shut-down, the tube bundle reactor comprising a major reactor portion which includes a bundle of vertically disposed reactor tubes, upper and lower tubesheets tightly connected to the upper and lower ends, respectively, of the reactor tubes, and a reactor shell enclosing the tube bundle, a heat transfer medium having a melting temperature in the range of from 100° C. to 450° C. flowing around the outer surfaces of the reactor tubes during normal operation and being circulated in at least one circuit through the major reactor portion, comprising the steps: (a) varying the heat transfer medium temperature during circulation of the heat transfer medium; and (b) passing a temperature gas through the reactor tubes at least when the heat transfer medium is not yet or no longer circulated.

摘要翻译： 一种在启动和关闭时改变用于催化气相反应的管束反应器的温度的方法，管束反应器包括主反应器部分，其包括一排垂直设置的反应器管，上管和下管紧密连接 反应器管的上端和下端以及包围管束的反应器壳体，具有在外表面流动的熔点在100℃至450℃范围内的传热介质 的反应器管，并且通过主反应器部分在至少一个回路中循环，包括以下步骤：（a）改变传热介质循环期间的传热介质温度; 和（b）至少当传热介质尚未或不再循环时，使温度气体通过反应器管。

公开(公告)号：US20130287652A1

公开(公告)日：2013-10-31

申请号：US13823525

申请日：2011-10-12

申请人： Manfred Lehr ,  Josef Dachs ,  Franz Egner ,  Rolf Bank ,  Bernd Stürmer ,  Volkmar Frick ,  Michael Specht

发明人： Manfred Lehr ,  Josef Dachs ,  Franz Egner ,  Rolf Bank ,  Bernd Stürmer ,  Volkmar Frick ,  Michael Specht

IPC分类号： B01J8/06

CPC分类号： B01J8/067 ,  B01J8/065 ,  B01J2208/0023 ,  B01J2208/00238 ,  B01J2208/0053 ,  C10G2/32 ,  C10G2/341 ,  C10L3/08 ,  F28F13/08

摘要： A tube bundle reactor for carrying out catalytic gas phase reactions, particularly methanation reactions, has a bundle of catalyst-filled reaction tubes through which reaction gas flows and around which heat carrier flows during operation. In the region of the catalyst filling, the reaction tubes run through at least two heat carrier zones which are separated from one another, the first of which heat carrier zones extends over the starting region of the catalyst filling. The reaction tubes each have a first reaction tube portion with a first hydraulic diameter of the catalyst filling and, downstream thereof in flow direction of the reaction gas, at least a second reaction tube portion with a second hydraulic diameter of the catalyst filling that is greater than the first hydraulic diameter of the catalyst filling.

摘要翻译： 用于进行催化气相反应，特别是甲烷化反应的管束反应器具有一束催化剂填充的反应管，反应气体在其中流动并在运行期间使热载体流过。 在催化剂填充的区域中，反应管穿过至少两个彼此分离的热载体区，其中第一个热载体区在催化剂填充物的起始区域上延伸。 反应管各自具有第一反应管部分，其具有催化剂填充物的第一水力直径，并且在反应气体的流动方向上在其下游，至少第二反应管部分具有催化剂填充物的第二水力直径更大 比第一液压直径的催化剂填充。

公开(公告)号：US08062605B2

公开(公告)日：2011-11-22

申请号：US12752249

申请日：2010-04-01

申请人： Manfred Lehr ,  Wolfgang Primbs

发明人： Manfred Lehr ,  Wolfgang Primbs

IPC分类号： F28D7/00

CPC分类号： B01J8/22 ,  B01J8/025 ,  B01J8/0285 ,  B01J2208/00185 ,  F28D7/12 ,  F28F9/0202 ,  F28F9/0246 ,  F28F2220/00

摘要： A cooling system for use in a shell-type reactor includes vertically extending double tubes with an inner tube and an outer tube closed at its lower end. The system also includes a distributor for supplying a fluid cooling medium into the upper end of the inner tubes and a horizontally extending plate, which on its upper surface includes at least two upwardly open, parallel grooves. Two adjacent grooves are separated by a common inner wall. At least one outer tube, having an upper end, is disposed in each groove, through the plate. Each outer tube is tightly welded to the plate on the groove base. The upper, open side of each groove is closed with a lid, so that each groove forms a collector for discharging the cooling medium from the outer tubes. Each inner tube opens through the lid into a distributor and is tightly attached to the lid.

摘要翻译： 用于壳型反应器的冷却系统包括垂直延伸的双管，内管和外管在其下端封闭。 该系统还包括用于将流体冷却介质供应到内管的上端的分配器和水平延伸的板，其在其上表面上包括至少两个向上开口的平行凹槽。 两个相邻的槽由共同的内壁分开。 具有上端的至少一个外管设置在每个凹槽中，穿过板。 每个外管紧紧焊接在槽底上的板上。 每个槽的上部开口侧用盖封闭，使得每个槽形成用于从外管排出冷却介质的收集器。 每个内管通过盖子打开到分配器中并且紧密地附接到盖子上。

公开(公告)号：US07521029B2

公开(公告)日：2009-04-21

申请号：US10541698

申请日：2003-01-31

申请人： Friedrich Guetlhuber ,  Manfred Lehr

发明人： Friedrich Guetlhuber ,  Manfred Lehr

IPC分类号： F28D7/00 ,  B01J19/00 ,  B01J10/00 ,  B01J8/04 ,  G05D16/00

CPC分类号： B01J8/008 ,  B01J3/02 ,  B01J3/03 ,  B01J3/042 ,  B01J4/002 ,  B01J8/0085 ,  B01J8/065 ,  B01J8/067 ,  B01J19/002 ,  B01J19/0053 ,  B01J19/26 ,  B01J2208/00203 ,  B01J2208/00212 ,  B01J2208/00495 ,  B01J2208/0053 ,  B01J2208/00548 ,  B01J2208/00716 ,  B01J2208/00849 ,  B01J2219/00263 ,  B01J2219/00265 ,  C07C51/21 ,  F28D7/16 ,  F28F9/0229 ,  F28F9/0265 ,  F28F2225/08 ,  Y10T137/043 ,  Y10T137/1654

摘要： The invention relates to a tubular reactor for carrying out catalytic gas-phase reactions, containing a catalyst tube bundle (8) that is traversed by the relevant reaction gas mixture, is filled with a catalyst, extends between two tube sheets (4, 148) and around which flows a heat transfer medium contained within a surrounding reactor jacket (6). The reactor also comprises gas entry and discharge hoods (2; 60) that cover the two tube sheets for supplying the relevant process gas to the catalyst tubes and for discharging the reacted process gas from the catalyst tubes. Together with all the parts that come into contact with the process gas mixture, the reactor is designed to have an appropriate strength for withstanding the deflagration and explosive pressures that are to be taken into account during its operation. The volume available to the process gas mixture prior to its entry into the catalyst tubes is restricted as much as possible in construction and flow engineering terms.

摘要翻译： 本发明涉及一种用于进行催化气相反应的管式反应器，其中包含由相关反应气体混合物穿过的催化剂管束（8），填充有催化剂，在两个管板（4,148）之间延伸， 并且在其周围流过包含在周围的反应器夹套（6）内的传热介质。 反应器还包括气体进入和排出罩（2; 60），其覆盖两个管板，用于将相关工艺气体供应到催化剂管并从催化剂管排出反应的工艺气体。 连同与工艺气体混合物接触的所有部件，反应器被设计为具有适当的强度，以承受在其操作期间要考虑的爆燃和爆炸压力。 过程气体混合物在其进入催化剂管之前可用的体积在结构和流程工程方面尽可能地受到限制。

公开(公告)号：US20100260651A1

公开(公告)日：2010-10-14

申请号：US12752249

申请日：2010-04-01

申请人： Manfred Lehr ,  Wolfgang Primbs

发明人： Manfred Lehr ,  Wolfgang Primbs

IPC分类号： F28D7/16

CPC分类号： B01J8/22 ,  B01J8/025 ,  B01J8/0285 ,  B01J2208/00185 ,  F28D7/12 ,  F28F9/0202 ,  F28F9/0246 ,  F28F2220/00

摘要： A cooling system for use in a shell-type reactor includes vertically extending double tubes with an inner tube and an outer tube closed at its lower end. The system also includes a distributor for supplying a fluid cooling medium into the upper end of the inner tubes and a horizontally extending plate, which on its upper surface includes at least two upwardly open, parallel grooves. Two adjacent grooves are separated by a common inner wall. At least one outer tube, having an upper end, is disposed in each groove, through the plate. Each outer tube is tightly welded to the plate on the groove base. The upper, open side of each groove is closed with a lid, so that each groove forms a collector for discharging the cooling medium from the outer tubes. Each inner tube opens through the lid into a distributor and is tightly attached to the lid.

摘要翻译： 用于壳型反应器的冷却系统包括垂直延伸的双管，内管和外管在其下端封闭。 该系统还包括用于将流体冷却介质供应到内管的上端的分配器和水平延伸的板，其在其上表面上包括至少两个向上开口的平行凹槽。 两个相邻的槽由共同的内壁分开。 具有上端的至少一个外管设置在每个凹槽中，穿过板。 每个外管紧紧焊接在槽底上的板上。 每个槽的上部开口侧用盖封闭，使得每个槽形成用于从外管排出冷却介质的收集器。 每个内管通过盖子打开到分配器中并且紧密地附接到盖子上。

公开(公告)号：US07449037B2

公开(公告)日：2008-11-11

申请号：US11203353

申请日：2005-08-12

申请人： Manfred Lehr ,  Franz Egner ,  Michael Claussen ,  Markus Maly

发明人： Manfred Lehr ,  Franz Egner ,  Michael Claussen ,  Markus Maly

IPC分类号： B01J8/00 ,  B01J19/00 ,  B01J8/04 ,  F28D1/00

CPC分类号： B01J8/067 ,  B01J8/065 ,  B01J2208/0007

摘要： A method for carrying out endothermic or exothermic gas phase reactions by using a tube bundle reactor with a tube bundle of catalyst-filled reaction tubes comprises the following steps: a) Introducing a reaction gas mixture into the reaction tubes; b) Dividing-up of the reaction gas mixture flow flowing through each of the reaction tubes into at least two partial flows, each partial flow having the same composition; c) Feeding-in of each partial flow at a different point along the catalyst filling with an existing flow resistance; d) Determining the desired partial flow volume for each partial flow (V1, V2, V3, V4); e) Calculating the pressure at the point of the first division of the reaction gas mixture (9); f) Calculating the pressure in the catalyst filling (12) at the point of feeding-in of each partial flow (V1, V2, V3, V4); and g) Setting of flow resistance for each point of feeding-in in such a way that the flow resistance at the desired partial flow volume corresponds to the pressure difference between the pressures determined in steps e) and f).

摘要翻译： 通过使用具有催化剂填充反应管的管束的管束反应器进行吸热或放热气相反应的方法包括以下步骤：a）将反应气体混合物引入反应管中; b）将流过每个反应管的反应气体混合物流分成至少两个部分流，每个部分流具有相同的组成; c）沿着催化剂填充的不同点处的每个部分流进入现有的流动阻力; d）确定每个部分流（V 1，V 2，V 3，V 4）的期望的部分流量， SUB>）; e）计算反应气体混合物（9）的第一分馏点的压力; f）计算每个部分流（V 1，V 2，V 3）的进料点处的催化剂填充物（12）中的压力， / SUB>，V 4）; 和g）以每一个进料点设定流动阻力，使得所需部分流量下的流动阻力对应于在步骤e）和f）中确定的压力之间的压力差。

公开(公告)号：US07837954B2

公开(公告)日：2010-11-23

申请号：US12128775

申请日：2008-05-29

申请人： Manfred Lehr

发明人： Manfred Lehr

IPC分类号： B01J8/04 ,  F28D7/00 ,  F28D1/02

CPC分类号： B01J8/067 ,  B01J8/008 ,  B01J2208/00212 ,  B01J2219/0002 ,  B01J2219/00038 ,  F22B1/1838 ,  F22B21/02 ,  F28D7/163 ,  F28D2021/0064 ,  F28F9/00 ,  F28F9/013 ,  F28F9/0219 ,  F28F9/0241 ,  F28F9/26

摘要： A set of prefabricated tube bundle reactor subassemblies is proposed which are adapted to be assembled at a construction site to provide a tube bundle reactor for carrying out catalytic gas and/or liquid phase reactions. In accordance with the invention, the reactor shell and the reactor heads, on the one hand, and the tube bundle and the tube sheets, on the other hand, form separate subassemblies, more specifically at least one shell/head subassembly, at least one head subassembly, and at least one tube bundle subassembly. The subassemblies comprise means for vertically supporting the tube bundle subassembly and for pressure tightly connecting the shell/head subassembly to the tube sheets without requiring heat treatment during assembly of the subassemblies. Likewise proposed are a tube bundle reactor for carrying out catalytic gas and/or liquid phase reactions and an arrangement of the kind of tube bundle reactors mentioned.

摘要翻译： 提出了一套预制管束反应器子组件，其适于在施工现场组装以提供用于进行催化气体和/或液相反应的管束反应器。 根据本发明，另一方面，一方面反应器壳体和反应器头部以及管束和管板形成分离的子组件，更具体地，形成至少一个壳/组件组件，至少一个 头部组件和至少一个管束子组件。 子组件包括用于垂直支撑管束子组件的装置，并且用于将壳体/头部组件压紧到管板上，而不需要在组件组装期间进行热处理。 同样提出的是用于进行催化气体和/或液相反应的管束反应器和所述类型的管束反应器的布置。