Oxygen getters for anode protection in a solid-oxide fuel cell stack
    4.
    发明授权
    Oxygen getters for anode protection in a solid-oxide fuel cell stack 有权
    在固体氧化物燃料电池堆中用于阳极保护的氧气吸气剂

    公开(公告)号:US07435490B2

    公开(公告)日:2008-10-14

    申请号:US11593672

    申请日:2006-11-07

    摘要: In a fuel cell assembly, nickel-based anodes are readily oxidized when exposed to oxygen as may happen through atmospheric invasion of the assembly during cool-down following shutdown of the assembly. Repeated anode oxidation and reduction can be destructive of the anodes, leading to cracking and failure. To prevent such oxygen migration, oxygen getter devices containing oxygen-gettering material such as metallic nickel are provided in the fuel passageways leading to and from the anodes. Oxidation of the oxygen-gettering material is readily reversed through reduction by fuel when the assembly is restarted.

    摘要翻译: 在燃料电池组件中,当暴露于氧气时,镍基阳极容易氧化,这可能是由于在组件关闭后的冷却期间通过组件的大气侵入而发生的。 重复的阳极氧化和还原可能是阳极的破坏,导致开裂和破坏。 为了防止这种氧迁移,在通向和从阳极的燃料通道中提供含有吸氧材料如金属镍的吸氧剂装置。 当组装重新启动时,吸氧材料的氧化很容易通过燃料的还原反转。

    Fuel cell stack having a featured interconnect element
    5.
    发明授权
    Fuel cell stack having a featured interconnect element 有权
    具有特征互连元件的燃料电池堆

    公开(公告)号:US08197981B2

    公开(公告)日:2012-06-12

    申请号:US11095063

    申请日:2005-03-31

    IPC分类号: H01M2/20 H01M8/24

    摘要: An interconnect element for electrically connecting an anode and a cathode in adjacent fuel cells in a fuel cell stack, wherein said interconnect element has at least one featured surface including dimples, bosses, and/or pins arranged in a two-dimensional pattern. Preferably, both surfaces are featured, as by mechanical dimpling, embossing, or chemical etching, so that protrusions of the interconnect surface extend into either or both of the adjacent gas flow spaces to make electrical contact with the surfaces of the anode and cathode. This permits conduction of heat from the anode. The protrusions create turbulence in gas flowing through the flow spaces, which increases hydrogen consumption at the anode and hence electric output of the cell.

    摘要翻译: 一种互连元件,用于将燃料电池堆中的相邻燃料电池中的阳极和阴极电连接,其中所述互连元件具有包括以二维图案布置的凹坑,凸起和/或销的至少一个特征表面。 优选地,两个表面的特征在于机械凹坑,压花或化学蚀刻,使得互连表面的突起延伸到相邻的气体流动空间中的一个或两个中,以与阳极和阴极的表面电接触。 这允许来自阳极的热传导。 突起在流过空间的气体中产生湍流,这增加了阳极处的氢消耗,从而增加了电池的电输出。

    Fuel cell stack having foil interconnects and laminated spacers
    6.
    发明授权
    Fuel cell stack having foil interconnects and laminated spacers 失效
    具有箔互连和层压间隔物的燃料电池堆

    公开(公告)号:US06821667B2

    公开(公告)日:2004-11-23

    申请号:US09968270

    申请日:2001-10-01

    IPC分类号: H01M802

    摘要: Interconnects and perimeter spacers for a fuel cell stack are provided as flexible elements which can conform to non-planarities in a stack's electrolyte elements and thereby avoid inducing torsional stresses in the electrolyte elements. The interconnects are foil elements about 0.005 inches thick, formed of a superalloy such as Hastelloy, Haynes 230, or a stainless steel. The perimeter spacers comprise a plurality of laminate thin spacer elements, each thin spacer element being a laminate of superalloy and a “soft” material such as copper, nickel, or mica. The spacer elements can slide past one another; thus the perimeter spacers can be physically thick, to form the gas flow spaces within the stack, while also being torsionally flexible.

    摘要翻译: 提供了用于燃料电池堆的互连和周边间隔物作为柔性元件,其可以符合堆叠电解质元件中的非平面性,从而避免在电解质元件中引起扭转应力。 这些互连件是约0.005英寸厚的箔元件,由诸如Hastelloy,Haynes 230或不锈钢的超级合金形成。 周边间隔件包括多个层压薄的间隔元件,每个薄间隔元件是超合金和诸如铜,镍或云母的“软”材料的层压体。 间隔元件可以彼此滑过; 因此周边间隔物可以物理上较厚,以在堆叠内形成气流空间,同时也具有挠性。

    Solid-oxide fuel cell system having a fuel combustor to pre-heat reformer on start-up
    10.
    发明授权
    Solid-oxide fuel cell system having a fuel combustor to pre-heat reformer on start-up 有权
    具有燃料燃烧器的固体氧化物燃料电池系统在启动时预热重整器

    公开(公告)号:US07410016B2

    公开(公告)日:2008-08-12

    申请号:US10178125

    申请日:2002-06-24

    IPC分类号: B60K1/00

    摘要: In a solid-oxide fuel cell system, a catalytic reformer unit provides reformate fuel for use by the cells in generating electricity. Both the reformer and the fuel cells require elevated temperatures for satisfactory operation. The reformer unit is provided with a combustion chamber and igniter ahead of the catalytic reformer plates such that, during start-up, fuel/air mixture normally destined for reformation may be ignited in the combustion chamber to provide a hot combustion exhaust which is fed through the catalytic reformer and the anode reformate flow spaces to assist in rapidly bringing the fuel cell system to operating temperature.

    摘要翻译: 在固体氧化物燃料电池系统中,催化重整单元提供用于发电的电池的重整燃料。 重整器和燃料电池都需要升高的温度才能令人满意的操作。 重整器单元在催化重整器板之前设置有燃烧室和点火器,使得在启动期间,通常用于改造的燃料/空气混合物可能在燃烧室中点燃以提供通过 催化重整器和阳极重整物流动空间,以帮助快速使燃料电池系统达到工作温度。