公开(公告)号：US06482524B1

公开(公告)日：2002-11-19

申请号：US09036927

申请日：1998-03-09

申请人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Hiroaki Kobayashi ,  Takashi Sunada ,  Toyoyuki Teranishi

发明人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Hiroaki Kobayashi ,  Takashi Sunada ,  Toyoyuki Teranishi

IPC分类号： B32B1706

CPC分类号： C04B41/009 ,  B05D1/185 ,  B05D3/10 ,  B05D5/083 ,  C03C17/34 ,  C03C17/3405 ,  C03C17/42 ,  C03C2217/76 ,  C04B41/52 ,  C04B41/89 ,  C04B2111/20 ,  C04B2111/27 ,  C09K3/18 ,  C23C26/00 ,  C23C30/00 ,  Y10T428/24355 ,  Y10T428/24364 ,  Y10T428/31612 ,  Y10T428/31667 ,  C04B41/4933 ,  C04B41/524 ,  C04B41/4961 ,  C04B41/522 ,  C04B41/455 ,  C04B33/00 ,  C04B35/00

摘要： For obtaining a substrate on the surface of which a water repellent film is firmly bonded through an undercoating film, and which shows a low critical inclination angle, superior durability, and high density, a water repellent and/or oil repellent film layer is formed by using a liquid for undercoating treatment. The liquid for undercoating treatment is obtained by dissolving and reacting a material having chlorosilyl radicle radicle in molecular form therein and is dissolved into an alcohol group solvent, so that a surface roughness (Ra) of less than 0.5 nm is obtained, thereby achieving high durability and a low critical inclination angle.

摘要翻译： 为了获得其表面上的基材，通过底涂膜牢固地粘合防水膜，并且显示出低临界倾斜角，优异的耐久性和高密度，通过以下方式形成防水和/或防油膜层： 使用液体进行底涂处理。 用于底涂处理的液体是通过将具有分子形式的具有氯甲硅烷基辐射体的材料溶解并反应并溶解在醇基溶剂中而获得的，从而获得小于0.5nm的表面粗糙度（Ra），从而获得高耐久性 和低临界倾角。

公开(公告)号：US06564935B1

公开(公告)日：2003-05-20

申请号：US09705076

申请日：2000-11-02

申请人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Mitsuhiro Kawazu ,  Mitsuo Asai

发明人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Mitsuhiro Kawazu ,  Mitsuo Asai

IPC分类号： B65D6900

CPC分类号： C03C17/30 ,  C09K3/18

摘要： A coating solution for water-repellent, oil-repellent, stain-proofing treatment is provided which does not become cloudy even if it is stored for a long time. Furthermore, a method for water-repellent, oil-repellent, stain-proofing treatment with the use of this coating solution is provided. The coating solution for water-repellent, oil-repellent, and stain-proofing treatment is obtained by mixing a first solution containing a fluoroalkyl group-containing silane and a second solution containing acid and a solvent, and this coating solution is used for the method for water-repellent, oil-repellent, stain-proofing treatment.

摘要翻译： 提供了防水，防油，防污处理的涂布溶液，即使长时间储存​​也不会变得混浊。 此外，提供了使用该涂布溶液进行防水，防油，防污处理的方法。 通过混合含有含氟烷基的硅烷的第一溶液和含有酸和溶剂的第二溶液，得到用于防水，防油和防污处理的涂布溶液，并且该涂布溶液用于该方法 用于防水，防油，防污处理。

公开(公告)号：US06465108B1

公开(公告)日：2002-10-15

申请号：US09360279

申请日：1999-07-26

申请人： Kazutaka Kamitani ,  Toyoyuki Teranishi ,  Kazuhiro Doushita ,  Takashi Sunada ,  Hiroaki Kobayashi ,  Hiroaki Yamamoto ,  Hisashi Ogawa

发明人： Kazutaka Kamitani ,  Toyoyuki Teranishi ,  Kazuhiro Doushita ,  Takashi Sunada ,  Hiroaki Kobayashi ,  Hiroaki Yamamoto ,  Hisashi Ogawa

IPC分类号： B32B904

CPC分类号： C03C17/30 ,  C03C1/008 ,  C03C17/25 ,  C03C17/3405 ,  C03C17/42 ,  C03C2217/213 ,  C03C2217/76 ,  C03C2218/113 ,  C23C18/1212 ,  C23C18/1245 ,  C23C18/1254 ,  C23C18/1295 ,  Y10T428/31612 ,  Y10T428/31663

摘要： Coating liquid prepared by dissolving an acid and a silicon alkoxide into alcohol, containing at least one of either a silicon alkoxide or a hydrolyzate thereof (including a partial hydrolyzate) in an amount of 0.010 to 3% by weight (in terms of silica), an acid in terms of 0.0010 to 1.0 normality, and water in terms of 0 to 10% by weight is coated on a substrate to produce an article coated with a silica-based film. By this method for producing a silica-based film coated article, an excellent silica-based film coated article can be obtained without requiring baking and pretreatment. Furthermore, a functional film coated article excellent in durability can be produced in a short period of time and safely by using the abovementioned silica-based film as a primer film and applying thereon an organosilane having a hydrolyzable group and a functional group having a specific function or a hydrolyzate thereof.

摘要翻译： 将含有0.010〜3重量％（以二氧化硅计）的含有硅烷醇盐或其水解物（包括部分水解产物）中的至少一种的酸和硅醇盐溶解在醇中制备的涂布液， 以0.0010至1.0的正常性为基准的酸，并且将0至10重量％的水涂覆在基材上以制备涂覆有二氧化硅基膜的制品。 通过该二氧化硅系薄膜涂布体的制造方法，可以得到优异的二氧化硅系薄膜被覆制品，而不需要烘烤和预处理。 此外，通过使用上述二氧化硅系膜作为底涂膜，可以在短时间内安全地制造耐久性优异的功能膜涂布制品，并在其上涂布具有可水解基团和具有特定功能的官能团的有机硅烷 或其水解产物。

公开(公告)号：US06623863B2

公开(公告)日：2003-09-23

申请号：US09822719

申请日：2001-03-30

申请人： Kazutaka Kamitani ,  Hiroaki Yamamoto

发明人： Kazutaka Kamitani ,  Hiroaki Yamamoto

IPC分类号： B32B904

CPC分类号： C09D183/00 ,  C03C17/009 ,  C09D1/00 ,  Y10T428/31612 ,  Y10T428/31663

摘要： There are provided articles coated with high-performance water-repellent films with high hardness that can withstand outdoor use, which are water-repellent film-coated articles that comprise a substrate and a water-repellent film composed mainly of silicon oxide and having a water-repellent group coated on the surface of the substrate, and are characterized by containing at least one type of metal oxide selected from the group consisting of magnesium oxide, calcium oxide, strontium oxide and boron oxide, as well as a process for preparation of such water-repellent film-coated articles at a high rate of productivity and a coating liquid composition for preparation of such water-repellent film-coated articles.

摘要翻译： 提供涂覆有可以经受户外使用的高硬度高性能防水膜的制品，其是包含基材的防水膜类制品和主要由氧化硅组成的具有水的防水膜 其特征在于，含有选自氧化镁，氧化钙，氧化锶和氧化硼中的至少一种金属氧化物，以及其制备方法 防水性薄膜制品，以及用于制备这种防水涂膜制品的涂布液组合物。

公开(公告)号：US20070212534A1

公开(公告)日：2007-09-13

申请号：US10594606

申请日：2005-03-31

申请人： Teruyuki Sasaki ,  Kazuyuki Inoguchi ,  Kazutaka Kamitani

发明人： Teruyuki Sasaki ,  Kazuyuki Inoguchi ,  Kazutaka Kamitani

IPC分类号： B32B17/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/213 ,  C03C2217/44 ,  C03C2218/113 ,  C08J7/047 ,  C08J2483/00 ,  C09D1/00 ,  C09D4/00 ,  Y10T428/2962 ,  Y10T428/2995 ,  Y10T428/31663 ,  C08G77/00

摘要： The present invention provides an article with a silica-based film, wherein the film does not separate from a substrate after the Taber abrasion test prescribed in Japanese Industrial Standards (JIS) R 3212 although the thickness of the film formed by a sol-gel process exceeds 300 nm. This film can be formed by an improved sol-gel process, that is, a sol-gel process by using a coating solution wherein silicon alkoxide has a concentration of more than 3 mass % and less than 9 mass % in terms of a SiO2 concentration, the molality of protons is 0.001 to 0.2 mol/kg, and the number of moles of the water is at least four times and at most ten times the total number of moles of the silicon atoms, and by heating a substrate at the temperature above 100° C.

摘要翻译： 本发明提供了一种具有二氧化硅基膜的制品，其中在日本工业标准（JIS）R 3212中规定的泰伯磨损试验之后，该膜不与基底分离，尽管通过溶胶 - 凝胶法形成的膜的厚度 超过300nm。 该膜可以通过改进的溶胶 - 凝胶法形成，即通过使用其中硅醇盐的浓度大于3质量％且小于9质量％的涂覆溶液的溶胶 - 凝胶法， SUB> 2 浓度时，质子的摩尔数为0.001〜0.2mol / kg，水的摩尔数为硅原子总摩尔数的4倍以上10倍以下， 通过在100℃以上的温度下加热基材

公开(公告)号：US07160626B2

公开(公告)日：2007-01-09

申请号：US10472289

申请日：2002-03-20

申请人： Kazutaka Kamitani

发明人： Kazutaka Kamitani

IPC分类号： B32B9/04

CPC分类号： C09D183/14 ,  C03C17/009 ,  C03C17/30 ,  C09D4/00 ,  C09D183/08 ,  Y10T428/3154 ,  Y10T428/31663 ,  C08G77/00 ,  C08G77/04

摘要： The invention is an coated article composed of a substrate and an organic-inorganic composite film, which is coated on the substrate and has an oxide of a cation atom capable of forming an oxide network coated on the surface of the substrate, and the same has a part of oxygen of the oxide substituted by an organic group, wherein the organic-inorganic composite film includes alkaline metal oxides at a ratio of 0.1 through 30% of the total number of the alkaline metal atoms and the cation atoms expressed in terms of the number of alkaline metal atoms, and the article coated with a high-performance organic-inorganic composite film, is able to withstand outdoor uses and has high hardness.

摘要翻译： 本发明是一种由基材和有机 - 无机复合膜组成的涂层制品，其被涂覆在基材上并具有能够形成在基材表面上形成氧化物网络的阳离子原子的氧化物，并且其具有 由有机基团取代的氧化物的氧的一部分，其中有机 - 无机复合膜包括碱金属氧化物，其碱金属原子总数为0.1〜30％，阳离子原子数为 碱金属原子数和涂有高性能有机 - 无机复合膜的制品能够经受户外使用，硬度高。

公开(公告)号：US07132094B2

公开(公告)日：2006-11-07

申请号：US10826697

申请日：2004-04-19

申请人： Takayuki Kato ,  Tomohiro Taniguchi ,  Makoto Egashira ,  Yasuhiro Shimizu ,  Takeo Hyodo ,  Kazutaka Kamitani

发明人： Takayuki Kato ,  Tomohiro Taniguchi ,  Makoto Egashira ,  Yasuhiro Shimizu ,  Takeo Hyodo ,  Kazutaka Kamitani

IPC分类号： B01J19/10 ,  C01F7/02 ,  C01F7/30

CPC分类号： C04B38/009 ,  C01F7/30 ,  C01F7/308 ,  C01P2004/34 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C04B35/6267 ,  C04B35/632 ,  C04B35/634 ,  C04B2235/3217 ,  C04B2235/449 ,  C04B2235/528 ,  C04B2235/5445 ,  C04B2235/5481 ,  C04B35/10 ,  C04B38/02

摘要： A method of producing hollow alumina particles in which the grain size of hollow alumina particles is controlled and in which a high formation ratio of hollow particles is obtained while suppressing the formation of solid particles. The method includes irradiating supersonic waves to an aqueous solution containing aluminum nitrate or aluminum acetate, and a surfactant or an organic acid to generate micro-liquid droplets in an atomized state, introducing only minute liquid droplets having a certain grain size or less, which have been classified by an air stream, into a furnace and burning them in air.

摘要翻译： 制造中空氧化铝颗粒的方法，其中中空氧化铝颗粒的颗粒尺寸被控制并且在抑制固体颗粒的形成的同时获得高中空颗粒的形成比。 该方法包括将超声波照射到含有硝酸铝或乙酸铝的水溶液中，以及表面活性剂或有机酸，以产生雾化状态的微液滴，仅引入具有一定粒度或更小的微小液滴， 被气流分类成炉，并在空气中燃烧。

公开(公告)号：US20060154048A1

公开(公告)日：2006-07-13

申请号：US10538765

申请日：2003-12-10

申请人： Toyoyuki Teranishi ,  Toshifumi Tsujino ,  Kazutaka Kamitani

发明人： Toyoyuki Teranishi ,  Toshifumi Tsujino ,  Kazutaka Kamitani

IPC分类号： C09D5/20 ,  C09D4/00 ,  C04B41/50 ,  B32B5/16

CPC分类号： C09D5/28 ,  C08K3/36 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  Y10T428/25 ,  Y10T428/26

摘要： An article coated with a functional coating film which has a base material, a primer layer coating the surface of the base material and having fine roughness and a functional layer coating the primer layer. The primer layer having fine roughness has portions formed by unevenly accumulating fine particles. The primer layer in the article contains silicon oxide as the main component, and the excellent transparency and the fine roughness are simultaneously exhibited.

摘要翻译： 涂覆有功能性涂膜的制品，其具有基材，涂覆基材表面并具有细小粗糙度的底漆层和涂覆底漆层的功能层。 具有细小粗糙度的底漆层具有通过不均匀地积聚微粒形成的部分。 制品中的底漆层含有氧化硅作为主要成分，同时表现出优异的透明性和细小的粗糙度。

公开(公告)号：US06964815B2

公开(公告)日：2005-11-15

申请号：US10257735

申请日：2002-02-15

申请人： Tetsuya Yoshitake ,  Toshifumi Tsujino ,  Kazutaka Kamitani

发明人： Tetsuya Yoshitake ,  Toshifumi Tsujino ,  Kazutaka Kamitani

IPC分类号： C03C17/00 ,  C03C17/25 ,  C03C17/34 ,  G02F1/1335 ,  B32B9/04 ,  B32B15/00 ,  B05D5/02 ,  B05D3/02

CPC分类号： G02B1/10 ,  C03C17/009 ,  C03C17/25 ,  C03C17/3411 ,  C03C2217/77 ,  C03C2218/113 ,  G02F1/133502 ,  G02F1/133553 ,  Y10T428/24355 ,  Y10T428/24628 ,  Y10T428/26

摘要： A sol-form application liquid 3 is prepared by mixing together two solvents A and B and two film components C and D. The sol-form application liquid 3 thus prepared is applied onto a glass substrate 200, thus forming a mixed layer 401 on the glass substrate 200. The glass substrate 200 having the mixed layer 401 formed thereon is left at room temperature, whereupon the solvent A evaporates and phase separation of the mixed layer 401 into an upper layer 403 and a lower layer 402 occurs. The mixed layer 401 is then heated, thus evaporating the solvent B in the lower layer 402 and gelating the film component C in the upper layer 403 and the film component D in the lower layer 402, and hence forming an internal scattering layer 404.

摘要翻译： 通过将两种溶剂A和B以及两种膜组分C和D混合在一起来制备溶胶形式的涂布液3.将如此制备的溶胶形式的涂布液3施加到玻璃基板200上，从而在 在其上形成有混合层401的玻璃基板200在室温下放置，溶剂A蒸发，混合层401相分离成上层403和下层402。 然后将混合层401加热，从而蒸发下层402中的溶剂B，并使上层402中的膜组分C和下层402中的膜组分D凝胶化，从而形成内部散射层404。

公开(公告)号：US20080311376A1

公开(公告)日：2008-12-18

申请号：US11658340

申请日：2005-07-29

申请人： Mizuho Matsuda ,  Kazutaka Kamitani ,  Takeshi Sunaga ,  Takeshi Yabuta

发明人： Mizuho Matsuda ,  Kazutaka Kamitani ,  Takeshi Sunaga ,  Takeshi Yabuta

IPC分类号： B32B5/18 ,  B05D5/06

CPC分类号： C03C17/42 ,  C03C1/008 ,  C03C17/007 ,  C03C2217/425 ,  C03C2217/478 ,  Y10T428/249985

摘要： The present invention improves abrasion resistance and persistence of anti-fogging properties of an anti-fogging article. The anti-fogging article of the present invention includes an article, a porous film formed on the surface thereof, and a hydrophilic film formed thereon. The porous film contains inorganic fine particles and a binder. The binder covers at least a part of surfaces of the inorganic fine particles and is interposed between the inorganic fine particles. The binder contains a metal oxide as its main component and a hydrophilic organic group other than an alkoxyl group. The hydrophilic film contains a hydrophilic organic polymer.

摘要翻译： 本发明提高了防雾制品的耐磨性和防雾性能的持续性。 本发明的防雾物品包括物品，在其表面上形成的多孔膜和在其上形成的亲水膜。 多孔膜含有无机微粒和粘合剂。 粘合剂覆盖无机细颗粒的至少一部分表面，并且介于无机细颗粒之间。 粘合剂含有作为主要成分的金属氧化物和除烷氧基以外的亲水性有机基团。 亲水性膜含有亲水性有机聚合物。