公开(公告)号：US20080311376A1

公开(公告)日：2008-12-18

申请号：US11658340

申请日：2005-07-29

申请人： Mizuho Matsuda ,  Kazutaka Kamitani ,  Takeshi Sunaga ,  Takeshi Yabuta

发明人： Mizuho Matsuda ,  Kazutaka Kamitani ,  Takeshi Sunaga ,  Takeshi Yabuta

IPC分类号： B32B5/18 ,  B05D5/06

CPC分类号： C03C17/42 ,  C03C1/008 ,  C03C17/007 ,  C03C2217/425 ,  C03C2217/478 ,  Y10T428/249985

摘要： The present invention improves abrasion resistance and persistence of anti-fogging properties of an anti-fogging article. The anti-fogging article of the present invention includes an article, a porous film formed on the surface thereof, and a hydrophilic film formed thereon. The porous film contains inorganic fine particles and a binder. The binder covers at least a part of surfaces of the inorganic fine particles and is interposed between the inorganic fine particles. The binder contains a metal oxide as its main component and a hydrophilic organic group other than an alkoxyl group. The hydrophilic film contains a hydrophilic organic polymer.

摘要翻译： 本发明提高了防雾制品的耐磨性和防雾性能的持续性。 本发明的防雾物品包括物品，在其表面上形成的多孔膜和在其上形成的亲水膜。 多孔膜含有无机微粒和粘合剂。 粘合剂覆盖无机细颗粒的至少一部分表面，并且介于无机细颗粒之间。 粘合剂含有作为主要成分的金属氧化物和除烷氧基以外的亲水性有机基团。 亲水性膜含有亲水性有机聚合物。

公开(公告)号：US20120148832A1

公开(公告)日：2012-06-14

申请号：US13390649

申请日：2010-08-17

申请人： Takeshi Yabuta ,  Fumiyoshi Kondo ,  Masaatsu Kido ,  Masahiro Hori ,  Mitsuhiro Kawazu ,  Kazutaka Kamitani

发明人： Takeshi Yabuta ,  Fumiyoshi Kondo ,  Masaatsu Kido ,  Masahiro Hori ,  Mitsuhiro Kawazu ,  Kazutaka Kamitani

IPC分类号： B32B5/16

CPC分类号： G02B1/11 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J35/006 ,  B01J37/0215 ,  C03C17/006 ,  C03C17/23 ,  C03C2217/42 ,  C03C2217/71 ,  C09D1/02 ,  C09D5/1618 ,  G02B27/0006 ,  Y10T428/259

摘要： Provided is a glass article that improves the film strength of a photocatalyst film while maintaining the photocatalytic function and the reflection suppressing function of the photocatalyst film. The photocatalyst film on the glass sheet is formed to contain, in mass %, 50 to 82% of silicon oxide particles, 8 to 40% of titanium oxide particles, and 7 to 20% of a binder component composed of silicon oxide. The average particle diameter of the silicon oxide particles is set to at least 5 times the average particle diameter of the titanium oxide particles. The photocatalyst film is formed to have a structure such that some of the silicon oxide particles in the film serve as protruding silicon oxide particles that are not in contact with the glass sheet and that have their top portions protruding from the surrounding titanium oxide particles and being exposed on the surface of the film, while some of the titanium oxide particles are interposed between the glass sheet and the protruding silicon oxide particles.

摘要翻译： 提供一种玻璃制品，其在保持光催化剂功能和光催化剂膜的反射抑制功能的同时提高光催化剂膜的膜强度。 形成玻璃板上的光催化剂膜，以质量％计含有50〜82％的氧化硅粒子，8〜40％的氧化钛粒子和7〜20％的由氧化硅构成的粘合剂成分。 将氧化硅粒子的平均粒径设定为氧化钛粒子的平均粒径的5倍以上。 光催化剂膜形成为具有这样的结构，使得该膜中的一些氧化硅颗粒用作与玻璃板不接触并且其顶部从周围的氧化钛颗粒突出的突出的氧化硅颗粒，并且是 暴露在膜的表面上，而一些氧化钛颗粒介于玻璃板和突出的氧化硅颗粒之间。

公开(公告)号：US08541106B2

公开(公告)日：2013-09-24

申请号：US13390649

申请日：2010-08-17

申请人： Takeshi Yabuta ,  Fumiyoshi Kondo ,  Masaatsu Kido ,  Masahiro Hori ,  Mitsuhiro Kawazu ,  Kazutaka Kamitani

发明人： Takeshi Yabuta ,  Fumiyoshi Kondo ,  Masaatsu Kido ,  Masahiro Hori ,  Mitsuhiro Kawazu ,  Kazutaka Kamitani

IPC分类号： B32B17/06

CPC分类号： G02B1/11 ,  B01J21/063 ,  B01J35/002 ,  B01J35/004 ,  B01J35/006 ,  B01J37/0215 ,  C03C17/006 ,  C03C17/23 ,  C03C2217/42 ,  C03C2217/71 ,  C09D1/02 ,  C09D5/1618 ,  G02B27/0006 ,  Y10T428/259

摘要： Provided is a glass article that improves the film strength of a photocatalyst film while maintaining the photocatalytic function and the reflection suppressing function of the photocatalyst film. The photocatalyst film on the glass sheet is formed to contain, in mass %, 50 to 82% of silicon oxide particles, 8 to 40% of titanium oxide particles, and 7 to 20% of a binder component composed of silicon oxide. The average particle diameter of the silicon oxide particles is set to at least 5 times the average particle diameter of the titanium oxide particles. The photocatalyst film is formed to have a structure such that some of the silicon oxide particles in the film serve as protruding silicon oxide particles that are not in contact with the glass sheet and that have their top portions protruding from the surrounding titanium oxide particles and being exposed on the surface of the film, while some of the titanium oxide particles are interposed between the glass sheet and the protruding silicon oxide particles.

摘要翻译： 提供一种玻璃制品，其在保持光催化剂功能和光催化剂膜的反射抑制功能的同时提高光催化剂膜的膜强度。 形成玻璃板上的光催化剂膜，以质量％计含有50〜82％的氧化硅粒子，8〜40％的氧化钛粒子和7〜20％的由氧化硅构成的粘合剂成分。 将氧化硅粒子的平均粒径设定为氧化钛粒子的平均粒径的5倍以上。 光催化剂膜形成为具有这样的结构，使得该膜中的一些氧化硅颗粒用作与玻璃板不接触并且其顶部从周围的氧化钛颗粒突出的突出的氧化硅颗粒，并且是 暴露在膜的表面上，而一些氧化钛颗粒介于玻璃板和突出的氧化硅颗粒之间。

公开(公告)号：US20070212534A1

公开(公告)日：2007-09-13

申请号：US10594606

申请日：2005-03-31

申请人： Teruyuki Sasaki ,  Kazuyuki Inoguchi ,  Kazutaka Kamitani

发明人： Teruyuki Sasaki ,  Kazuyuki Inoguchi ,  Kazutaka Kamitani

IPC分类号： B32B17/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C2217/213 ,  C03C2217/44 ,  C03C2218/113 ,  C08J7/047 ,  C08J2483/00 ,  C09D1/00 ,  C09D4/00 ,  Y10T428/2962 ,  Y10T428/2995 ,  Y10T428/31663 ,  C08G77/00

摘要： The present invention provides an article with a silica-based film, wherein the film does not separate from a substrate after the Taber abrasion test prescribed in Japanese Industrial Standards (JIS) R 3212 although the thickness of the film formed by a sol-gel process exceeds 300 nm. This film can be formed by an improved sol-gel process, that is, a sol-gel process by using a coating solution wherein silicon alkoxide has a concentration of more than 3 mass % and less than 9 mass % in terms of a SiO2 concentration, the molality of protons is 0.001 to 0.2 mol/kg, and the number of moles of the water is at least four times and at most ten times the total number of moles of the silicon atoms, and by heating a substrate at the temperature above 100° C.

摘要翻译： 本发明提供了一种具有二氧化硅基膜的制品，其中在日本工业标准（JIS）R 3212中规定的泰伯磨损试验之后，该膜不与基底分离，尽管通过溶胶 - 凝胶法形成的膜的厚度 超过300nm。 该膜可以通过改进的溶胶 - 凝胶法形成，即通过使用其中硅醇盐的浓度大于3质量％且小于9质量％的涂覆溶液的溶胶 - 凝胶法， SUB> 2 浓度时，质子的摩尔数为0.001〜0.2mol / kg，水的摩尔数为硅原子总摩尔数的4倍以上10倍以下， 通过在100℃以上的温度下加热基材

公开(公告)号：US07160626B2

公开(公告)日：2007-01-09

申请号：US10472289

申请日：2002-03-20

申请人： Kazutaka Kamitani

发明人： Kazutaka Kamitani

IPC分类号： B32B9/04

CPC分类号： C09D183/14 ,  C03C17/009 ,  C03C17/30 ,  C09D4/00 ,  C09D183/08 ,  Y10T428/3154 ,  Y10T428/31663 ,  C08G77/00 ,  C08G77/04

摘要： The invention is an coated article composed of a substrate and an organic-inorganic composite film, which is coated on the substrate and has an oxide of a cation atom capable of forming an oxide network coated on the surface of the substrate, and the same has a part of oxygen of the oxide substituted by an organic group, wherein the organic-inorganic composite film includes alkaline metal oxides at a ratio of 0.1 through 30% of the total number of the alkaline metal atoms and the cation atoms expressed in terms of the number of alkaline metal atoms, and the article coated with a high-performance organic-inorganic composite film, is able to withstand outdoor uses and has high hardness.

摘要翻译： 本发明是一种由基材和有机 - 无机复合膜组成的涂层制品，其被涂覆在基材上并具有能够形成在基材表面上形成氧化物网络的阳离子原子的氧化物，并且其具有 由有机基团取代的氧化物的氧的一部分，其中有机 - 无机复合膜包括碱金属氧化物，其碱金属原子总数为0.1〜30％，阳离子原子数为 碱金属原子数和涂有高性能有机 - 无机复合膜的制品能够经受户外使用，硬度高。

公开(公告)号：US07132094B2

公开(公告)日：2006-11-07

申请号：US10826697

申请日：2004-04-19

申请人： Takayuki Kato ,  Tomohiro Taniguchi ,  Makoto Egashira ,  Yasuhiro Shimizu ,  Takeo Hyodo ,  Kazutaka Kamitani

发明人： Takayuki Kato ,  Tomohiro Taniguchi ,  Makoto Egashira ,  Yasuhiro Shimizu ,  Takeo Hyodo ,  Kazutaka Kamitani

IPC分类号： B01J19/10 ,  C01F7/02 ,  C01F7/30

CPC分类号： C04B38/009 ,  C01F7/30 ,  C01F7/308 ,  C01P2004/34 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  C04B35/6267 ,  C04B35/632 ,  C04B35/634 ,  C04B2235/3217 ,  C04B2235/449 ,  C04B2235/528 ,  C04B2235/5445 ,  C04B2235/5481 ,  C04B35/10 ,  C04B38/02

摘要： A method of producing hollow alumina particles in which the grain size of hollow alumina particles is controlled and in which a high formation ratio of hollow particles is obtained while suppressing the formation of solid particles. The method includes irradiating supersonic waves to an aqueous solution containing aluminum nitrate or aluminum acetate, and a surfactant or an organic acid to generate micro-liquid droplets in an atomized state, introducing only minute liquid droplets having a certain grain size or less, which have been classified by an air stream, into a furnace and burning them in air.

摘要翻译： 制造中空氧化铝颗粒的方法，其中中空氧化铝颗粒的颗粒尺寸被控制并且在抑制固体颗粒的形成的同时获得高中空颗粒的形成比。 该方法包括将超声波照射到含有硝酸铝或乙酸铝的水溶液中，以及表面活性剂或有机酸，以产生雾化状态的微液滴，仅引入具有一定粒度或更小的微小液滴， 被气流分类成炉，并在空气中燃烧。

公开(公告)号：US20060154048A1

公开(公告)日：2006-07-13

申请号：US10538765

申请日：2003-12-10

申请人： Toyoyuki Teranishi ,  Toshifumi Tsujino ,  Kazutaka Kamitani

发明人： Toyoyuki Teranishi ,  Toshifumi Tsujino ,  Kazutaka Kamitani

IPC分类号： C09D5/20 ,  C09D4/00 ,  C04B41/50 ,  B32B5/16

CPC分类号： C09D5/28 ,  C08K3/36 ,  C09D1/00 ,  C09D7/61 ,  C09D7/67 ,  Y10T428/25 ,  Y10T428/26

摘要： An article coated with a functional coating film which has a base material, a primer layer coating the surface of the base material and having fine roughness and a functional layer coating the primer layer. The primer layer having fine roughness has portions formed by unevenly accumulating fine particles. The primer layer in the article contains silicon oxide as the main component, and the excellent transparency and the fine roughness are simultaneously exhibited.

摘要翻译： 涂覆有功能性涂膜的制品，其具有基材，涂覆基材表面并具有细小粗糙度的底漆层和涂覆底漆层的功能层。 具有细小粗糙度的底漆层具有通过不均匀地积聚微粒形成的部分。 制品中的底漆层含有氧化硅作为主要成分，同时表现出优异的透明性和细小的粗糙度。

公开(公告)号：US06964815B2

公开(公告)日：2005-11-15

申请号：US10257735

申请日：2002-02-15

申请人： Tetsuya Yoshitake ,  Toshifumi Tsujino ,  Kazutaka Kamitani

发明人： Tetsuya Yoshitake ,  Toshifumi Tsujino ,  Kazutaka Kamitani

IPC分类号： C03C17/00 ,  C03C17/25 ,  C03C17/34 ,  G02F1/1335 ,  B32B9/04 ,  B32B15/00 ,  B05D5/02 ,  B05D3/02

CPC分类号： G02B1/10 ,  C03C17/009 ,  C03C17/25 ,  C03C17/3411 ,  C03C2217/77 ,  C03C2218/113 ,  G02F1/133502 ,  G02F1/133553 ,  Y10T428/24355 ,  Y10T428/24628 ,  Y10T428/26

摘要： A sol-form application liquid 3 is prepared by mixing together two solvents A and B and two film components C and D. The sol-form application liquid 3 thus prepared is applied onto a glass substrate 200, thus forming a mixed layer 401 on the glass substrate 200. The glass substrate 200 having the mixed layer 401 formed thereon is left at room temperature, whereupon the solvent A evaporates and phase separation of the mixed layer 401 into an upper layer 403 and a lower layer 402 occurs. The mixed layer 401 is then heated, thus evaporating the solvent B in the lower layer 402 and gelating the film component C in the upper layer 403 and the film component D in the lower layer 402, and hence forming an internal scattering layer 404.

摘要翻译： 通过将两种溶剂A和B以及两种膜组分C和D混合在一起来制备溶胶形式的涂布液3.将如此制备的溶胶形式的涂布液3施加到玻璃基板200上，从而在 在其上形成有混合层401的玻璃基板200在室温下放置，溶剂A蒸发，混合层401相分离成上层403和下层402。 然后将混合层401加热，从而蒸发下层402中的溶剂B，并使上层402中的膜组分C和下层402中的膜组分D凝胶化，从而形成内部散射层404。

公开(公告)号：US20070036985A1

公开(公告)日：2007-02-15

申请号：US11541144

申请日：2006-09-28

申请人： Kazutaka Kamitani ,  Kazuyuki Inoguchi ,  Teruyuki Sasaki ,  Nobuki Iwai ,  Hisashi Ogawa ,  Takashi Muromachi

发明人： Kazutaka Kamitani ,  Kazuyuki Inoguchi ,  Teruyuki Sasaki ,  Nobuki Iwai ,  Hisashi Ogawa ,  Takashi Muromachi

IPC分类号： B32B17/06 ,  B32B15/00 ,  B05D3/02 ,  B05D1/12 ,  B05D5/06

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C17/366 ,  C03C2217/211 ,  C03C2217/213 ,  C03C2217/231 ,  C03C2217/244 ,  C03C2217/29 ,  C03C2217/44 ,  C03C2217/476 ,  C03C2217/948 ,  C03C2218/113 ,  C09D4/00 ,  C08G77/00

摘要： An infrared ray-cutting glass according to which the capability of an IR-cutting component can be sufficiently maintained while securing sufficient hardness. The IR-cutting glass 100 is comprised of a glass substrate 20, and an IR-cutting film 10 containing ITO fine particles 12 as an infrared ray-cutting component. The IR-cutting film 10 is formed, using an infrared ray-cutting component not containing a fluorine component, on a surface of the glass substrate 20 by a sol-gel method carried out at a low temperature of less than 350° C. The IR-cutting glass 100 having the IR-cutting glass 10 has a haze of not more than 7% after a wear resistance test carried out on the surface on which the IR-cutting film 10 is formed.

摘要翻译： 一种红外线光线切割用玻璃，其能够在确保足够的硬度的同时充分保持IR切断部件的能力。 IR切割玻璃100由玻璃基板20和含有作为红外线光线切断部件的ITO微粒12的IR切断膜10构成。 通过在小于350℃的低温下进行的溶胶 - 凝胶法，在玻璃基板20的表面上形成使用不含氟成分的红外线切断用红外线切断膜10。 在形成有IR切割膜10的表面进行耐磨性试验后，具有IR切割玻璃10的IR切割玻璃100具有不大于7％的雾度。

公开(公告)号：US06482524B1

公开(公告)日：2002-11-19

申请号：US09036927

申请日：1998-03-09

申请人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Hiroaki Kobayashi ,  Takashi Sunada ,  Toyoyuki Teranishi

发明人： Hiroaki Yamamoto ,  Kazutaka Kamitani ,  Hiroaki Kobayashi ,  Takashi Sunada ,  Toyoyuki Teranishi

IPC分类号： B32B1706

CPC分类号： C04B41/009 ,  B05D1/185 ,  B05D3/10 ,  B05D5/083 ,  C03C17/34 ,  C03C17/3405 ,  C03C17/42 ,  C03C2217/76 ,  C04B41/52 ,  C04B41/89 ,  C04B2111/20 ,  C04B2111/27 ,  C09K3/18 ,  C23C26/00 ,  C23C30/00 ,  Y10T428/24355 ,  Y10T428/24364 ,  Y10T428/31612 ,  Y10T428/31667 ,  C04B41/4933 ,  C04B41/524 ,  C04B41/4961 ,  C04B41/522 ,  C04B41/455 ,  C04B33/00 ,  C04B35/00

摘要： For obtaining a substrate on the surface of which a water repellent film is firmly bonded through an undercoating film, and which shows a low critical inclination angle, superior durability, and high density, a water repellent and/or oil repellent film layer is formed by using a liquid for undercoating treatment. The liquid for undercoating treatment is obtained by dissolving and reacting a material having chlorosilyl radicle radicle in molecular form therein and is dissolved into an alcohol group solvent, so that a surface roughness (Ra) of less than 0.5 nm is obtained, thereby achieving high durability and a low critical inclination angle.

摘要翻译： 为了获得其表面上的基材，通过底涂膜牢固地粘合防水膜，并且显示出低临界倾斜角，优异的耐久性和高密度，通过以下方式形成防水和/或防油膜层： 使用液体进行底涂处理。 用于底涂处理的液体是通过将具有分子形式的具有氯甲硅烷基辐射体的材料溶解并反应并溶解在醇基溶剂中而获得的，从而获得小于0.5nm的表面粗糙度（Ra），从而获得高耐久性 和低临界倾角。