公开(公告)号：US4780260A

公开(公告)日：1988-10-25

申请号：US095795

申请日：1987-09-14

申请人： Keiji Yoshida ,  Koji Shimizu ,  Mitsuo Hamada

发明人： Keiji Yoshida ,  Koji Shimizu ,  Mitsuo Hamada

IPC分类号： B29C39/02 ,  C08J3/24 ,  B28B7/22

CPC分类号： C08J3/245 ,  B29C39/025 ,  B29K2083/00 ,  B29K2083/005 ,  C08J2383/04

摘要： The present invention provides a method for producing silicone rubber moldings composed of a uniform, smooth and hard exterior layer and a relatively soft interior portion. In accordance with this method the surfaces of the mold cavity are coated with an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms before the curable organosiloxane used to form the interior portion of the molding is injected into the mold cavity and cured.

摘要翻译： 本发明提供一种由均匀，平滑且硬的外层和相对柔软的内部组成的硅橡胶模制品的制造方法。 根据该方法，在将用于形成模制件的内部的可固化的有机硅氧烷注射到模腔中并固化之前，模腔的表面涂覆有含有至少两个与硅键合的氢原子的有机氢聚硅氧烷。

公开(公告)号：US4743670A

公开(公告)日：1988-05-10

申请号：US95794

申请日：1987-09-14

申请人： Keiji Yoshida ,  Koji Shimizu ,  Mitsuo Hamada

发明人： Keiji Yoshida ,  Koji Shimizu ,  Mitsuo Hamada

IPC分类号： C08J3/03 ,  C08J3/16 ,  C08J3/26 ,  C08G77/06

CPC分类号： C08J3/03 ,  C08J3/16 ,  C08J3/26 ,  C08J2383/04

摘要： Cured silicone rubber in the form of a finely divided powder is prepared by (1) dispersing a heat-curable liquid silicone rubber composition in water maintained at a temperature of from 0.degree. to 25.degree. C., (2) dispersing the resultant dispersion in a liquid heated to a temperature of at least 50.degree. C., and (3) recovering the resultant cured powder. The liquid silicone rubber composition is preferably maintained at a temperature of from -60.degree. to 0.degree. C. before being emulsified and said liquid is preferably water.

摘要翻译： 通过（1）将热固性液体硅橡胶组合物分散在保持在0℃至25℃的水中的水中制备细粉末形式的固化硅橡胶，（2）将所得分散体分散在 加热到至少50℃的温度的液体，（3）回收得到的固化粉末。 液体硅橡胶组合物优选在乳化之前保持在-60℃至0℃的温度，并且所述液体优选为水。

公开(公告)号：US20070155893A1

公开(公告)日：2007-07-05

申请号：US11680934

申请日：2007-03-01

申请人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

发明人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

IPC分类号： C08L83/00

CPC分类号： B01F3/0807 ,  B01F5/061 ,  B01F5/0682 ,  B01F5/0688 ,  B01F7/00758 ,  B01F13/103 ,  C08J3/03 ,  C08J2383/04

摘要： Method for preparation of an aqueous emulsion from a curable silicone composition consisting of (A) an organopolysiloxane having at least two silicon-bonded hydroxyl groups, (B) an organohydrogensiloxane, and (C) a curing catalyst, said method being characterized by (i) continuously supplying component (A), component (B) and component (C), or a mixture of components (A) and (B) and component (C) through individual inlet ports into a continuous mixer and mixing said components at a temperature not exceeding 10° C., (ii) continuously supplying the obtained mixture and (D) an aqueous solution of a surface-active agent to an emulsifier, and emulsifying the components at a temperature not exceeding 20° C. An apparatus for the preparation of an aqueous emulsion of a curable silicone composition comprising of a continuous mixer for mixing components (A) through (C), a distribution unit connected to the lower part of the mixer, and an emulsifier. Method for preparation of a suspension of cured silicone particles by allowing such emulsion to stand at room temperature, or heating the aforementioned emulsion.

摘要翻译： 由（A）具有至少两个与硅键合的羟基的有机聚硅氧烷，（B）有机氢硅氧烷和（C）固化催化剂）组成的可固化有机硅组合物制备水乳液的方法，所述方法的特征在于（i ）将组分（A），组分（B）和组分（C）或组分（A）和组分（B）和组分（C）的混合物通过各个入口端连续供给到连续混合器中，并在所述组分 不超过10℃，（ii）将所得混合物和（D）表面活性剂的水溶液连续供给到乳化剂中，并在不超过20℃的温度下乳化该组分。 的可固化硅氧烷组合物的水性乳液，其包含用于混合组分（A）至（C）的连续混合器，与混合器的下部连接的分配单元和乳化剂。 通过使这种乳液在室温下放置或加热上述乳液来制备固化的硅氧烷颗粒的悬浮液的方法。

公开(公告)号：US5025054A

公开(公告)日：1991-06-18

申请号：US433802

申请日：1989-11-09

申请人： Keiji Yoshida ,  Mitsuo Hamada

发明人： Keiji Yoshida ,  Mitsuo Hamada

IPC分类号： C09G1/00 ,  C09G1/02 ,  C09G1/12

CPC分类号： C09G1/12

摘要： A polish including a film forming wax material and a silicone rubber. The rubber is in the form of particles mixed with the film forming wax, and the silicone rubber particles contain a silicone oil. The particles have an average diameter of from about 0.3 .mu.m to about 30 .mu.m. The polish includes at least one additive selected from the group consisting of organic solvents, a second silicone oil, and surfactants. The film forming wax material is one of carnauba wax, montan wax, candelilla wax, ceresin wax, paraffin waxes, or beeswax. The silicone rubber forming the particles is one of addition reaction curable silicone rubber compositions, condensation reaction curable silicone rubber compositions, organic peroxide curable organopolysiloxane compositions, or high energy curable silicone rubber compositions.

摘要翻译： 包括成膜蜡材料和硅橡胶的抛光剂。 橡胶是与成膜蜡混合的颗粒的形式，硅橡胶颗粒含有硅油。 颗粒的平均直径为约0.3μm至约30μm。 抛光剂包括至少一种选自有机溶剂，第二硅油和表面活性剂的添加剂。 成膜蜡材料是巴西棕榈蜡，褐煤蜡，小烛树蜡，纯地蜡，石蜡或蜂蜡中的一种。 形成颗粒的硅橡胶是加成反应可固化的硅橡胶组合物，缩合反应可固化的硅橡胶组合物，有机过氧化物可固化的有机聚硅氧烷组合物或高能可固化的硅橡胶组合物之一。

公开(公告)号：US4946893A

公开(公告)日：1990-08-07

申请号：US275498

申请日：1988-11-23

申请人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

发明人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

IPC分类号： B29B9/12 ,  B29K83/00 ,  C08J3/12 ,  C08J3/205 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07

CPC分类号： C08J3/205 ,  C08L83/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/70 ,  C08J2383/04

摘要： Cured silicone rubber powder containing large amounts of particulate material formed by dispersing a liquid silicone rubber composition curable by a platinum-catalyzed hydrosilation reaction into water. The presence of a low molecular weight, volatile polydiorganosiloxane makes it possible to incorporate at least 100 parts by weight of particulate material per 100 parts of curable polydiorganosiloxane into the composition. The volatile polydiorganosiloxane is removed from the cured polwder. Finely divided magnetic metals, electrically conductive materials and reinforcing silica powders can be incorporated using the present method.

公开(公告)号：US4985483A

公开(公告)日：1991-01-15

申请号：US411136

申请日：1989-09-22

申请人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

发明人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

IPC分类号： C08K5/54 ,  C08K5/5435 ,  C08L27/12 ,  C08L27/16 ,  C08L83/04 ,  C08L83/07 ,  C08L83/08 ,  C08L87/00 ,  C09J127/12 ,  C09J183/07

CPC分类号： C08K5/54 ,  C08L27/12 ,  C08L27/16 ,  C08L83/08 ,  C08L2205/22 ,  C08L83/04

摘要： Curable fluororubber compositions exhibit excellent processability on roll mills and can be molded without sticking to or staining the mold surfaces when the composition contains from 0.1 to 30 weight parts per 100 weight parts of fluororubber of a finely divided cured silicone material in the form of a rubber, gel or resin. An epoxy-substituted alkoxysilane or a partial hydrolysis product thereof is present as an ingredient of the curable composition when it is desired to cohesively bond the cured fluororubber to a metal or plastic substrate.

公开(公告)号：US07452195B2

公开(公告)日：2008-11-18

申请号：US11680934

申请日：2007-03-01

申请人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

发明人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

IPC分类号： B29B9/06

CPC分类号： B01F3/0807 ,  B01F5/061 ,  B01F5/0682 ,  B01F5/0688 ,  B01F7/00758 ,  B01F13/103 ,  C08J3/03 ,  C08J2383/04

摘要： Method for preparation of an aqueous emulsion from a curable silicone composition consisting of (A) an organopolysiloxane having at least two silicon-bonded hydroxyl groups, (B) an organohydrogensiloxane, and (C) a curing catalyst, said method being characterized by (i) continuously supplying component (A), component (B) and component (C), or a mixture of components (A) and (B) and component (C) through individual inlet ports into a continuous mixer and mixing said components at a temperature not exceeding 10° C., (ii) continuously supplying the obtained mixture and (D) an aqueous solution of a surface-active agent to an emulsifier, and emulsifying the components at a temperature not exceeding 20° C. An apparatus for the preparation of an aqueous emulsion of a curable silicone composition comprising of a continuous mixer for mixing components (A) through (C), a distribution unit connected to the lower part of the mixer, and an emulsifier. Method for preparation of a suspension of cured silicone particles by allowing such emulsion to stand at room temperature, or heating the aforementioned emulsion.

摘要翻译： 由（A）具有至少两个与硅键合的羟基的有机聚硅氧烷，（B）有机氢硅氧烷和（C）固化催化剂）组成的可固化有机硅组合物制备水乳液的方法，所述方法的特征在于（i ）将组分（A），组分（B）和组分（C）或组分（A）和组分（B）和组分（C）的混合物通过各个入口端连续供给到连续混合器中，并在所述组分 不超过10℃，（ii）将所得混合物和（D）表面活性剂的水溶液连续供给到乳化剂中，并在不超过20℃的温度下乳化该组分。 的可固化硅氧烷组合物的水性乳液，其包含用于混合组分（A）至（C）的连续混合器，与混合器的下部连接的分配单元和乳化剂。 通过使这种乳液在室温下放置或加热上述乳液来制备固化的硅氧烷颗粒的悬浮液的方法。

公开(公告)号：US5002995A

公开(公告)日：1991-03-26

申请号：US420984

申请日：1989-10-13

申请人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

发明人： Masayuki Saito ,  Keiji Yoshida ,  Mitsuo Hamada

IPC分类号： C08L33/04 ,  C08K3/00 ,  C08L33/08 ,  C08L83/04

CPC分类号： C08K3/0033 ,  C08L33/08 ,  C08L83/04

摘要： An acrylic rubber composition containing an amino group-containing silicon compound is characterized by excellent roll workability and a rapid vulcanization rate and characteristically does not require secondary vulcanization.

公开(公告)号：US07202301B2

公开(公告)日：2007-04-10

申请号：US10475451

申请日：2002-04-26

申请人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

发明人： Kazuhiko Ando ,  Keiji Yoshida ,  Toyohiko Yamadera ,  Yoshitsugu Morita ,  Mitsuo Hamada

IPC分类号： C08G77/06

CPC分类号： B01F3/0807 ,  B01F5/061 ,  B01F5/0682 ,  B01F5/0688 ,  B01F7/00758 ,  B01F13/103 ,  C08J3/03 ,  C08J2383/04

摘要： Method for preparation of an aqueous emulsion from a curable silicone composition consisting of (A) an organopolysiloxane having at least two silicon-bonded hydroxyl groups, (B) an organohydrogensiloxane, and (C) a curing catalyst, said method being characterized by (i) continuously supplying component (A), component (B) and component (C), or a mixture of components (A) and (B) and component (C) through individual inlet ports into a continuous mixer and mixing said components at a temperature not exceeding 10° C., (ii) continuously supplying the obtained mixture and (D) an aqueous solution of a surface-active agent to an emulsifier, and emulsifying the components at a temperature not exceeding 20° C. An apparatus for the preparation of an aqueous emulsion of a curable silicone composition comprising of a continuous mixer for mixing components (A) through (C), a distribution unit connected to the lower part of the mixer, and an emulsifier. Method for preparation of a suspension of cured silicone particles by allowing such emulsion to stand at room temperature, or heating the aforementioned emulsion.

摘要翻译： 由（A）具有至少两个与硅键合的羟基的有机聚硅氧烷，（B）有机氢硅氧烷和（C）固化催化剂）组成的可固化有机硅组合物制备水乳液的方法，所述方法的特征在于（i ）将组分（A），组分（B）和组分（C）或组分（A）和组分（B）和组分（C）的混合物通过各个入口端连续供给到连续混合器中，并在所述组分 不超过10℃，（ii）将所得混合物和（D）表面活性剂的水溶液连续供给到乳化剂中，并在不超过20℃的温度下乳化该组分。 的可固化硅氧烷组合物的水性乳液，其包含用于混合组分（A）至（C）的连续混合器，与混合器的下部连接的分配单元和乳化剂。 通过使这种乳液在室温下放置或加热上述乳液来制备固化的硅氧烷颗粒的悬浮液的方法。

公开(公告)号：US4749741A

公开(公告)日：1988-06-07

申请号：US29123

申请日：1987-03-23

申请人： Masayuki Saito ,  Koji Shimizu ,  Mitsuo Hamada

发明人： Masayuki Saito ,  Koji Shimizu ,  Mitsuo Hamada

IPC分类号： C08G79/00 ,  C09J4/00 ,  C08L83/02

CPC分类号： C08G79/00 ,  C09J4/00

摘要： Cohesive bonding between silicone rubber compositions and plastics is achieved using primer compositions comprising a solution of at least one member of a specified class of organotitanate esters in an organic liquid. Cohesive bonding of silicone rubber compositions to both plastic and metals is achieved by including at least one member from either of two specified classes of organosilicon compounds in the primer composition together with the organotitanate ester.

摘要翻译： 使用底漆组合物实现硅橡胶组合物和塑料之间的粘合粘合，所述底漆组合物包含有机钛酸酯中至少一种成分在有机液体中的溶液。 通过将两种特定类别的有机硅化合物中的至少一种与有机钛酸酯一起包括在底漆组合物中，来实现硅橡胶组合物与塑料和金属的粘合。