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    Process for the preparation of finely divided, water-swellable polysaccharide graft polymers
    2.
    发明授权
    Process for the preparation of finely divided, water-swellable polysaccharide graft polymers 失效
    精细分散的水溶性多糖聚酰胺的制备方法

    公开(公告)号：US5180800A

    公开(公告)日：1993-01-19

    申请号：US695223

    申请日：1991-05-03

    申请人： Klaus Heidel ,  Frank Krause ,  Peter Hofmann

    发明人： Klaus Heidel ,  Frank Krause ,  Peter Hofmann

    IPC分类号： C08F2/14 ,  C08F2/18 ,  C08F2/32 ,  C08F251/00

    CPC分类号： C08F251/00

    摘要： Finely divided polysaccharide graft polymers having a high absorption capacity for urine and water are prepared by semi-continuous reverse-phase suspension polymerization, in which an aqueous solution of an unsaturated carboxylic acid and an initiator is metered continuously into a suspension of a polysaccharide in an organic solvent and the polymer obtained is subsequently partial dehydrated and the crosslinked.

    摘要翻译： 通过半连续反相悬浮聚合制备具有对尿和水的高吸收能力的细分多糖接枝聚合物，其中将不饱和羧酸和引发剂的水溶液连续计量加入到多糖的悬浮液中 得到的聚合物随后部分脱水并交联。

    Bonding of fibre-reinforced material with an injection-moulding material; component and apparatus for conduct of the process
    3.
    发明授权
    Bonding of fibre-reinforced material with an injection-moulding material; component and apparatus for conduct of the process 有权
    纤维增强材料与注射成型材料的接合; 用于进行该过程的部件和装置

    公开(公告)号：US08771574B2

    公开(公告)日：2014-07-08

    申请号：US12280841

    申请日：2007-02-19

    申请人： Frank Krause

    发明人： Frank Krause

    IPC分类号： B29C70/42 ,  B29C45/14

    CPC分类号： B29C45/14311 ,  B29C45/1418 ,  B29C45/14786 ,  B29C2045/14286 ,  B29C2045/14877 ,  Y10T428/24826 ,  Y10T428/2929

    摘要： The invention relates to a process for the bonding of a fiber-reinforced material to an injection-molding material. The invention further relates to an article produced according to the process.It is an object of the invention to improve the bond between a fiber-reinforced starting material and a material applied by injection.To achieve the object, a fiber-reinforced plastics material is heated locally, and further plastics material is applied by injection. This produces a particularly good coherent bond between the further plastics material and the fiber-reinforced plastics material. Ease of handling is also provided.The invention relates to a component produced according to the process and also to an apparatus for carrying out the process.

    摘要翻译： 本发明涉及一种将纤维增强材料粘合到注射成型材料上的方法。 本发明还涉及根据该方法生产的制品。 本发明的目的是改善纤维增强起始材料与通过注射施加的材料之间的粘结。 为了实现该目的，纤维增强塑料材料被局部加热，并且通过注射施加另外的塑料材料。 这在另外的塑料材料和纤维增强塑料材料之间产生特别好的粘结。 还提供了便于处理。 本发明涉及根据该方法生产的部件以及用于执行该方法的装置。

    Reinforcement Element for a Vehicle Hollow Body
    4.
    发明申请
    Reinforcement Element for a Vehicle Hollow Body 审中-公开
    汽车空心体的增强元件

    公开(公告)号：US20080296164A1

    公开(公告)日：2008-12-04

    申请号：US12131496

    申请日：2008-06-02

    申请人： Ulrich Dajek ,  Ralf Zimnol ,  Frank Krause ,  Boris Koch ,  Martin Klocke

    发明人： Ulrich Dajek ,  Ralf Zimnol ,  Frank Krause ,  Boris Koch ,  Martin Klocke

    IPC分类号： B32B3/20 ,  C25D5/00

    CPC分类号： B62D29/002 ,  B62D29/004 ,  Y10T428/24744

    摘要： The present invention relates to one-piece reinforcement elements consisting of an elongate shell-shaped basic body, the inner space of which has reinforcement ribs which are fixedly connected to the basic body, the reinforcement ribs consisting of plastic injection-molded on and their connection to the basic body taking place at discrete connection points via perforations in the basic body through which the plastic passes and extends over the surfaces of the perforations, and of a rigid structure reinforcement which is appended from the same plastic, by means of the same injection-molded operation, at at least one end of the basic body and which corresponds essentially to the form of the cross section of the hollow profile to be reinforced at this point of a body, an expandable adhesive material being applied over a portion of the surface of the rigid structure reinforcement and of the elongate shell-shaped basic body, the form of the rigid structure reinforcement and of the elongate basic body and also the quantity and distribution of the expandable adhesive being selected such that the adhesive material, during expansion, does not touch the inner surface of the outer panel of the body cavity to be reinforced and touches and adheres to at least part of the other inner walls of the body cavity to be reinforced, to the production of these and to their use.

    摘要翻译： 本发明涉及一体式增强元件，其由细长的壳状基体组成，其内部空间具有固定地连接到基体的加强肋，加强肋由注射成型的塑料及其连接 通过基体中的穿孔在塑料通过并延伸穿过穿孔表面的离散连接点上发生的基体，以及通过相同的注射从同一塑料附加的刚性结构加强件 在基体的至少一端处，并且其基本上对应于在本体的该点处被加强的中空型材的横截面的形状，可膨胀的粘合剂材料施加在表面的一部分上 的刚性结构加固件和细长壳体基体，刚性结构加强件和细长件的形式 碱性体以及可膨胀粘合剂的数量和分布被选择为使得粘合剂材料在膨胀期间不接触待加强的体腔外板的内表面并且接触和粘附到至少部分 体腔的其他内壁需要加固，以生产这些和使用它们。

    Absorbent inserts, method of producing them and their use
    6.
    发明授权
    Absorbent inserts, method of producing them and their use 有权
    吸收性插入物，其制造方法及其用途

    公开(公告)号：US06350710B1

    公开(公告)日：2002-02-26

    申请号：US09147476

    申请日：1999-02-25

    申请人： Gerd Jonas ,  Helmut Klimmek ,  Frank Krause ,  Klaus Pflüger

    发明人： Gerd Jonas ,  Helmut Klimmek ,  Frank Krause ,  Klaus Pflüger

    IPC分类号： B32B516

    CPC分类号： B32B3/266 ,  B01J20/28021 ,  B01J20/28023 ,  B01J20/28033 ,  B01J20/2805 ,  B32B3/30 ,  B32B5/22 ,  B32B23/00 ,  B32B27/00 ,  B32B2264/02 ,  B32B2307/726 ,  B32B2439/70 ,  C08F261/04 ,  C08F281/00 ,  C08F290/062 ,  Y10T428/237 ,  Y10T428/31504 ,  Y10T442/2484 ,  Y10T442/2525 ,  Y10T442/664 ,  Y10T442/673

    摘要： The invention relates to an absorbent insert for foodstuff packagings, the liquid-absorbing component of which is a superabsorbent polymer which, in a hitherto unrivaled fashion, persistently absorbs and retains large quantities of liquid even under high pressure load, protects the foodstuffs from bacterial decay, and prevents contamination of the packaging goods by migrating soluble constituents of the polymer. This combination of properties of the superabsorbers used is expressed by the QSAP 0.3 quotient of retention according to the tea bag test+absorption against pressure (AAP) 0.3, divided by the amount of solubles (LA), which quotient is at least 20. Superabsorbers having such properties are obtained by using special combinations of crosslinkers. Furthermore, the invention relates to a process for producing said absorbent inserts and their use in foodstuff packagings, as ice substitute, and as leak-proofing means in transport packagings.

    摘要翻译： 本发明涉及一种用于食品容器的吸收性插入物，其液体吸收组分是超吸收聚合物，其以至无可比拟的方式即使在高压力负载下仍持续吸收并保留大量液体，保护食品免受细菌衰变 并且通过迁移聚合物的可溶性成分来防止包装物质的污染。 所使用的超吸收剂的这种性质的组合由根据茶包试验+吸收压力（AAP）0.3的QSAP 0.3保留量除以可商品（LA）的量，该商为至少20.超吸收剂 通过使用交联剂的特殊组合获得这些性质。 此外，本发明涉及一种生产所述吸收性插入物的方法及其在食品容器中的用途，作为冰替代物，以及用作运输包装中的防漏装置。

    Interpolymers of unsaturated carboxylic acids and unsaturated sulfur acids
    7.
    发明授权
    Interpolymers of unsaturated carboxylic acids and unsaturated sulfur acids 失效
    不饱和羧酸和不饱和硫酸的共聚物

    公开(公告)号：US06207780B1

    公开(公告)日：2001-03-27

    申请号：US08925460

    申请日：1997-09-08

    申请人： Dolf Stockhausen ,  Helmut Klimmek ,  Frank Krause ,  Matthias Berghahn

    发明人： Dolf Stockhausen ,  Helmut Klimmek ,  Frank Krause ,  Matthias Berghahn

    IPC分类号： C08F22802

    CPC分类号： C11D3/378 ,  C08F8/44 ,  C08F220/04 ,  C08F222/02 ,  C08F228/02 ,  C11D3/394 ,  C14C3/20 ,  C14C9/02 ,  C14C9/04 ,  D06L4/12 ,  D06M15/263 ,  D06M15/333 ,  D06M15/3566 ,  D06P1/5214 ,  D06P1/5221 ,  D06P1/5228 ,  D06P1/525 ,  D06P1/5257 ,  D06P5/08 ,  C08F8/12 ,  C08F220/06 ,  C08F222/06 ,  C08F218/08

    摘要： The present invention relates to water-soluble polymers built up of a) monoethylenically unsaturated dicarboxylic acids and/or their salts, b) monoethylenically unsaturated monocarboxylic acids and/or their salts, c) monounsaturated monomers which, after hydrolysis or saponification, can be converted into monomers having a hydroxyl group covalently bonded at the C—C-chain, d) monoethylenically unsaturated sulfonic acid groups or sulfate groups-containing monomers, and optionally e) further radically copolymerizable monomers, with the sum of the monomers of a) to e) amounting to 100%. The present invention further relates to a process for the production of these polymers by radical polymerization and hydrolysis in aqueous medium, and to the use of these polymers as additive or cobuilder in detergents and cleaners, in the pretreatment of cotton, as bleaching stabilizers, as auxiliary agent in textile printing, and in the manufacture of leather, as well as for the inhibition of water hardness, and as dispersing agent as well as detergents and cleaners.

    摘要翻译： 本发明涉及由a）单烯属不饱和二羧酸和/或其盐组成的水溶性聚合物，b）单烯属不饱和一元羧酸和/或其盐，c）单不饱和单体，其在水解或皂化后可转化为 具有在CC链上共价结合的羟基的单体，d）单烯键式不饱和磺酸基或含硫酸基的单体，以及任选的另外的可自由基共聚的单体，a）至e）的单体总和为100 本发明还涉及通过在水性介质中自由基聚合和水解制备这些聚合物的方法，以及这些聚合物作为添加剂或助洗剂在洗涤剂和清洁剂中的用途，在棉花的预处理中作为漂白稳定剂 ，作为纺织印染助剂，以及皮革的制造，以及抑制水硬度，a nd作为分散剂以及洗涤剂和清洁剂。

    Graft copolymers of unsaturated monomers and sugars, a process for the production and the use thereof
    8.
    发明授权
    Graft copolymers of unsaturated monomers and sugars, a process for the production and the use thereof 失效
    不饱和单体和糖的接枝共聚物，其制备方法和用途

    公开(公告)号：US5854191A

    公开(公告)日：1998-12-29

    申请号：US713538

    申请日：1996-09-13

    申请人： Frank Krause ,  Helmut Klimmek

    发明人： Frank Krause ,  Helmut Klimmek

    IPC分类号： D06L3/00 ,  B01F17/52 ,  C02F5/00 ,  C08F220/02 ,  C08F220/04 ,  C08F251/00 ,  C08L51/02 ,  C09B67/42 ,  C09D17/00 ,  C09D151/02 ,  C11D3/37 ,  C14C3/00 ,  D06L1/00 ,  D06M15/03 ,  D06M101/00 ,  D06M101/02 ,  D06M101/16 ,  D06P1/52 ,  D06P5/08 ,  D21H17/24 ,  D06P5/00

    CPC分类号： D06P5/08 ,  C08F220/04 ,  C08F251/00 ,  C08L51/02 ,  C09D151/02 ,  C09D17/004 ,  C11D3/3788 ,  C14C3/00 ,  D06P1/5207

    摘要： The present invention relates to water-soluble, acid-groups-containing graft copolymers which are at least partially biodegradable and are based on sugars and monoethylenically unsaturated carboxylic acids, sulfonic acids and/or phosphonic acids or the salts of said acids as well as optional further monomers. The present invention further relates to a process for producing the graft copolymers at temperatures of up to 200.degree. C. by means of-radical polymerization initiators, in that a total mixture of 5-60%-wt. mono-, di- and oligosaccharides, the derivatives thereof or the mixtures thereof, and 95-40%-wt. of a monomer mixture comprising at least one monoethylenically unsaturated carboxylic acid, at least one monoethylenically unsaturated sulfonic acid, one monoethylenically unsaturated sulfuric acid ester and/or vinylphosphonic acid or the salts of said acids with monovalent cations, as well as optional further monomers is polymerized. The present invention further relates to the use of the graft copolymers in aqueous systems, for binding multivalent metal ions, inhibiting the water hardness, as additive in detergents and cleaning agents, as textile auxiliary, dispersing agent, in particular for pigments, and as auxiliary agent in the production of paper and leather.

    摘要翻译： 本发明涉及至少部分可生物降解并且基于糖和单烯键式不饱和羧酸，磺酸和/或膦酸或所述酸的盐以及任选的可溶于水的可溶于酸的基团的接枝共聚物 进一步的单体。 本发明还涉及一种通过自由基聚合引发剂在高达200℃的温度下生产接枝共聚物的方法，其中5-60重量％ 单糖，二糖和寡糖，其衍生物或其混合物，和95-40重量％ 包含至少一种单烯属不饱和羧酸，至少一种单烯属不饱和磺酸，一个单烯属不饱和硫酸酯和/或乙烯基膦酸或所述酸与一价阳离子的盐以及任选的其它单体的单体混合物被聚合 。 本发明还涉及在水系统中用于结合多价金属离子，抑制水硬度，作为洗涤剂和清洁剂中的添加剂的用途，作为纺织助剂，分散剂，特别是颜料和助剂 代理生产纸和皮革。

    Solar thermal collector
    9.
    发明申请
    Solar thermal collector 审中-公开
    太阳能集热器

    公开(公告)号：US20060130827A1

    公开(公告)日：2006-06-22

    申请号：US11313035

    申请日：2005-12-20

    申请人： Gerhard Opelka ,  Frank Krause ,  Constantin Schwecke

    发明人： Gerhard Opelka ,  Frank Krause ,  Constantin Schwecke

    IPC分类号： F24J2/24

    CPC分类号： F24S10/73 ,  F24S10/501 ,  F24S10/80 ,  Y02E10/44

    摘要： A solar thermal collector comprising multiplicity of chords and webs is disclosed. The first, second and third horizontal chord of the solar thermal collector are connected to one another by webs positioned vertically to said horizontal chords. The first horizontal chord is transparent and the second horizontal chord, which is positioned between the first and third horizontal chords, absorbs thermal radiation and is perforated. The horizontal chords and said webs of the inventive solar thermal collector comprise thermoplastic materials. Producing the solar thermal collector including perforating the second horizontal chord by means of a laser beam is also disclosed.

    摘要翻译： 公开了一种包括多个弦和腹板的太阳能热收集器。 太阳能热收集器的第一，第二和第三水平弦通过垂直定位到所述水平和弦的腹板彼此连接。 第一个水平和弦是透明的，位于第一和第三个水平和弦之间的第二个水平弦吸收热辐射并被穿孔。 本发明的太阳能热收集器的水平和弦和所述腹板包括热塑性材料。 还公开了通过激光束穿透第二水平弦的太阳能热收集器的生产。