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    Crosslinkable polymer composition
    2.
    发明授权
    Crosslinkable polymer composition 失效
    可交联聚合物组合物

    公开(公告)号：US06884837B2

    公开(公告)日：2005-04-26

    申请号：US09804495

    申请日：2001-03-12

    申请人： Klaus Kohlhammer ,  Abdulmajid Hashemzadeh

    发明人： Klaus Kohlhammer ,  Abdulmajid Hashemzadeh

    IPC分类号： C08J3/12 ,  C03C25/32 ,  C08F2/04 ,  C08F2/22 ,  C08G81/02 ,  C08L25/14 ,  C08L33/06 ,  C08L35/06 ,  C08L101/02 ,  C08L101/08 ,  D04H1/4218 ,  D04H1/593 ,  D04H1/60 ,  D04H1/64 ,  D04H1/68 ,  D06M15/227 ,  D06M15/233 ,  D06M15/244 ,  D06M15/263 ,  D06M15/273 ,  D06M15/327 ,  D06M15/347 ,  D06M15/356 ,  D06M23/08 ,  C08K3/20 ,  C08F8/30

    CPC分类号： D04H1/64 ,  C03C25/32 ,  C08G81/021 ,  C08L25/14 ,  C08L33/06 ,  C08L33/066 ,  C08L35/06 ,  C08L2205/02 ,  D04H1/4218 ,  D04H1/593 ,  D04H1/60 ,  D04H1/68 ,  D06M15/227 ,  D06M15/233 ,  D06M15/244 ,  D06M15/263 ,  D06M15/273 ,  D06M15/327 ,  D06M15/347 ,  D06M15/3562 ,  D06M23/08 ,  C08L2666/04

    摘要： The present invention provides a crosslinkable polymer composition in the form of its aqueous polymer dispersion or polymer powder, including A) a copolymer having a glass transition temperature Tg or a melting temperature of ≧30° C. and containing units derived from one or more comonomers selected from the group consisting of vinyl esters of branched or unbranched alkylcarboxylic acids of 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides and from 0.1 to 50% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated carboxyl-containing comonomers, and B) a copolymer containing units derived from one or more comonomers selected from the group consisting of vinyl esters of branched or unbranched alkylcarboxylic acids of 1 to 18 carbon atoms, acrylic esters or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides and from 0.1 to 50% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers having functional groups capable of entering a covalent bond with the carboxyl groups of said copolymer A).

    摘要翻译： 本发明提供其聚合物水分散体或聚合物粉末形式的可交联聚合物组合物，其包括A）具有玻璃化转变温度Tg或熔点> 30℃的共聚物，并且含有衍生自一个或多个 选自由1至18个碳原子的支链或非支链烷基羧酸的乙烯基酯组成的组的共聚单体，1至15个碳原子的支链或非支链醇的丙烯酸酯或甲基丙烯酸酯，二烯，烯烃，乙烯基芳族化合物和乙烯基卤化物， 0.1至50重量％，基于共聚单体的总重量，一种或多种烯属不饱和羧酸的共聚单体，和B）含有衍生自一种或多种共聚单体的共聚物的共聚物，所述共聚单体选自由支链 或1-18个碳原子的无支链烷基羧酸，1-15个碳原子的支链或非支链醇的丙烯酸酯或甲基丙烯酸酯 原子，二烯，烯烃，乙烯基芳烃和乙烯基卤化物，和基于共聚单体总重量的0.1-50重量％的一种或多种具有能够与羧基共价键的官能团的烯属不饱和共聚单体 所述共聚物A）。

    Process for forming recyclable articles
    3.
    发明授权
    Process for forming recyclable articles 失效
    形成可回收物品的方法

    公开(公告)号：US06695993B2

    公开(公告)日：2004-02-24

    申请号：US10056273

    申请日：2002-01-25

    申请人： Abdulmajid Hashemzadeh ,  Klaus Kohlhammer ,  Konrad Alfons Wierer ,  Herbert Pröbstl

    发明人： Abdulmajid Hashemzadeh ,  Klaus Kohlhammer ,  Konrad Alfons Wierer ,  Herbert Pröbstl

    IPC分类号： A29B1114

    CPC分类号： B29B17/0042 ,  B29K2101/10 ,  B29K2105/06 ,  C08K9/08 ,  D04H1/4218 ,  D04H1/4266 ,  D04H1/435 ,  D04H1/587 ,  D04H1/64 ,  Y02W30/62 ,  C08L33/04

    摘要： A process for forming particulate materials and binders into articles that are reusable after comminution, wherein the particulate materials are treated with a binder composition containing. A) one or more copolymers containing one or more comonomer units selected from the group consisting of vinyl esters of branched or unbranched alkyl carboxylic acids of 1 to 18 carbon atoms, acrylic or methacrylic esters of branched or unbranched alcohols of 1 to 15 carbon atoms, dienes, olefins, vinyl aromatics and vinyl halides, and further containing 4 to 60% by weight, based on the total weight of the copolymer, of one or more comonomer units containing polar groups, and B) one or more fillers having a polar surface capable of interaction with the polar groups of copolymer A), and formed into articles and consolidated, and, if appropriate, the formed article obtained thereby is comminuted for recycling and the material obtained thereby is reused for forming new articles.

    摘要翻译： 一种将颗粒材料和粘合剂形成物料的方法，其在粉碎后可重复使用，其中所述颗粒材料用含有的粘合剂组合物处理。A）一种或多种含有一种或多种共聚单体单元的共聚物，所述共聚单体选自乙烯基支链 或1至18个碳原子的无支链烷基羧酸，1至15个碳原子的支链或非支链醇的丙烯酸或甲基丙烯酸酯，二烯，烯烃，乙烯基芳族化合物和乙烯基卤化物，并且还包含4至60重量％ 共聚物，含有极性基团的一种或多种共聚单体单元的总重量，和B）具有能与共聚物A的极性基团相互作用的极性表面的一种或多种填料），并形成制品并固化，如果合适 将由此获得的成型体粉碎以进行再循环，由此得到的材料再次用于形成新的制品。

    Process for the cold molding of particulate materials
    4.
    发明授权
    Process for the cold molding of particulate materials 失效
    颗粒材料冷成型工艺

    公开(公告)号：US06774161B2

    公开(公告)日：2004-08-10

    申请号：US10354479

    申请日：2003-01-30

    申请人： Abdulmajid Hashemzadeh ,  Klaus Kohlhammer ,  Thomas Lehmann ,  Peter Weiler

    发明人： Abdulmajid Hashemzadeh ,  Klaus Kohlhammer ,  Thomas Lehmann ,  Peter Weiler

    IPC分类号： C08J300

    CPC分类号： C08J5/04

    摘要： Particulate materials are cold molded by preheating a binder and the material to be bound to a temperature of from 160 to 240° C., and then press molding at a temperature less than 80° C. and at a pressure of from 1 to 120 bar to give a molding, wherein the binder contains a polymer powder or aqueous polymer dispersion thereof, the polymer having a glass transition temperature Tg greater than 80° C. and a complex viscosity less than 15,000 Pa·s at 190° C., and derived from one or more comonomer units from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics, and vinyl halides. The moldings exhibit excellent properties including resistance to sagging at elevated temperatures, and are recyclable.

    摘要翻译： 颗粒材料通过预热粘合剂和要结合到160至240℃的温度的材料进行冷成型，然后在低于80℃的温度和1至120巴的压力下进行压制成型 其中粘合剂含有聚合物粉末或其聚合物水分散体，该聚合物的玻璃化转变温度Tg大于80℃，复数粘度在190℃下小于15,000Pa.s，并得到 来自一个或多个共聚单体单元，任选支化的C 1-18烷基羧酸的乙烯基酯，任选支链的C 1-15醇的（甲基）丙烯酸酯，二烯，烯烃，乙烯基芳烃和卤代乙烯。 模制品具有优异的性能，包括在高温下的下垂阻力，并且是可回收的。

    Process for preparing cationic polyvinyl acetals
    7.
    发明授权
    Process for preparing cationic polyvinyl acetals 失效
    制备阳离子聚乙烯醇缩醛的方法

    公开(公告)号：US07498391B2

    公开(公告)日：2009-03-03

    申请号：US11430397

    申请日：2006-05-09

    申请人： Abdulmajid Hashemzadeh ,  Bernhard Glaser

    发明人： Abdulmajid Hashemzadeh ,  Bernhard Glaser

    IPC分类号： C08F20/10 ,  C08F220/10 ,  C08F2/00 ,  C08F118/02 ,  C08F22/26 ,  C08F118/16 ,  C08F122/26 ,  C08F218/16 ,  C08F8/00

    CPC分类号： C08F2/18 ,  C08F8/12 ,  C08F8/28 ,  C08F2800/20 ,  C09D11/106 ,  C08F216/06 ,  C08F218/08 ,  C08F226/02

    摘要： Cationic polyvinyl acetals are prepared by copolymerizing one or more cationic N-alkyldiallylammonium salt monomers with one or more vinyl esters of branched or unbranched carboxylic acids having 1 to 15 carbon atoms, hydrolyzing the resulting copolymers to copolymers containing ≧50 mol % vinyl alcohol units, and acetalizating the vinyl alcohol units with one or more aliphatic aldehydes having 1 to 15 carbon atoms, their acetals, and/or hemiacetals, wherein the copolymerization takes place in a mixture of water and monovalent aliphatic alcohol having a water content of 2% to 35% by weight.

    摘要翻译： 阳离子聚乙烯醇缩醛通过将一种或多种阳离子N-烷基二烯丙基铵盐单体与一种或多种具有1至15个碳原子的支链或非支链羧酸的乙烯基酯共聚制备，将所得共聚物水解成含有≥50mol％乙烯醇单元的共聚物 并且用一种或多种具有1至15个碳原子的脂肪族醛缩合乙烯醇单元，它们的缩醛和/或半缩醛，其中共聚合在水和含水量为2％的一价脂族醇的混合物中发生， 35重量％。

    Process of making and treating cellulose fibers or yarns with a polysiloxane
    8.
    发明授权
    Process of making and treating cellulose fibers or yarns with a polysiloxane 失效
    用聚硅氧烷制造和处理纤维素纤维或纱线的方法

    公开(公告)号：US6048479A

    公开(公告)日：2000-04-11

    申请号：US860220

    申请日：1997-07-01

    申请人： Abdulmajid Hashemzadeh

    发明人： Abdulmajid Hashemzadeh

    IPC分类号： D06M15/65 ,  D01F2/00 ,  D01F11/02 ,  D01F2/02 ,  D06M15/356

    CPC分类号： D01F11/02 ,  D01F2/00 ,  Y10T428/2933 ,  Y10T428/2965

    摘要： A process for manufacturing cellulose fibers or yarns with a reduced tendency to form fibrils includes treating fibers or yarns, which are washed after the filament forming process but not yet dried, with a cross-linking agent. The process includes treating the fibers or yarns with reactive polysiloxanes which are modified with amino, polyalkylene oxide, epoxy or carboxyl functional groups and which cross-link with themselves. The process is particularly suitable for fibers produced according to the NMMO process.

    摘要翻译： PCT No.PCT / EP95 / 05109 Sec。 371日期1997年7月1日 102（e）日期1997年7月1日PCT 1995年12月22日PCT PCT。 出版物WO96 / 20302 日期1996年7月4日制造纤维素纤维或纱线形成原纤维的趋势的方法包括处理纤维或纱线，其在丝成型过程之后用交联剂进行洗涤，但尚未干燥。 该方法包括用用氨基，聚环氧烷，环氧或羧基官能团改性并与其自身交联的反应性聚硅氧烷处理纤维或纱线。 该方法特别适用于根据NMMO工艺生产的纤维。

    High solids content solutions of organosilicone copolymers with high silicone content and high solids content, and process for preparation thereof, and use thereof
    9.
    发明授权
    High solids content solutions of organosilicone copolymers with high silicone content and high solids content, and process for preparation thereof, and use thereof 有权
    具有高有机硅含量和高固含量的有机硅共聚物的高固含量溶液及其制备方法及其用途

    公开(公告)号：US08318879B2

    公开(公告)日：2012-11-27

    申请号：US12375340

    申请日：2007-08-07

    申请人： Abdulmajid Hashemzadeh

    发明人： Abdulmajid Hashemzadeh

    IPC分类号： C08F30/08

    CPC分类号： C08F283/12 ,  C08F290/068 ,  C08F290/148 ,  C08L51/085 ,  C08L2666/02 ,  C09D151/085 ,  C09J151/085

    摘要： The invention relates to soliconorganocopolymers with high silicon content, with a silicon content of ≧25 wt. % in form of a high solid content solution thereof, with a solid content of >30 wt. %, obtainable with radically initiated solution polymerization of a) 20 to 75 wt. % of one or more ethylenic unsaturated monomers, and b) 25 to 80 wt. % of one or more silicones of the general formula R1aR3−aSiO(SiR2O)nSiR3−aR1a, wherein R is equal or different, and refers to a monovalent, possibly substitutes, alkyle- or alkoxy group with 1 to 18 C-atoms, R1 refers to a polymerizable group, a is 0 or 1 and n=10 to 1000, wherein 85 to 100 wt. % of the silicones b) contain one or two polymerizable groups, wherein silicones b) with only one polymerizable group only in the mixture with silicones b) with two polymerizable groups and in a weight ratio

    摘要翻译： 本发明涉及具有高硅含量的硅含量为≥25wt。 其固体含量高于30重量％的高固含量溶液。 ％，可通过自由基引发的溶液聚合获得，a）20至75wt。 ％的一种或多种烯属不饱和单体，和b）25〜80wt。 通式为R1aR3-aSiO（SiR2O）nSiR3-aR1a的一种或多种硅氧烷，其中R等于或不同，并且是指具有1至18个C原子的单价可能的取代的烷基或烷氧基，R1 是指可聚合基团，a为0或1，n = 10至1000，其中85至100重量％ 硅氧烷的百分数b）含有一个或两个可聚合基团，其中硅氧烷b）仅在与硅氧烷的混合物中仅具有一个可聚合基团b）具有两个可聚合基团，并且使用重量比<50/50。 组分的％指示a）至b）指所用单体的总重量，并加入至100重量份。 其特征在于聚合在溶剂或溶剂混合物中进行，其中硅b）包含小于5wt。 ％在正常条件下。

    Use of Protective Colloid-Stabilized Polymerizates as Low-Profile Additive (LPA)
    10.
    发明申请
    Use of Protective Colloid-Stabilized Polymerizates as Low-Profile Additive (LPA) 审中-公开
    保护性胶体稳定化聚合物作为低轮廓添加剂（LPA）的使用

    公开(公告)号：US20120035314A1

    公开(公告)日：2012-02-09

    申请号：US13258916

    申请日：2010-03-12

    申请人： Abdulmajid Hashemzadeh ,  Rene Gräwe

    发明人： Abdulmajid Hashemzadeh ,  Rene Gräwe

    IPC分类号： C08L33/02 ,  C08L31/04

    CPC分类号： C08J5/24

    摘要： The invention relates to the use of protective colloid-stabilized polymerizates as low profile additive (LPA), characterized in that the protective colloids carry one or more functional group selected from the group comprising carboxyl, sulfate, sulfonate, phosphate, phosphonate, hydroxyl and nitrogen-functional groups, having the stipulation that the mass fraction of the hydroxyl groups equals ≦10 wt % based on the total mass of a protective colloid.

    摘要翻译： 本发明涉及保护性胶体稳定化聚合物作为低分子添加剂（LPA）的用途，其特征在于保护胶体携带一种或多种选自羧基，硫酸酯，磺酸酯，磷酸酯，膦酸酯，羟基和氮的官能团 官能团，其规定羟基的质量分数等于＆lt; nE; 10重量％，基于保护胶体的总质量。