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    Process for the production of perfluoroalkylsulphonyl fluorides and electrodes for performance of the process
    9.
    发明授权
    Process for the production of perfluoroalkylsulphonyl fluorides and electrodes for performance of the process 失效
    用于生产全氟烷基磺酰基氟化物和电极的方法，用于实施该方法

    公开(公告)号：US5364507A

    公开(公告)日：1994-11-15

    申请号：US100241

    申请日：1993-08-02

    申请人： Andreas Bulan ,  Rainer Weber ,  Zbigniew Muziol ,  Hartmut Schlecker ,  Hans-Heinrich Moretto

    发明人： Andreas Bulan ,  Rainer Weber ,  Zbigniew Muziol ,  Hartmut Schlecker ,  Hans-Heinrich Moretto

    IPC分类号： C07C309/80 ,  C07C303/22 ,  C25B3/08 ,  C25B11/04 ,  C25B11/06

    CPC分类号： C07C303/22 ,  C25B11/04 ,  C25B3/08

    摘要： The present invention provides a process for the production of perfluoroalkylsulphonyl fluorides of the formula C.sub.n F.sub.2n+1 SO.sub.2 F with n=6-10 by electrochemical fluorination of alkylsulphonyl halides of the general formula C.sub.n H.sub.2n+1 SO.sub.2 X with n=6-10 and X=F, Cl, Br or I in hydrogen fluoride, which process is characterised in that electrodes are used which consist of nickel with a columnar structure or which are coated with nickel with a columnar structure as shown in FIG. 1.The invention also provides electrodes for the production of perfluoroalkylsulphonyl fluorides from the corresponding alkylsulphonyl halides by electrochemical fluorination in hydrogen fluoride, which electrodes are characterised in that they consist of nickel with a columnar structure or are coated with nickel with a columnar structure.

    摘要翻译： 本发明提供通过电化学氟化通式C n H 2n + 1 SO 2 X的烷基磺酰卤，n = 6-10和X = F，Cl，制备式C n F 2n + 1 SO 2 F的全氟烷基磺酰氟的n = 6-10的方法， Br或I在氟化氢中，其特征在于使用由具有柱状结构的镍组成的电极，或者如图1所示用柱状结构的镍涂覆的电极。 本发明还提供用于通过氟化氢中的电化学氟化从相应的烷基磺酰卤生产全氟烷基磺酰氟的电极，该电极的特征在于它们由具有柱状结构的镍组成或用柱状结构的镍涂覆。