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    Polymers of aromatic n-3-oxohydrocarbon-substituted acrylamides
    1.
    发明授权
    Polymers of aromatic n-3-oxohydrocarbon-substituted acrylamides 失效
    芳族N-3-氧代烃基取代的丙烯酰胺的聚合物

    公开(公告)号：US3578637A

    公开(公告)日：1971-05-11

    申请号：US3578637D

    申请日：1968-07-19

    Applicant: LUBRIZOL CORP

    Inventor： COLEMAN LESTER E

    IPC: A61K9/00 ,  C07C233/30 ,  C08F20/56 ,  C08F20/58 ,  C08F3/40

    CPC classification number: C10M1/08 ,  C08F20/58 ,  C10M2207/40 ,  C10M2207/402 ,  C10M2207/404 ,  C10M2217/024 ,  C10M2217/028 ,  C10M2217/06 ,  C10M2229/02 ,  C10M2229/05

    Abstract: NOVEL N-3-OXOHYDROCARBON - SUBSTITUTED ACRYLAMIDES CONTAINING AN AROMATIC RADICAL IN EITHER THE 1 OR 3 POSITION ON THE OXOHYDROCARBON SUBSTITUENT ARE PREPARED BY THE REACTION OF ACRYLONITRILE WITH AN AROMATIC KETONE HAVING AT LEAST ONE ALPHA HYDROGEN ATOM, OR WITH A MIX, TURE OF SUCH A KETONE WITH AN AROMATIC OR ALIPHATIC ALDEHYDE OR KETONE HAVING AT LEAST ONE ALPLHA HYDROGEN ATOM, IN THE PRESENCE OF SULFURIC ACID; OR BY THE REACTION OF ACRYLONITRILE WITH A B=HYDROXY OXOHYDROCARBON OR AN A,B-UNSATRUATED OXOHYDROCARBON DERIVED FROM SAID AROMATIC KETONE OR MIXTURE. OIL-SOLUBLE PLOLYMERS FORMED BY THE POLYMERIZATION OF THESE ACRYLAMIDES, AND ALSO BY THE POLYMERIZATION OF ACRYLAMIDES CONTAINING AT LEAST TWO AROMATIC SUBSTITUENTS, ONE IN THE 1 POSITION AND ONE IN THE 3 POSITION OF THE NITROGEN SUBSTITUENT, ARE USEFUL AS VISCOSITY INDEX IMPROVERS FOR LUBRICATING OILS.

    Method for preparing alkoxypropionamides
    3.
    发明授权
    Method for preparing alkoxypropionamides 失效
    制备烷氧基丙酸的方法

    公开(公告)号：US3647875A

    公开(公告)日：1972-03-07

    申请号：US3647875D

    申请日：1970-03-02

    Applicant: LUBRIZOL CORP

    Inventor： COLEMAN LESTER E

    IPC: C07C235/06 ,  C07C103/00

    CPC classification number: C07C235/06 ,  Y10S516/07

    Abstract: N- 3 -OXOHYDROCARBON-SUBSTITUTED 3-ALKOXYPROPIONAMIDES ARE PREPARED BY REACTING AN ALCOHOL WITH AN N-3OXOHYDROCARBON-SUBSTITUTED ACRYLAMIDE IN THE PRESENCE OF A STRONGLY ALKALINE CATALYST, THE MOLE RATIO OF ALCOHOL TO SUBSTITUTED ACRYLAMIDE BEING BETWEEN ABOUT 8:1 AND 12:1. THE PRODUCTS ARE USEFUL AS CHEMICAL INTERMEDIATES FOR THE PREPARATION OF NOVEL AND USEFUL COMPOUNDS; FOR EXAMPLE, N-(1-1-DIMETHYL-3-OXOBUTYL)-3-METHOXYPROPIONAMIDE CAN BE CONVERTED TO N-(1,1-DIMETHYL-3-HYDROXYBUTYL)-ACRYLAMIDE BY HYDROGENATION FOLLOWED BY ALKALINE PYROLYSIS.

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