摘要:
An improved process for the polymerization of cyclic ethers to polyethers using strong Bronsted acid catalysts is disclosed. The catalysts are fluorinated sulfonic acid containing polymers. The resulting polyethers are useful as monomers and in adhesives.
摘要:
Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要:
Selected partially fluorinated olefins containing terminal unfluorinated vinyl groups, and optionally containing other functional groups, may be copolymerized with other olefins such as ethylene and/or propylene using metallocene or Ziegler-Natta type polymerization catalyst systems. The resulting polymers may be used as molding resins, elastomers, for films and in coatings.
摘要:
Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Sine some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene. Also disclosed is a copolymer of an olefin and a fluorinated monomer of the formula H.sub.2 C.dbd.CH(CH.sub.2).sub.a R.sub.f R.sup.42 wherein "a" is an integer of 2 to 20, R.sub.f is a perfluoroalkylene group optionally containing one or more ether linkages, and R.sup.42 is a functional group other than fluorine.
摘要:
Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要:
Fluorine containing terminal olefins may be grafted onto polymers containing hydrogen bound to carbon in the presence of free radicals. The olefins may also contain other functional groups. The resulting novel grafted polymers are useful as molding resins, for coating and as catalysts.
摘要:
Disclosed are ionomers comprising functionalized polyolefins having fluoroalkyl sulfonate pendant groups and ionically conductive compositions formed therefrom by the addition of solvents.
摘要:
Disclosed are ionomers comprising functionalized polyolefins having fluoroalkyl sulfonate pendant groups and ionically conductive compositions formed therefrom by the addition of solvents.
摘要:
The disclosure discloses a method and device for power control in non-adaptive retransmission. The solution thereof includes: when UE does not obtain a TPC adjustment value of a current HARQ process by parsing, determining a current power control mode; if the mode is an accumulation mode, determining whether the calculated sum of TPC adjustment values of each HARQ process is smaller than a given threshold, if yes, obtaining a transmission power by adding an increment adjustment value to a retransmission power, otherwise, calculating the transmission power of UE according to a formula in a protocol; if the mode is an absolute value mode, obtaining a transmission power by adding an increment adjustment value to a retransmission power. The solution can improve the SINR detected by an eNB and improve a retransmission success rate, thereby saving radio resources, facilitating utilization of radio resources and reduction of transmission delay, improving the throughput rate of an LTE system and improving the system performance.
摘要:
Processing a message includes receiving at a message processing system the message that is distributed by a message distributor, the message having a message type, based at least in part on the message type, locating among a plurality of subscriber groups a subscriber group that subscribes to the message type, each of the plurality of subscriber groups having a unique identifier and comprising one or more message subscriber nodes, at least some of the one or more message subscriber nodes in each of the plurality of subscriber groups being connected to the message processing system, and transmitting the message to a message subscriber node that belongs to the subscriber group that is located.