公开(公告)号：US20050159558A1

公开(公告)日：2005-07-21

申请号：US11076298

申请日：2005-03-09

申请人： Ludo Govaerts ,  Dirk Arren ,  Tatsuo Fukushi ,  William Coggio ,  Klaus Hintzer ,  Harald Kaspar

发明人： Ludo Govaerts ,  Dirk Arren ,  Tatsuo Fukushi ,  William Coggio ,  Klaus Hintzer ,  Harald Kaspar

IPC分类号： F16L11/04 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  B32B27/28 ,  B32B27/30 ,  C08K5/00 ,  C08K5/54 ,  C08L27/12 ,  C08F14/18

CPC分类号： B32B27/28 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  C08K5/54 ,  Y10T428/1393 ,  C08L27/12

摘要： The present invention comprises a substrate having a fluoropolymer on at least one of its surfaces wherein one of the substrates or the fluoropolymer comprises a hydride function MH wherein M is Si, Ge, Sn or Pb. The invention further comprises articles comprising the substrate and fluoropolymer; a method of bonding the fluoropolymer to the substrate; a fluoropolymer composition that contains the fluoropolymer, a polyhydroxy cure composition, and an organic composition comprising the hydride function MH; a premix that contains the fluoropolymer and the hydride function MH; and a fluoropolymer composition that comprises (a) a thermoplastic fluoropolymer comprising Cl, Brand/or I atoms and (b) an organic compound that comprises the hydride function MH.

公开(公告)号：US06906145B2

公开(公告)日：2005-06-14

申请号：US10282677

申请日：2002-10-29

申请人： Ludo Govaerts ,  Dirk H. Arren ,  Tatsuo Fukushi ,  William D. Coggio ,  Klaus Hintzer ,  Harald Kaspar

发明人： Ludo Govaerts ,  Dirk H. Arren ,  Tatsuo Fukushi ,  William D. Coggio ,  Klaus Hintzer ,  Harald Kaspar

IPC分类号： F16L11/04 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  B32B27/28 ,  B32B27/30 ,  C08K5/00 ,  C08K5/54 ,  C08L27/12 ,  C08L27/22 ,  C08F8/06 ,  C08F8/12 ,  C08F8/42

CPC分类号： B32B27/28 ,  B32B1/08 ,  B32B7/10 ,  B32B25/08 ,  C08K5/54 ,  Y10T428/1393 ,  C08L27/12

摘要： The present invention comprises a substrate having a fluoropolymer on at least one of its surfaces wherein one of the substrates or the fluoropolymer comprises a hydride function MH wherein M is Si, Ge, Sn or Pb. The invention further comprises articles comprising the substrate and fluoropolymer; a method of bonding the fluoropolymer to the substrate; a fluoropolymer composition that contains the fluoropolymer, a polyhydroxy cure composition, and an organic composition comprising the hydride function MH; a premix that contains the fluoropolymer and the hydride function MH; and a fluoropolymer composition that comprises (a) a thermoplastic fluoropolymer comprising Cl, Brand/or I atoms and (b) an organic compound that comprises the hydride function MH.

摘要翻译： 本发明包括在其至少一个表面上具有含氟聚合物的基材，其中一个基材或含氟聚合物包含氢化物功能MH，其中M是Si，Ge，Sn或Pb。 本发明还包括包含基材和含氟聚合物的制品; 将含氟聚合物粘合到基材上的方法; 含氟聚合物的含氟聚合物组合物，多羟基固化组合物和包含氢化物功能MH的有机组合物; 含氟聚合物和氢化物功能MH的预混物; 和含氟聚合物组合物，其包含（a）包含Cl，Brand /或I原子的热塑性含氟聚合物和（b）包含氢化物功能MH的有机化合物。

公开(公告)号：US06884860B1

公开(公告)日：2005-04-26

申请号：US10627430

申请日：2003-07-25

申请人： Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Gernot Löhr ,  Tatsuo Fukushi ,  Erik Vermeulen

发明人： Harald Kaspar ,  Lisa P. Chen ,  Klaus Hintzer ,  Gernot Löhr ,  Tatsuo Fukushi ,  Erik Vermeulen

IPC分类号： C08F12/20 ,  C08F214/18

CPC分类号： C08F214/18

摘要： A fluoropolymer suitable for the preparation of a fluoroelastomer. The fluoropolymer generally includes repeating units derived from the monomers tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride, chlorotrifluoroethylene and optionally one or more repeating units from fluorinated monomers other than tetrafluoroethylene, hexafluoropropylene, vinylidene fluoride and chlorotrifluoroethylene.

摘要翻译： 适用于制备含氟弹性体的含氟聚合物。 氟聚合物通常包括衍生自单体四氟乙烯，六氟丙烯，偏二氟乙烯，三氟氯乙烯的重复单元和任选的一个或多个来自氟代单体的除四氟乙烯，六氟丙烯，偏二氟乙烯和氯三氟乙烯之外的重复单元。

公开(公告)号：US06864336B2

公开(公告)日：2005-03-08

申请号：US10660437

申请日：2003-09-11

申请人： Harald Kaspar ,  Klaus Hintzer ,  Guy van Gool ,  Franz März ,  Allan T. Worm ,  Tatsuo Fukushi

发明人： Harald Kaspar ,  Klaus Hintzer ,  Guy van Gool ,  Franz März ,  Allan T. Worm ,  Tatsuo Fukushi

IPC分类号： C09K3/10 ,  C08F2/16 ,  C08F2/38 ,  C08F8/00 ,  C08F8/22 ,  C08F14/00 ,  C08F214/22

CPC分类号： C08F8/30 ,  C08F2800/10 ,  C08F2810/20 ,  C08F2810/30 ,  C08F214/22

摘要： The present invention is based on quad-fluoropolymer suitable for the preparation of a fluoroelastomer. The fluoropolymer comprises repeating units derived from 10 to 40 mol % of tetrafluoroethylene, 40 to 65 mol % of vinylidene fluoride, 1 to 30 mol % of a perfluorinated vinyl ether of the formula CF2═CFOCF2CF2CF2OCF3, 1 to 20 mol % of perfluoromethyl vinylether.

摘要翻译： 本发明基于适用于制备含氟弹性体的四氟聚合物。 氟聚合物包含衍生自10〜40摩尔％的四氟乙烯，40〜65摩尔％的偏氟乙烯，1〜30摩尔％的式CF2 = CFOCF2CF2CF2OCF3的全氟化乙烯基醚，1〜20摩尔％的全氟甲基乙烯基醚的重复单元。

公开(公告)号：US07265162B2

公开(公告)日：2007-09-04

申请号：US10712590

申请日：2003-11-13

申请人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Helmut Lochhaas

发明人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Helmut Lochhaas

IPC分类号： C08F2/46

CPC分类号： C08J5/225 ,  B01D67/009 ,  B01D71/32 ,  B01D71/82 ,  C08F114/26 ,  C08J3/28 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of electron beam radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.

摘要翻译： 提供了一种用于制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加电子束 辐射到高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X是F，Cl，Br ，OH或-O - ，其中M +是单价阳离子，第二侧基包括Br，Cl或I. 通常，膜具有90微米或更小，更通常为60或更小，最通常为30微米或更小的厚度。

公开(公告)号：US20050107490A1

公开(公告)日：2005-05-19

申请号：US10712590

申请日：2003-11-13

申请人： Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

发明人： Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

IPC分类号： B01D67/00 ,  B01D71/32 ,  B01D71/36 ,  B01D71/82 ,  C08F114/26 ,  C08F214/26 ,  C08J3/28 ,  C08J5/22 ,  H01M8/10 ,  C08G2/00

CPC分类号： C08J5/225 ,  B01D67/009 ,  B01D71/32 ,  B01D71/82 ,  C08F114/26 ,  C08J3/28 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of electron beam radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.

摘要翻译： 提供了一种用于制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加电子束 辐射到高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X是F，Cl，Br ，OH或-O - ，其中M +是单价阳离子，第二侧基包括Br，Cl或I. 通常，膜具有90微米或更小，更通常为60或更小，最通常为30微米或更小的厚度。

公开(公告)号：US10093761B2

公开(公告)日：2018-10-09

申请号：US13992493

申请日：2011-12-16

申请人： Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Harald Kaspar ,  Larry A. Last ,  Peter J. Scott ,  Zai-Ming Qiu

发明人： Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Harald Kaspar ,  Larry A. Last ,  Peter J. Scott ,  Zai-Ming Qiu

IPC分类号： C08F228/02 ,  C07C17/275 ,  C07C303/22 ,  C07C313/04 ,  C08F214/18

摘要： Described herein is a composition having a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of Formula (I), Formula (II); and combinations thereof, wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R is a linking group; Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group; R1 and R2 are end-groups; p is 0 or 1; m is at least 1; and M is a cation. Also disclosed are methods of making and articles thereof.

公开(公告)号：US20130251930A1

公开(公告)日：2013-09-26

申请号：US13992493

申请日：2011-12-16

申请人： Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Harald Kaspar ,  Larry A. Last ,  Peter J. Scott ,  Zai-Ming Qiu

发明人： Gregg D. Dahlke ,  Denis Duchesne ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Harald Kaspar ,  Larry A. Last ,  Peter J. Scott ,  Zai-Ming Qiu

IPC分类号： C08F228/02

CPC分类号： C08F228/02 ,  C07C17/275 ,  C07C303/22 ,  C07C313/04 ,  C08F214/18 ,  C08F214/182 ,  Y10T428/139 ,  C07C19/07 ,  C07C19/075 ,  C07C309/82 ,  C07C309/80 ,  C07C309/81

摘要： Described herein is a composition having a fluoropolymer derived from the polymerization of a monomer and a sulfinate-containing molecule, wherein the sulfinate-containing molecule is selected from the group consisting of Formula (I), Formula (II); and combinations thereof, wherein X1, X2, and X3 are each independently selected from H, F, Cl, a C1 to C4 alkyl group, and a C1 to C4 fluorinated alkyl group; R is a linking group; Z1 and Z2 are independently selected from F, CF3, and a perfluoroalkyl group; R1 and R2 are end-groups; p is 0 or 1; m is at least 1; and M is a cation. Also disclosed are methods of making and articles thereof.

摘要翻译： 本文描述了具有衍生自单体和含亚磺酸酯的分子的聚合的含氟聚合物的组合物，其中所述含亚磺酸酯的分子选自式（I），式（II）; 和其组合，其中X1，X2和X3各自独立地选自H，F，Cl，C1-C4烷基和C1至C4氟化烷基; R是连接基团; Z 1和Z 2独立地选自F，CF 3和全氟烷基; R1和R2是端基; p为0或1; m至少为1; 而M是阳离子。 还公开了制造方法及其制品。

公开(公告)号：US20060148971A1

公开(公告)日：2006-07-06

申请号：US11305978

申请日：2005-12-19

申请人： Naiyong Jing ,  Tatsuo Fukushi ,  Chuntao Cao ,  Lan Liu ,  Thomas Klun ,  William Coggio ,  Vivian Jones

发明人： Naiyong Jing ,  Tatsuo Fukushi ,  Chuntao Cao ,  Lan Liu ,  Thomas Klun ,  William Coggio ,  Vivian Jones

IPC分类号： C08G75/02

CPC分类号： C08J3/005 ,  C08J7/047 ,  C08J2327/12 ,  C08J2427/00 ,  C08L27/12 ,  C08L27/16 ,  C08L27/18 ,  C08L2205/02 ,  C09D127/12 ,  C09D127/16 ,  C09D127/18 ,  C08L2666/04

摘要： A fluoropolymer coating composition contains a homogeneous mixture of crystalline submicron fluoropolymer particles dispersed in a solvent-borne solution of less crystalline or amorphous fluororesin. The composition may be prepared by blending a latex containing crystalline submicron fluoropolymer particles with a latex containing less crystalline or amorphous fluororesin particles, coagulating and drying the blended latices, and dissolving the dried blend in a solvent for the fluororesin particles. Quasi-homogenous compositions may be prepared by blending dry crystalline submicron fluoropolymer particles with a) dry less crystalline or amorphous fluororesin particles and a solvent for the fluororesin particles, or b) a solvent-borne solution of less crystalline or amorphous fluororesin. Rubbing the disclosed coatings can provide a thin, continuous or nearly continuous fluoropolymer surface layer atop a less crystalline or amorphous fluororesin binder containing crystalline submicron fluoropolymer particles.

公开(公告)号：US20060147723A1

公开(公告)日：2006-07-06

申请号：US11026640

申请日：2004-12-30

申请人： Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy Tatge ,  William Coggio ,  Christopher Walker ,  Thomas Klun ,  William Schultz ,  Zai-Ming Qiu

发明人： Naiyong Jing ,  Chuntao Cao ,  Tatsuo Fukushi ,  Timothy Tatge ,  William Coggio ,  Christopher Walker ,  Thomas Klun ,  William Schultz ,  Zai-Ming Qiu

IPC分类号： B32B27/00 ,  B05D5/06 ,  B05D3/02 ,  C07C61/08

CPC分类号： G02B1/111 ,  Y10T428/24942 ,  Y10T428/3154 ,  Y10T428/31663

摘要： An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer or reactive fluoropolymer, an amino silane ester coupling agent or ester equivalent, a multi-olefinic crosslinker, and optional surface modified inorganic particles or sol gel precursors.

摘要翻译： 用于抗反射膜或耦合到光学显示器的经济，光学透射，防污和防油墨，耐用的低折射率含氟聚合物组合物。 在本发明的一个方面，组合物由含氟聚合物或反应性含氟聚合物，氨基硅烷酯偶联剂或酯当量的反应产物，多烯属交联剂和任选的表面改性的无机颗粒或溶胶凝胶前体形成。