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    Polyurethane-based thickeners for aqueous compositions
    1.
    发明授权
    Polyurethane-based thickeners for aqueous compositions 失效
    用于水性组合物的聚氨酯类增稠剂

    公开(公告)号：US5612408A

    公开(公告)日：1997-03-18

    申请号：US593036

    申请日：1996-01-29

    申请人： Klaus Konig ,  Jurgen Schwindt ,  Jan Mazanek ,  Josef Pedain ,  Manfred Dietrich ,  Gerhard Klein ,  Karl-Roland Jerg

    发明人： Klaus Konig ,  Jurgen Schwindt ,  Jan Mazanek ,  Josef Pedain ,  Manfred Dietrich ,  Gerhard Klein ,  Karl-Roland Jerg

    IPC分类号： C09K3/00 ,  C08G18/28 ,  C08G18/48 ,  C08G65/28 ,  C08L75/00 ,  C08L75/08 ,  C09D7/00 ,  C09D175/00 ,  C09D175/04 ,  C08G18/12 ,  C08G18/42

    CPC分类号： C08G18/4833 ,  C08G18/283 ,  C09D7/002 ,  C08L75/04

    摘要： The present invention relates to a process for the preparation of polyurethanes suitable for use as thickeners for aqueous compositions by reacting at an NCO/OH equivalent ratio of 0.9:1 to 1.2:1a) a polyether component having an OH number of 10 to 30 mg KOH/g and obtained by the alkoxylation of a mixture ofa1) 30 to 80 mole % of a monofunctional alcohol or alkylphenol having 8 to 30 carbon atoms,a2) 2 to 10 mole % of sodium hydroxide or potassium hydroxide,a3) 10 to 60 mole % of water anda4) 0 to 10 mole % of a trihydric to hexahydric alcohol having a molecular weight of 92 to 600, with ethylene oxide or a mixture of ethylene oxide with up to 20 mole %, based on the total moles of alkylene oxides, of propylene oxide, in which the percentages of a1) to a4) add up to 100,withb) a polyisocyanate component containing at least one organic diisocyanate, optionally in admixture with up to 20 mole %, based on the total moles of component b), of higher than difunctional polyisocyanates.The invention also relates to the polyurethanes obtainable by this method and their use, optionally in combination with other thickeners, for the thickening of aqueous systems.

    摘要翻译： 本发明涉及一种制备适合用作水性组合物增稠剂的聚氨酯的方法，其通过以0.9:1至1.2:1的NCO / OH当量比反应a）OH数为10至30的聚醚组分 mg KOH / g，通过a1）30〜80摩尔％的单官能醇或碳原子数为8〜30的烷基酚的混合物的烷氧基化得到，a2）2〜10摩尔％的氢氧化钠或氢氧化钾，a3）10 至60摩尔％的水和a4）0至10摩尔％的分子量为92至600的三元至六元醇与环氧乙烷或环氧乙烷的混合物至多20摩尔％，基于总摩尔数 的环氧丙烷，其中a1）至a4）的百分比加到100，其中b）含有至少一种有机二异氰酸酯的多异氰酸酯组分，任选地与至多20摩尔％的混合物，基于总计 组分b）的摩尔数高于双官能多异氰酸酯。 本发明还涉及通过该方法获得的聚氨酯，以及它们用于任选与其它增稠剂组合的用于增稠水性体系的用途。

    Process for the production of liquid bromine-containing alkoxylation products
    2.
    发明授权
    Process for the production of liquid bromine-containing alkoxylation products 失效
    用于生产液态含溴烷氧基化产物的方法

    公开(公告)号：US4621104A

    公开(公告)日：1986-11-04

    申请号：US785710

    申请日：1985-10-09

    申请人： Manfred Dietrich ,  Manfred Schmidt ,  Rolf Wiedermann ,  Klaus Konig

    发明人： Manfred Dietrich ,  Manfred Schmidt ,  Rolf Wiedermann ,  Klaus Konig

    IPC分类号： C07C41/03 ,  C07C41/22 ,  C07C43/17 ,  C08G18/38 ,  C08G18/67 ,  C08G18/14

    CPC分类号： C07C41/03 ,  C07C41/22 ,  C08G18/381 ,  C08G18/6775 ,  C08G2105/02

    摘要： Liquid bromine-containing alkoxylation products of butyne-(1,4)-diol which are storage stable are produced. More specifically, 1.5 to 2.5 mols alkylene oxide are reacted with each mol of butyne-(1,4)-diol present at elevated temperature in the presence of a catalyst. The catalyst is selected from (1) thioethers having a molecular weight of up to 5000 obtained by adding a mercaptan and/or mercaptoalcohol to an unsaturated hydrocarbon and/or (2) thioethers other than those of (1) having a molecular weight of from 500 to 5000 and/or (3) alkali metal chlorides. This alkoxylation product is then reacted with bromine at -10.degree. to 80.degree. C. The bromide is reoxidized with aqueous hydrogen peroxide solution, stabilized with a relatively non-volatile epoxide and dehydrated. The product thus obtained is particularly useful in the production of flame resistant isocyanate addition products such as polyurethane foams.

    摘要翻译： 产生储存稳定的丁炔（1,4） - 二醇的含溴含氟烷氧基化产物。 更具体地说，在催化剂存在下，将1.5-2.5摩尔环氧烷与升高的温度下存在的每摩尔丁炔 - （1,4） - 二醇反应。 催化剂选自（1）通过向不饱和烃和/或（2）除了（1）分子量为不饱和烃的硫醚和/或（2）的硫醚加入硫醇和/或巯基醇，分子量高达5000的硫醚， 500至5000和/或（3）碱金属氯化物。 然后将该烷氧基化产物与溴在-10℃至80℃反应。溴化物用过氧化氢水溶液再氧化，用相对不挥发的环氧化物稳定并脱水。 由此得到的产品在聚氨酯泡沫等耐火性异氰酸酯加成产物的生产中特别有用。

    Stable polyurethane dispersions and process for production thereof
    3.
    发明授权
    Stable polyurethane dispersions and process for production thereof 失效
    稳定的聚氨酯分散体及其制备方法

    公开(公告)号：US4089835A

    公开(公告)日：1978-05-16

    申请号：US691174

    申请日：1976-05-28

    申请人： Klaus Konig ,  Manfred Dietrich

    发明人： Klaus Konig ,  Manfred Dietrich

    IPC分类号： C08G18/08 ,  C08G18/10 ,  C08G18/28 ,  C08G18/32 ,  C08G18/40 ,  C08G18/65 ,  C08K5/11 ,  C08G18/12

    CPC分类号： C08G18/65 ,  C08G18/0876 ,  C08G18/10 ,  C08G18/2805 ,  C08G18/3225 ,  C08G18/409 ,  Y10S516/928

    摘要： The instant invention is directed to stable dispersions and the process of their manufacture. The stable dispersions of the instant invention comprise polyureas and/or polyhydrazo-dicarbonamides as the disperse phase in an hydroxyl group containing material selected from the group consisting of polyethers, polyesters, polyester amides, polycarbonates, and mixtures thereof, and are produced by reacting (1) organic polyisocyanates with (2) polyamines containing primary and/or secondary amino groups and/or hydrazines and/or hydrazides in (3) the hydroxyl group containing material. Component (3) may also contain relatively low molecular weight polyols and/or inert organic solvents. Components (1), (2) and (3) are continuously introduced into a flow mixer in such a quantity that the average residence time in the mixer is less than ten minutes.

    摘要翻译： 本发明涉及稳定的分散体及其制造方法。 本发明的稳定分散体包含聚脲和/或聚二氢二碳酰胺作为选自聚醚，聚酯，聚酯酰胺，聚碳酸酯及其混合物的含羟基材料中的分散相，并且通过使（ 1）具有（2）含（3）含羟基材料的伯和/或仲氨基和/或肼和/或酰肼的多胺的有机多异氰酸酯。 组分（3）还可以含有相对低分子量的多元醇和/或惰性有机溶剂。 将组分（1），（2）和（3）连续引入流动混合器中，使得在混合器中的平均停留时间小于10分钟。

    Process for the preparation of polymers containing hydroxyl groups and their use for the production of polyurethanes
    4.
    发明授权
    Process for the preparation of polymers containing hydroxyl groups and their use for the production of polyurethanes 失效
    制备含羟基聚合物的方法及其用于生产聚氨酯的方法

    公开(公告)号：US4803246A

    公开(公告)日：1989-02-07

    申请号：US849649

    申请日：1986-04-09

    申请人： Manfred Dietrich ,  Josef Pedain ,  Klaus Konig ,  Peter Hohlein

    发明人： Manfred Dietrich ,  Josef Pedain ,  Klaus Konig ,  Peter Hohlein

    IPC分类号： C08G18/00 ,  C08F8/00 ,  C08F8/14 ,  C08G18/62 ,  C08L75/00

    CPC分类号： C08F8/14 ,  C08G18/6258

    摘要： The present invention is directed to a process for the preparation of polymers containing hydroxyl groups by reacting polymers based on acrylic acid and/or methacrylic acid and containing carboxyl groups with alkylene oxides in the presence of catalysts, characterized in that the catalysts used are(a) addition products containing two thioether groups of (i) mercaptoalkanols corresponding to the formula ##STR1## and (ii) doubly unsaturated terpene hydrocarbons and/or condensation products with a maximum molecular weight of 5000 obtained by the condensation of such addition products on their own or with other polyhydric alcohols having a molecular weight of 62 to about 200, and/or(b) relatively high molecular weight thioethers having a molecular weight of about 500 to 5000 obtainable by the condensation of thiodiglycols corresponding to the formula ##STR2## optionally in admixture with up to 50 hydroxyl equivalents percent, based on the total mixture, of other polyhydroxyl compounds having a molecular weight of 62 to about 200, in which formula, R and R' may be identical or different and denote hydrogen or a methyl group.The present invention is further directed to the use of the hydroxyl containing alkoxylation products obtained by this process as reactants for organic polyisocyanates (optionally blocked with blocking agents for isocyanate groups) in the production of polyurethane plastics, in particular high quality polyurethane coatings.

    摘要翻译： 本发明涉及一种通过在催化剂存在下，通过使基于丙烯酸和/或甲基丙烯酸的聚合物与烯化氧反应的聚合物制备含羟基的聚合物的方法，其特征在于所用的催化剂是（a ）含有两个硫醚基团的加成产物（i）对应于式“IMAGE”的巯基链烷醇和（ii）通过自身缩合产生的双不饱和萜烯烃和/或最大分子量为5000的缩合产物 或分子量为62至约200的其它多元醇，和/或（b）分子量为约500至5000的相对较高分子量的硫醚，其可通过任选地在式 与其他多羟基化合物的混合物混合至多50个羟基当量百分比 分子量为62至约200，其中R和R'可以相同或不同，表示氢或甲基。 本发明还涉及通过该方法获得的含羟基烷氧基化产物作为有机多异氰酸酯的反应物（任选地用异氰酸酯基团的封闭剂封端）用于生产聚氨酯塑料，特别是高质量聚氨酯涂料中的用途。

    Stable dispersions of polyureas and/or polyhydrazodi-carbonamides in relatively high molecular weight, hydroxyl group-containing compounds process for the production thereof and use thereof for the production of polyurethanes
    5.
    发明授权
    Stable dispersions of polyureas and/or polyhydrazodi-carbonamides in relatively high molecular weight, hydroxyl group-containing compounds process for the production thereof and use thereof for the production of polyurethanes 失效
    聚脲和/或聚肼二酰胺在相对高分子量的含羟基化合物的生产中的稳定分散体及其用于生产聚氨酯的用途

    公开(公告)号：US4761434A

    公开(公告)日：1988-08-02

    申请号：US811186

    申请日：1985-12-20

    申请人： Manfred Dietrich ,  Klaus Konig

    发明人： Manfred Dietrich ,  Klaus Konig

    IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/40 ,  C08G18/65 ,  C08L75/08 ,  C08G18/14

    CPC分类号： C08G18/409 ,  C08G18/0876 ,  C08L75/08

    摘要： The present invention is directed to a stable dispersion of a polyurea and/or a polyhydrazodicarbonamide having a solids content of from 5 to 40%, by weight, in a relatively high molecular weight, hydroxyl group-containing polyether, obtained by continuously reacting:(a) an organic di- and/or polyisocyanate withan amine-functional material selected from the group consisting of (i) primary and/or secondary amino group-containing di- and/or polyamines, (ii) hydrazines, (iii) hydrazides and (iv) mixtures thereof in(c) said polyetherat an equivalent ratio of components (a) to (b) of from 1.051:1 to 1.50:1 in a throughflow mixer in such a quantity that the average residence time of the reaction components in the mixer is less than 10 minutes and collecting the reaction product issuing from the throughflow mixer in a receiver optionally with heating to from 50.degree. to 150.degree. C. and optionally with subsequent stirring. The invention also relates to the production and use of such dispersions.

    摘要翻译： 本发明涉及在相对高分子量的含羟基的聚醚中固体含量为5至40重量％的聚脲和/或聚二酰氨基脲的稳定分散体，其通过连续反应获得：（ a）有机二 - 和/或多异氰酸酯，其中胺官能材料选自（i）含伯和/或仲氨基的二 - 和/或多胺，（ii）肼，（iii）酰肼 和（iv）在（c）所述聚醚中的混合物，其中组分（a）至（b）的当量比为1.051:1至1.50:1，在通流混合器中的量使反应的平均停留时间 混合器中的组分少于10分钟，并将来自通流混合器的反应产物在接收器中收集，任选地加热至50至150℃，任选随后搅拌。 本发明还涉及这种分散体的生产和使用。

    Process for the production of oligoesters containing hydroxy groups and their use
    6.
    发明授权
    Process for the production of oligoesters containing hydroxy groups and their use 失效
    生产含有羟基的低聚酯及其用途的方法

    公开(公告)号：US4757097A

    公开(公告)日：1988-07-12

    申请号：US65486

    申请日：1987-06-23

    申请人： Manfred Dietrich ,  Manfred Kapps ,  Klaus Konig ,  Roland Nast

    发明人： Manfred Dietrich ,  Manfred Kapps ,  Klaus Konig ,  Roland Nast

    IPC分类号： C08G18/42 ,  C07C67/08 ,  C07C69/42 ,  C07C69/657 ,  C08G18/50 ,  C08G63/66 ,  C08G65/32 ,  C08G69/40 ,  C08G18/14

    CPC分类号： C07C69/42 ,  C07C67/08 ,  C07C69/657

    摘要： Oligoesters having hydroxyl groups and an OH number of from 200 to 600 mg KOH/g are made by reacting a cyclic dicarboxylic acid anhydride in which no halogen is present with a polyfunctional alcohol or dialkanolamine in a molar ratio of from 1:0.5 to 1:1.5 at a temperature of from 50.degree. to 150.degree. C. to form the corresponding dicarboxylic acid semiester and/or semiamide. This semiester and/or semiamide is then alkoxylated with ethylene oxide and/or propylene oxide in the presence of a catalyst at 80.degree. to 150.degree. C. The equivalent ratio of acid groups to alkylene oxide groups is from 1:0.8 to 1:1.7. The catalysts are reaction products of alkoxides with at least 3 C-atoms with ammonia, piperidine, piperazine and/or C.sub.2 -C.sub.6 aliphatic, polyamines, preferably diamines in which all of the NH-functional groups have been alkoxylated. The resultant oligoester may then be reacted with a polyisocyanate optionally in the presence of known additives, such as blowing agents and catalysts.

    摘要翻译： 通过使不存在卤素的环状二羧酸酐与多官能醇或二烷醇胺以摩尔比为1：0.5〜1：1的比例使羟基和OH值为200〜600mg KOH / g的低聚酯制成。 1.5，温度为50-150℃，形成相应的二羧酸半酯和/或半酰胺。 然后将该半酯和/或半酰胺在80-150℃的催化剂存在下，用环氧乙烷和/或环氧丙烷进行烷氧基化。酸基与环氧烷基的当量比为1:0.8至1:1.7 。 催化剂是具有至少3个C原子的烷氧基与氨，哌啶，哌嗪和/或C 2 -C 6脂族多胺，优选其中所有NH官能团已被烷氧基化的二胺的反应产物。 然后可将所得的低聚酯与多异氰酸酯反应，任选地在已知的添加剂如发泡剂和催化剂的存在下进行。