公开(公告)号：US09156022B2

公开(公告)日：2015-10-13

申请号：US13816054

申请日：2011-07-19

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/00 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C10G2/00

CPC分类号： B01J23/005 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0045 ,  B01J37/0201 ,  C10G2/33 ,  C10G2/334

摘要： The invention relates to a novel method of preparing attrition resistance spinel supports for Fischer Tropsch catalysts. The process comprises: (a) combining aluminum oxide, metal compound capable of forming spinel phase, and soluble compound of a trivalent aluminum; (b) mixing the combination resulting in (a) in a manner sufficient to form a slurry comprising the aforementioned combination; and (c) processing the mixture of (b) under conditions sufficient to form metal aluminate spinel composition. Metal aluminate spinel, for example, is formed in the last step by calcining the mixture from (b) at a temperature in the range of 700 to 1300° C., but the process is also capable, of producing attrition resistant supports (e.g., having a DI of 5 or less) at a relatively lower temperature in the range of 700 to 1050° C. The invention also produces the attrition resistance with lower metal loadings than that reported for prior attrition resistant spinel supports.

摘要翻译： 本发明涉及一种制备费托催化剂的耐磨性尖晶石载体的新方法。 该方法包括：（a）将氧化铝，能够形成尖晶石相的金属化合物和三价铝的可溶性化合物结合起来; （b）混合所得到的（a）以足以形成包含上述组合的浆料的方式的组合; 和（c）在足以形成金属铝酸盐尖晶石组合物的条件下处理（b）的混合物。 例如，金属铝酸盐尖晶石通过在700至1300℃的温度下煅烧来自（b）的混合物在最后步骤中形成，但是该方法还能够生产耐磨载体（例如， 在相对较低的温度下在700至1050℃的范围内具有5或更小的DI。本发明还产生具有比对于现有的耐磨尖晶石载体报告的金属负载更低的耐磨性。

公开(公告)号：US20130199966A1

公开(公告)日：2013-08-08

申请号：US13814905

申请日：2011-07-29

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/889 ,  C07C1/04

CPC分类号： B01J23/8896 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/088 ,  B01J37/18 ,  C07C1/0445 ,  C10G2/33 ,  C10G2/332 ,  C10G2/342 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/703

摘要： A method of producing an aluminium oxide supported catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: spray-drying a slurry of γ-alumina and a source of a spinel forming metal to form a solid precursor material; calcining the precursor material to form a modified support material including a metal aluminate spinel; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, and activating the catalyst.

摘要翻译： 一种制备用于费 - 托合成反应的氧化铝载体催化剂的方法，其包括：喷雾干燥γ-氧化铝和尖晶石形成金属源的浆料以形成固体前体材料; 煅烧前体材料以形成包含金属铝酸盐尖晶石的改性载体材料; 用钴源浸渍改性氧化铝载体材料; 煅烧浸渍的载体材料，并活化催化剂。

公开(公告)号：US09242229B2

公开(公告)日：2016-01-26

申请号：US13814905

申请日：2011-07-29

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/75 ,  B01J23/889 ,  B01J23/00 ,  B01J23/89 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00 ,  C10G45/58 ,  C10G47/00 ,  C07C1/04 ,  B01J23/755 ,  B01J23/76 ,  B01J23/80

CPC分类号： B01J23/8896 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/1014 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/088 ,  B01J37/18 ,  C07C1/0445 ,  C10G2/33 ,  C10G2/332 ,  C10G2/342 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2300/703

摘要： A method of producing an aluminum oxide supported catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: spray-drying a slurry of γ-alumina and a source of a spinel forming metal to form a solid precursor material; calcining the precursor material to form a modified support material including a metal aluminate spinel; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, and activating the catalyst.

摘要翻译： 一种制备用于费 - 托合成反应的氧化铝载体催化剂的方法，其包括：喷雾干燥γ-氧化铝的浆料和尖晶石形成金属源以形成固体前体材料; 煅烧前体材料以形成包含金属铝酸盐尖晶石的改性载体材料; 用钴源浸渍改性氧化铝载体材料; 煅烧浸渍的载体材料，并活化催化剂。

公开(公告)号：US20130143736A1

公开(公告)日：2013-06-06

申请号：US13816054

申请日：2011-07-19

申请人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

发明人： Manoj M. Koranne ,  Erling Rytter ,  Sigrid Eri ,  Oyvind Borg

IPC分类号： B01J23/00 ,  B01J23/755 ,  B01J23/06

CPC分类号： B01J23/005 ,  B01J21/04 ,  B01J23/06 ,  B01J23/755 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/0045 ,  B01J37/0201 ,  C10G2/33 ,  C10G2/334

摘要： The invention relates to a novel method of preparing attrition resistance spinel supports for Fischer Tropsch catalysts. The process comprises: (a) combining aluminum oxide, metal compound capable of forming spinel phase, and soluble compound of a trivalent aluminum; (b) mixing the combination resulting in (a) in a manner sufficient to form a slurry comprising the aforementioned combination; and (c) processing the mixture of (b) under conditions sufficient to form metal aluminate spinel composition. Metal aluminate spinel, for example, is formed in the last step by calcining the mixture from (b) at a temperature in the range of 700 to 1300° C., but the process is also capable, of producing attrition resistant supports (e.g., having a DI of 5 or less) at a relatively lower temperature in the range of 700 to 1050° C. The invention also produces the attrition resistance with lower metal loadings than that reported for prior attrition resistant spinel supports.

摘要翻译： 本发明涉及一种制备费托催化剂的耐磨性尖晶石载体的新方法。 该方法包括：（a）将氧化铝，能够形成尖晶石相的金属化合物和三价铝的可溶性化合物结合起来; （b）混合所得到的（a）以足以形成包含上述组合的浆料的方式的组合; 和（c）在足以形成金属铝酸盐尖晶石组合物的条件下处理（b）的混合物。 例如，金属铝酸盐尖晶石通过在700至1300℃的温度下煅烧来自（b）的混合物在最后步骤中形成，但是该方法还能够生产耐磨载体（例如， 在相对较低的温度下在700至1050℃的范围内具有5或更小的DI。本发明还产生具有比对于现有的耐磨尖晶石载体报告的金属负载更低的耐磨性。

公开(公告)号：US20130210939A1

公开(公告)日：2013-08-15

申请号：US13817501

申请日：2011-08-17

申请人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

发明人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

IPC分类号： C10G3/00

CPC分类号： C10G3/62 ,  B01J23/005 ,  B01J23/75 ,  B01J23/94 ,  B01J33/00 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J38/10 ,  B01J38/12 ,  C07C1/045 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/75 ,  C07C2523/889 ,  C07C2523/89 ,  C10G2/332 ,  Y02P20/584 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S502/518

摘要： A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidising gas to oxidise carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

摘要翻译： 一种从费 - 托合成反应器再生失活催化剂的方法，催化剂是负载型钴催化剂。 该方法包括以下步骤：其中一部分失活催化剂与液体烃一起从反应器中排出的抽出步骤; 浓缩步骤，其中液体烃中催化剂的浓度增加; 煅烧步骤，其中失活的催化剂组合物经受氧化气体以将失活的催化剂中所含的含碳材料氧化成含碳材料的组分的气态氧化物; 和再活化步骤，其中使失活催化剂组合物再活化以产生再生催化剂。

公开(公告)号：US08921252B2

公开(公告)日：2014-12-30

申请号：US13817501

申请日：2011-08-17

申请人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

发明人： Erling Rytter ,  Sigrid Eri ,  Torild Hulsund Skagseth ,  Oyvind Borg

IPC分类号： B01J38/12 ,  C10G3/00 ,  B01J23/94 ,  B01J33/00 ,  B01J35/02 ,  B01J35/10 ,  B01J38/10 ,  C07C1/04 ,  C10G2/00 ,  B01J23/00 ,  B01J23/75

CPC分类号： C10G3/62 ,  B01J23/005 ,  B01J23/75 ,  B01J23/94 ,  B01J33/00 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J38/10 ,  B01J38/12 ,  C07C1/045 ,  C07C2521/04 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/75 ,  C07C2523/889 ,  C07C2523/89 ,  C10G2/332 ,  Y02P20/584 ,  Y02P30/20 ,  Y10S502/514 ,  Y10S502/518

摘要： A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidizing gas to oxidize carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

摘要翻译： 一种从费 - 托合成反应器再生失活催化剂的方法，催化剂是负载型钴催化剂。 该方法包括以下步骤：其中一部分失活催化剂与液体烃一起从反应器中排出的抽出步骤; 浓缩步骤，其中液体烃中催化剂的浓度增加; 煅烧步骤，其中使失活的催化剂组合物经受氧化气体以将包含在失活催化剂中的含碳材料氧化成含碳材料的组分的气态氧化物; 和再活化步骤，其中使失活催化剂组合物再活化以产生再生催化剂。

公开(公告)号：US20100184872A1

公开(公告)日：2010-07-22

申请号：US12525070

申请日：2008-01-29

申请人： Sigrid Eri ,  Erling Rytter ,  Oyvind Borg ,  Alejandro Antonini ,  Kate Elizabeth McCulloch

发明人： Sigrid Eri ,  Erling Rytter ,  Oyvind Borg ,  Alejandro Antonini ,  Kate Elizabeth McCulloch

IPC分类号： B01J23/889 ,  B01J19/00 ,  B01J8/00 ,  C07C27/00

CPC分类号： B01J37/08 ,  B01J21/04 ,  B01J23/005 ,  B01J23/75 ,  B01J23/8896 ,  C10G2/332 ,  C10G2/342

摘要： A method of producing a catalyst for use in a Fischer-Tropsch synthesis reaction. The method comprises the steps of: impregnating a catalyst support material with an active cobalt catalyst component to form a catalyst precursor; and calcining the catalyst precursor in an atmosphere of a dry calcining gas.

摘要翻译： 一种制备用于费 - 托合成反应的催化剂的方法。 该方法包括以下步骤：用催化剂载体材料浸渍活性钴催化剂组分以形成催化剂前体; 并在干煅烧气体的气氛中煅烧催化剂前体。

公开(公告)号：US20130184360A1

公开(公告)日：2013-07-18

申请号：US13811588

申请日：2011-07-15

申请人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstad

发明人： Sigrid Eri ,  Erling Rytter ,  Rune Myrstad

IPC分类号： C10G2/00

CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/005 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/8896 ,  B01J23/8913 ,  B01J33/00 ,  B01J35/1019 ,  B01J35/1033 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/14 ,  B01J37/18 ,  C10G2/342 ,  C10G2300/703 ,  C10G2300/705

摘要： A method of preparing a Fischer-Tropsch catalyst for handling, storage, transport and deployment, including the steps of impregnating a porous support material with a source of cobalt, calcining the impregnated support material activating the catalyst, and passivating the activated catalyst.

摘要翻译： 一种制备用于处理，储存，运输和展开的费 - 托催化剂的方法，包括用钴源浸渍多孔载体材料，煅烧浸渍的活化催化剂的载体材料和钝化活化的催化剂的步骤。

公开(公告)号：US20130012606A1

公开(公告)日：2013-01-10

申请号：US13510867

申请日：2010-11-16

申请人： Erling Rytter ,  Øyvind Borg ,  Sigrid Eri ,  Thomas Sperle

发明人： Erling Rytter ,  Øyvind Borg ,  Sigrid Eri ,  Thomas Sperle

IPC分类号： B01J23/78 ,  B01J23/80 ,  B01J23/889 ,  B01J23/89 ,  C07C1/04 ,  B01J23/83

CPC分类号： B01J21/04 ,  B01J23/005 ,  B01J23/75 ,  B01J23/83 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/8946 ,  B01J35/0053 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/08 ,  B01J37/18 ,  C07C1/0435 ,  C07C1/0445 ,  C07C2523/78 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/1022 ,  C10G2300/703

摘要： A process for the preparation of an F-T catalyst in which the presence of alkaline earth metals is minimized in the support itself and in the processing conditions, in order to provide a catalyst with an alkaline earth metal content of less than 2000 ppm.

摘要翻译： 一种制备F-T催化剂的方法，其中碱土金属的存在在载体本身和处理条件下最小化，以提供碱土金属含量小于2000ppm的催化剂。

公开(公告)号：US10040054B2

公开(公告)日：2018-08-07

申请号：US13510867

申请日：2010-11-16

申请人： Erling Rytter ,  Øyvind Borg ,  Sigrid Eri ,  Thomas Sperle

发明人： Erling Rytter ,  Øyvind Borg ,  Sigrid Eri ,  Thomas Sperle

IPC分类号： B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/889 ,  B01J23/89 ,  C07C1/04 ,  B01J21/04 ,  B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00

摘要： A process for the preparation of an F-T catalyst in which the presence of alkaline earth metals is minimized in the support itself and in the processing conditions, in order to provide a catalyst with an alkaline earth metal content of less than 2000 ppm.