公开(公告)号：US08912110B2

公开(公告)日：2014-12-16

申请号：US13547351

申请日：2012-07-12

Applicant: Manuela Serban ,  Mark P. Lapinski

Inventor： Manuela Serban ,  Mark P. Lapinski

IPC: B01J31/00 ,  B01J37/00 ,  B01J27/138 ,  B01J27/132 ,  B01J27/13 ,  B01J27/125 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/58 ,  B01J23/56 ,  B01J23/42 ,  B01J23/44 ,  B01J23/70 ,  B01J23/72 ,  B01J23/90 ,  B01J23/96 ,  C10G35/04 ,  C10G35/06 ,  C08F4/02 ,  C08F4/60

CPC classification number: B01J37/18 ,  B01J23/63 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/0201 ,  C10G35/06 ,  C10G69/10 ,  C10G2300/1044 ,  C10G2400/02 ,  C10G2400/04

Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.

Abstract translation: 一个实施方案是用于石脑油催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，碱金属或碱土金属，镧系金属和载体。 通常，催化剂的平均体积密度为约0.300至约1.00克/立方厘米。 催化剂的铂含量小于约0.375重量％，锡含量为约0.1至约2重量％，钾含量为约100至约600wppm，铈含量为约0.1至约1重量％。 镧系元素金属可以在催化剂的100微米表面层中以镧系元素金属的浓度分布，其量小于催化剂中心核心处的镧系金属浓度的两倍。

公开(公告)号：US08882994B2

公开(公告)日：2014-11-11

申请号：US13327164

申请日：2011-12-15

Applicant: Mark D. Moser ,  David A. Wegerer ,  Kurt M. VandenBussche ,  Manuela Serban ,  Mark P. Lapinski ,  Mary Jo Wier ,  Gregory J. Gajda

Inventor： Mark D. Moser ,  David A. Wegerer ,  Kurt M. VandenBussche ,  Manuela Serban ,  Mark P. Lapinski ,  Mary Jo Wier ,  Gregory J. Gajda

IPC: C10G35/04

CPC classification number: C10G59/02 ,  C10G59/06 ,  C10G2400/30

Abstract: A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The process includes passing a catalyst stream in a counter-current flow relative to the hydrocarbon process stream.

Abstract translation: 提出了一种从碳氢化合物原料流重整提高芳族化合物产率的方法。 该方法包括将石脑油进料流分解成轻质烃物流，以及将较稠油的浓度较高的环烷烃。 将重质流重整以将环烷烃转化为芳族化合物，并且所得产物流用轻质烃流进一步重整以提高芳烃产率。 该方法包括使相对于烃工艺物流的逆流流动催化剂流。

公开(公告)号：US20130256193A1

公开(公告)日：2013-10-03

申请号：US13433617

申请日：2012-03-29

Applicant: Mark P. Lapinski ,  Kurt M. VandenBussche ,  Manuela Serban

Inventor： Mark P. Lapinski ,  Kurt M. VandenBussche ,  Manuela Serban

IPC: C10G35/04 ,  C10G35/06 ,  B01J19/00 ,  C10G35/12

CPC classification number: C10G35/24 ,  B01J23/96 ,  B01J38/44 ,  C10G35/04 ,  C10G35/06 ,  C10G35/12

Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进助催化剂金属在催化石脑油重整单元中原位加入至少一种催化剂颗粒的方法。 该方法可以包括将催化剂石脑油重整单元引入包含助催化剂金属的化合物，并且在实施这种添加的条件下将有效量的助催化剂金属从包含促进剂金属的化合物加入催化剂颗粒中，并改善烃的转化率 饲料。

公开(公告)号：US08518240B2

公开(公告)日：2013-08-27

申请号：US12701264

申请日：2010-02-05

Applicant: Manuela Serban ,  Mark P. Lapinski ,  Mark D. Moser

Inventor： Manuela Serban ,  Mark P. Lapinski ,  Mark D. Moser

IPC: C10G35/04 ,  C10G25/00 ,  C10G25/12 ,  C10G7/12

CPC classification number: C10G25/00 ,  C10G35/04 ,  C10G2300/1096 ,  C10G2300/201

Abstract: One exemplary embodiment can be a process for removing one or more polynuclear aromatics from at least one reformate stream from a reforming zone. The PNAs may be removed using an adsorption zone. The adsorption zone can include first and second vessels. Generally, the process includes passing the at least a portion of an effluent of the reforming zone through the first vessel containing a first activated carbon. The adsorption zone is operated at a temperature of at least 370° C.

Abstract translation: 一个示例性实施方案可以是从重整区从至少一种重整产物流中除去一种或多种多核芳烃的方法。 可以使用吸附区去除PNA。 吸附区可以包括第一和第二容器。 通常，该方法包括使重整区的流出物的至少一部分通过含有第一活性炭的第一容器。 吸附区在至少370℃的温度下运行

公开(公告)号：US20130158319A1

公开(公告)日：2013-06-20

申请号：US13327164

申请日：2011-12-15

Applicant: Mark D. Moser ,  David A. Wegerer ,  Kurt M. Vanden Bussche ,  Manuela Serban ,  Mark P. Lapinski ,  Mary Jo Wier ,  Gregory J. Gajda

Inventor： Mark D. Moser ,  David A. Wegerer ,  Kurt M. Vanden Bussche ,  Manuela Serban ,  Mark P. Lapinski ,  Mary Jo Wier ,  Gregory J. Gajda

IPC: C07C7/00

CPC classification number: C10G59/02 ,  C10G59/06 ,  C10G2400/30

Abstract: A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The process includes passing a catalyst stream in a counter-current flow relative to the hydrocarbon process stream.

Abstract translation: 提出了一种从碳氢化合物原料流重整提高芳族化合物产率的方法。 该方法包括将石脑油进料流分解成轻质烃物流，以及将较稠油的浓度较高的环烷烃。 将重质流重整以将环烷烃转化为芳族化合物，并且所得产物流用轻质烃流进一步重整以提高芳烃产率。 该方法包括使相对于烃工艺物流的逆流流动催化剂流。

公开(公告)号：US20120277511A1

公开(公告)日：2012-11-01

申请号：US13440381

申请日：2012-04-05

Applicant: Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski

Inventor： Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski

IPC: C07C5/393 ,  C07C7/10

CPC classification number: C10G45/68 ,  C10G35/04 ,  C10G59/02 ,  C10G61/04 ,  C10G2300/4006 ,  C10G2300/4018 ,  C10G2400/30

Abstract: A process for reforming a hydrocarbon stream is presented. The process involves increasing the processing temperatures in the reformers. The reformers are operated under different conditions to utilize advantages in the equilibriums, but require modifications to prevent increasing thermal cracking and to prevent increases in coking. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.

Abstract translation: 提出了一种重整烃流的方法。 该方法涉及提高改性剂中的加工温度。 改造者在不同条件下运行，以利用平衡中的优点，但需要进行修改以防止增加热裂解并防止焦化增加。 该方法利用普通的催化剂和用于回收生成的所需芳族化合物的常见的下游方法。

公开(公告)号：US20100018906A1

公开(公告)日：2010-01-28

申请号：US12177851

申请日：2008-07-22

Applicant: Mark P. Lapinski ,  Richard R. Rosin

Inventor： Mark P. Lapinski ,  Richard R. Rosin

IPC: C10G45/00 ,  B01D53/94 ,  C01B31/18

CPC classification number: B01D53/864 ,  B01D53/02 ,  B01D2251/202 ,  B01D2253/108 ,  B01D2255/1026 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/502 ,  B01J23/96 ,  B01J38/10 ,  C10G35/06

Abstract: One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.

Abstract translation: 一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。 该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

公开(公告)号：US6126814A

公开(公告)日：2000-10-03

申请号：US583725

申请日：1996-02-02

Applicant: Mark P. Lapinski ,  Kenneth L. Riley ,  Thomas R. Halbert ,  William Lasko ,  Jeffrey L. Kaufman

Inventor： Mark P. Lapinski ,  Kenneth L. Riley ,  Thomas R. Halbert ,  William Lasko ,  Jeffrey L. Kaufman

IPC: B01J23/882 ,  B01J35/10 ,  C10G45/06 ,  C10G45/08 ,  C10G45/04

CPC classification number: C10G45/08 ,  B01J23/882 ,  B01J35/006 ,  B01J35/0073 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0009 ,  C10G2400/02

Abstract: A process for hydrodesulfurizing naphtha feedstream wherein the reactor inlet temperature is below the dew point of the feedstock at the reactor inlet so that the naphtha will completely vaporize within the catalyst bed. It is preferred to use a catalyst comprised of about 1 to about 10 wt. % MoO.sub.3, about 0.1 to about 5 wt. % CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 .ANG. to 200 .ANG., a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO.sub.3 surface concentration of about 0.5.times.10.sup.-4 to about 3.0.times.10.sup.-4 g MoO.sub.3 /m.sup.2, and an average particle size of less than about 2.0 mm in diameter.

Abstract translation: 一种加氢脱硫石脑油原料流的方法，其中反应器入口温度低于反应器入口处原料的露点，使得石脑油在催化剂床内完全蒸发。 优选使用包含约1至约10wt。 ％MoO 3，约0.1至约5wt。 ％CoO支持在合适的支撑材料上。 它们的特征还在于具有平均中等孔径从约60至200，Co / Mo原子比为约0.1至约1.0，MoO 3表面浓度为约0.5×10 -4至约3.0×10 -4 g MoO 3 / m2，平均颗粒直径小于约2.0mm。

公开(公告)号：US20130261363A1

公开(公告)日：2013-10-03

申请号：US13547351

申请日：2012-07-12

Applicant: Manuela Serban ,  Mark P. Lapinski

Inventor： Manuela Serban ,  Mark P. Lapinski

IPC: B01J23/63 ,  C07C5/42 ,  B01J21/04 ,  B01J27/135 ,  B01J27/138 ,  B01J27/13

CPC classification number: B01J37/18 ,  B01J23/63 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/0201 ,  C10G35/06 ,  C10G69/10 ,  C10G2300/1044 ,  C10G2400/02 ,  C10G2400/04

Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.

Abstract translation: 一个实施方案是用于石脑油催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，碱金属或碱土金属，镧系金属和载体。 通常，催化剂的平均体积密度为约0.300至约1.00克/立方厘米。 催化剂的铂含量小于约0.375重量％，锡含量为约0.1至约2重量％，钾含量为约100至约600wppm，铈含量为约0.1至约1重量％。 镧系元素金属可以在催化剂的100微米表面层中以镧系元素金属的浓度分布，其量小于催化剂中心核心处的镧系金属浓度的两倍。

公开(公告)号：US07909988B2

公开(公告)日：2011-03-22

申请号：US12104482

申请日：2008-04-17

Applicant: Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Schreier ,  Simon R. Bare

Inventor： Mark P. Lapinski ,  Gregory J. Gajda ,  Jeffry T. Donner ,  Richard R. Rosin ,  Marc R. Schreier ,  Simon R. Bare

IPC: C10G35/04

CPC classification number: C10G35/085 ,  C10G35/095 ,  C10G35/24

Abstract: One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进金属催化剂组分从催化石脑油重整单元中的至少一个供体颗粒转移至至少一个受体颗粒的方法。 该方法可以包括在有效量的金属催化剂组分从至少一个供体颗粒转移到至少一个受体颗粒的条件下进行这种转移以提高烃进料的转化率。