摘要:
A pneumatic radial tire having sidewalls, the rubber composition of said sidewalls comprising, based on 100 parts by weight of rubber, 20 to 90 parts by weight of butadienepiperylene copolymer and 80 to 10 parts by weight of at least one rubbery diene polymer selected from the group consisting of natural rubber, synthetic polyisoprene rubber, polybutadiene rubber, butadiene-styrene copolymer rubber, ethylenepropylene-diene ternary copolymer rubber and acrylonitrile-butadiene copolymer rubber.
摘要:
A styrene-butadiene copolymer having a high styrene content is disclosed, which is obtained by polymerizing styrene and butadiene in a hydrocarbon solvent in the presence of an organolithium compound and, if necessary, a Lewis base and then coupling with a tin halide compound. This copolymer contains in its main chain at least 30 wt % of polymer having a tin-carbon bond and has a bound styrene content of more than 25 wt % but not more than 60 wt % and a content of vinyl bond in butadiene portion of not less than 30% but less than 50%.
摘要:
Rubber compositions for tires having low rolling resistance and excellent running stability consist mainly of a rubber blend consisting of 10-90% by weight of a high vinyl amorphous butadiene-styrene copolymeric rubber obtained by copolymerizing styrene with 1,3-butadiene and containing 3-30% by weight of bonded styrene and not less than 60% by weight of 1,2-bond in butadiene unit, and 90-10% by weight of a dienic rubber having a glass transition temperature of lower than -60.degree. C.
摘要:
A rubber composition for tire having low rolling resistance and high wet skid resistance, breakage strength and wear resistance consists mainly of a rubber component containing at least 20 parts by weight of a high vinyl butadiene-styrene copolymer rubber obtained by copolymerizing randomly styrene with 1,3-butadiene, and containing 3-30% by weight of bonded styrene and 60-95% by weight of 1,2-bond in butadiene unit, and further containing metal-butadienyl bonds in its main chain in a weight fraction of at least 20% by weight.
摘要:
A rubber composition adapted to be used as a tread rubber is disclosed. The rubber composition has remarkably improved resistance against heat generation, breakage resistance, wear resistance, wet skid resistance and low-temperature brittleness, and consists mainly of a rubber blend consisting of 20-95 parts by weight of a styrene-butadiene block copolymer having a specifically limited structure and 80-5 parts by weight of a diene rubber.
摘要:
A branched styrene-butadiene copolymer and a pneumatic tire using the same as a tread base rubber are disclosed. This copolymer is produced by coupling an active styrene-butadiene copolymer anion, which is obtained by polymerizing styrene and butadiene in a hydrocarbon solvent in the presence of ether or a tertiary amine and an initiator of an organolithium compound, with a tin halide compound. In the copolymer, the ratio of branched copolymer connected with tin-butadienyl bond is at least 20% by weight, and the content of bound styrene is not less than 3% by weight but less than 25% by weight, and the content of vinyl bond in butadiene portion is not less than 30% but less than 50%.
摘要:
A rubber composition suitable for use in tire tread is disclosed, which contains at least 20 parts by weight of a block copolymer per 100 parts by weight of total rubber content. This block copolymer comprises (A) a polymer segment obtained by starting from conjugated diolefin and monovinyl aromatic hydrocarbon and having a content of monovinyl aromatic hydrocarbon bond of not more than 10% by weight and (B) a copolymer segment obtained by copolymerization of conjugated diolefin and monovinyl aromatic hydrocarbon and having a content of monovinyl aromatic hydrocarbon bond of 15-50% by weight. Further, the block copolymer satisfies the following conditions:(i) the block copolymer contains at least 10% by weight of each of the segments (A) and (B);(ii) a total content of monovinyl aromatic hydrocarbon bond in the block copolymer is 10-40% by weight;(iii) an average content of vinyl bond in conjugated diolefin portion of the block copolymer is 20-70% by weight; and(iv) the block copolymer includes at least 20% by weight of a polymer having a metal-carbon bond in its molecular chain.
摘要:
A branched styrene-butadiene copolymer and a pneumatic tire using the same as a tread base rubber are disclosed. This copolymer is produced by coupling an active styrene-butadiene copolymer anion, which is obtained by polymerizing styrene and butadiene in a hydrocarbon solvent in the presence of ether or a tertiary amine and an initiator of an organolithium compound, with a tin halide compound. In the copolymer, the ratio of branched copolymer connected with tin-butadienyl bond is at least 20% by weight, and the content of bound styrene is not less than 3% by weight but less than 25% by weight, and the content of vinyl bond in butadiene portion is not less than 30% but less than 50%.
摘要:
Disclosed herein is a rubber composition for use in vibration insulating material, which comprises as rubber components 5-50 parts by weight of a copolymer consisting of 99.5-45% by weight of a conjugated diolefin, 0.5-30% by weight of an ethylenically unsaturated carboxylic acid and 0-40% by weight of another vinly monomer polymerizable therewith, and 50-95 parts by weight of at least one rubber selected from natural rubber and synthetic diene rubbers. This rubber composition is excellent in the breaking properties and vibration insulating properties with a small temperature dependence of hysteresis loss.
摘要:
Disclosure is herein made of a rubber composition containing at least 30% by weight of a butadiene copolymer which is characterized in that: (i) the content of vinyl bonds in a polybutadiene portion is from 40 to 70%; (ii) the content of bound vinyl aromatic compound is from 25 to 50% by weight: (iii) the ratio Mw/Mn between the weight average molecular weight (Mw) and the number average molecular weight (Mn) when calculated as polystyrene according to the gel permeation chromatograph (GPC) method is from 1.8 to 5, and the distribution of the molecular weight is unimodal; (iv) the rate of the copolymer having the weight average molecular weight of not more than 100,000 when calculated as polystyrene is from 10 to 30%; (v) the rate of the copolymer having the weight average molecular weight of not less than 2,000,000 when calculated as polystyrene is from 10 to 30%; and (vi) the Mooney viscosity (ML.sub.1+4 100.degree. C.) is from 20 to 100.