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1.发明授权
公开(公告)号：US5173189A
公开(公告)日：1992-12-22
申请号：US714036
申请日：1991-06-12
申请人： Masaru Hoshi , Tsutomu Nakagawa , Akon Higuchi , Toshio Sugizaki
发明人： Masaru Hoshi , Tsutomu Nakagawa , Akon Higuchi , Toshio Sugizaki
摘要： A membrane for the separation of an organic solvent from a water-organic solvent mixture has a polymeric membrane of a copolymer consisting essentially of an .alpha., .beta.-unsaturated carbonyl compound as a main monomer. The .alpha., .beta.-unsaturated carbonyl compound includes an acrylic acid ester or a methacrylic acid ester. The polymeric membrane has a crosslinked structure. The polymeric membrane is carried on a support member in the form of a flat membrane, a pipe or a hollow fiber. The polymeric member includes particles therein. The polymeric membrane is sandwiched by the support members to form a composite-type separation membrane. The composite-type separation membrane is modulated.
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公开(公告)号：US08252401B2
公开(公告)日：2012-08-28
申请号：US12531777
申请日：2008-03-04
申请人： Shiori Beppu , Toshio Sugizaki
发明人： Shiori Beppu , Toshio Sugizaki
CPC分类号： B32B27/08 , B32B7/12 , B32B27/16 , B32B27/18 , B32B27/22 , B32B27/308 , B32B27/32 , B32B27/36 , B32B27/40 , B32B2270/00 , B32B2274/00 , B32B2307/54 , B32B2307/72 , B32B2307/748 , B32B2457/00 , C09J7/401 , C09J2421/005 , C09J2423/005 , Y10T428/14 , Y10T428/1452 , Y10T428/1476 , Y10T428/24355 , Y10T428/24479
摘要： A release sheet is provided. The release sheet comprises: a base material having one surface and the other surface; and a release agent layer provided on the one surface of the base material. The release agent layer contains substantially no silicone compound and is constituted of a polymer material containing a polyolefine-based thermoplastic elastomer of which density is in the range of 0.80 to 0.90 g/cm3. A Young's modulus of the release agent layer is in the range of 0.1 to 0.3 GPa. An arithmetic mean deviation of a profile Ra of the other surface of the base material is in the range of 100 to 1800 nm. This makes it possible to sufficiently suppress adverse effects on electric components and the like, prevent blocking from occurring when the release film is wound up in a rolled form and stored in this state, and exhibit superior releasability. A pressure-sensitive adhesive article is also provided.
摘要翻译： 提供了一个脱模片。 该剥离片包括：具有一个表面和另一个表面的基材; 以及设置在基材的一个表面上的脱模剂层。 脱模剂层基本上不含有硅氧烷化合物，并且由含有密度在0.80〜0.90g / cm 3范围内的聚烯烃类热塑性弹性体的聚合物材料构成。 剥离剂层的杨氏模量在0.1〜0.3GPa的范围内。 基材的另一面的轮廓Ra的算术平均偏差在100〜1800nm的范围内。 这使得可以充分地抑制对电气部件等的不利影响，防止当剥离膜卷绕成卷状并在该状态下储存时发生阻塞，并且表现出优异的脱模性。 还提供了一种压敏粘合剂制品。
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公开(公告)号：US20100310808A1
公开(公告)日：2010-12-09
申请号：US12744678
申请日：2008-10-30
申请人： Shiori Beppu , Naoki Taya , Toshio Sugizaki
发明人： Shiori Beppu , Naoki Taya , Toshio Sugizaki
CPC分类号： B32B27/18 , B32B7/06 , B32B7/12 , B32B27/08 , B32B27/10 , B32B27/285 , B32B27/32 , B32B2270/00 , B32B2307/21 , B32B2307/50 , B32B2307/538 , B32B2307/72 , B32B2307/748 , B32B2405/00 , C09J7/40 , C09J2423/005 , C09J2453/005 , Y10T428/1452 , Y10T428/31938
摘要： An electrostatic charge on a release sheet is prevented, and thus workability during paying out of a release sheet from a roll is improved.A release sheet 10 comprises a release sheet base 11, an undercoat layer 12 formed on the release sheet base 11, and a release agent layer 13 formed on the undercoat layer 12. The undercoat layer 12 contains a polyolefin-type antistatic agent with specific surface resistance (ASTM D 257) of less than or equal to 109Ω. The surface resistivity (JIS K 6911) of the release sheet 10 is less than or equal to 1014 Ω/square.
摘要翻译： 防止了剥离片上的静电电荷，从而提高了从卷筒出来的脱模片的加工性。 剥离片10包括剥离片基材11，形成在剥离片基材11上的底涂层12和形成在底涂层12上的剥离剂层13.底涂层12含有具有比表面积的聚烯烃类抗静电剂 电阻（ASTM D 257）小于或等于109＆OHgr。 剥离片10的表面电阻率（JIS K 6911）小于或等于1014Ω·平方。
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公开(公告)号：US20100112262A1
公开(公告)日：2010-05-06
申请号：US12531777
申请日：2008-03-04
申请人： Shiori Beppu , Toshio Sugizaki
发明人： Shiori Beppu , Toshio Sugizaki
CPC分类号： B32B27/08 , B32B7/12 , B32B27/16 , B32B27/18 , B32B27/22 , B32B27/308 , B32B27/32 , B32B27/36 , B32B27/40 , B32B2270/00 , B32B2274/00 , B32B2307/54 , B32B2307/72 , B32B2307/748 , B32B2457/00 , C09J7/401 , C09J2421/005 , C09J2423/005 , Y10T428/14 , Y10T428/1452 , Y10T428/1476 , Y10T428/24355 , Y10T428/24479
摘要： A release sheet is provided. The release sheet comprises: a base material having one surface and the other surface; and a release agent layer provided on the one surface of the base material. The release agent layer contains substantially no silicone compound and is constituted of a polymer material containing a polyolefine-based thermoplastic elastomer of which density is in the range of 0.80 to 0.90 g/cm3. A Young's modulus of the release agent layer is in the range of 0.1 to 0.3 GPa. An arithmetic mean deviation of a profile Ra of the other surface of the base material is in the range of 100 to 1800 nm. This makes it possible to sufficiently suppress adverse effects on electric components and the like, prevent blocking from occurring when the release film is wound up in a rolled form and stored in this state, and exhibit superior releasability. A pressure-sensitive adhesive article is also provided.
摘要翻译： 提供了一个脱模片。 该剥离片包括：具有一个表面和另一个表面的基材; 以及设置在基材的一个表面上的脱模剂层。 脱模剂层基本上不含有硅氧烷化合物，并且由含有密度在0.80〜0.90g / cm 3范围内的聚烯烃类热塑性弹性体的聚合物材料构成。 剥离剂层的杨氏模量在0.1〜0.3GPa的范围内。 基材的另一面的轮廓Ra的算术平均偏差在100〜1800nm的范围内。 这使得可以充分地抑制对电气部件等的不利影响，防止当剥离膜卷绕成卷状并在该状态下储存时发生阻塞，并且表现出优异的脱模性。 还提供了一种压敏粘合剂制品。
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公开(公告)号：US20070166523A1
公开(公告)日：2007-07-19
申请号：US11653049
申请日：2007-01-12
申请人： Tomomi Fukaya , Toshio Sugizaki
发明人： Tomomi Fukaya , Toshio Sugizaki
CPC分类号： B29C33/68 , B29K2105/12 , B29K2707/04 , B29K2995/0005 , C09J7/40 , C09J7/401 , C09J2205/31 , C09J2421/005 , C09J2423/005 , C09J2433/005 , C09J2461/005 , C09J2483/005 , H01G4/12 , H01G4/308 , Y10T428/249924 , Y10T428/25 , Y10T428/26 , Y10T428/263 , Y10T428/265 , Y10T428/31663 , Y10T428/31855
摘要： A film having an antistatic releasing agent layer comprising fiber-shaped carbon and disposed on at least one of the faces of a substrate film, a release film having a releasing agent layer disposed on one face of a substrate and an antistatic layer which comprises a cured product of a resin composition of the active energy ray curing type comprising fiber-shaped carbon or a combination of fiber-shaped carbon and an electrically conductive macromolecular compound and is disposed on the other face of the substrate film, and processes for producing the films. The release films have a relatively small thickness of the antistatic layer, exhibit the stable antistatic function, are excellent in smoothness, do not adversely affect hardening of the resin releasing agent, exhibit the excellent releasing function and provide the excellent productivity.
摘要翻译： 一种具有抗静电脱模剂层的薄膜，其包含纤维状碳并设置在基材膜的至少一个表面上，具有设置在基材的一个表面上的脱模剂层的脱模膜和抗静电层，所述抗静电层包含固化 包括纤维状碳或纤维状碳和导电性高分子化合物的组合的活性能量射线固化型树脂组合物的产品，并且设置在基材膜的另一面上，以及用于制备膜的方法。 剥离膜的抗静电层厚度相对较小，抗静电功能稳定，平滑性优异，不会对树脂剥离剂的硬化产生不利影响，显示出优异的剥离功能，提供优异的生产率。
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公开(公告)号：US06773778B2
公开(公告)日：2004-08-10
申请号：US09894371
申请日：2001-06-27
申请人： Yutaka Onozawa , Toshio Sugizaki , Satoshi Sakurai
发明人： Yutaka Onozawa , Toshio Sugizaki , Satoshi Sakurai
IPC分类号： B32B706
CPC分类号： C08J7/047 , B32B17/1033 , B32B27/08 , C08J2483/00 , Y10T428/14 , Y10T428/1457 , Y10T428/1471 , Y10T428/2848 , Y10T428/31507
摘要： A hard coat film is providend, having excellent resistance to impact and weather, and high surface hardness, which is suitable for being stuck on the external surfaces, e.g., those of window panes or plastic boards for windows. In the hard coat film, a silicon-base hard coat layer is provided on one side of a multi-layered base composed of a plurality of the same or different laminated resin films.
摘要翻译： 提供了一种硬涂膜，具有优异的耐冲击性和耐候性，以及高表面硬度，适用于粘贴在诸如窗玻璃或窗用塑料板的外表面上。 在硬涂膜中，在由多个相同或不同的层叠树脂膜构成的多层基材的一面上设置硅基硬涂层。
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公开(公告)号：US08470953B2
公开(公告)日：2013-06-25
申请号：US13195591
申请日：2011-08-01
申请人： Mikihiro Kashio , Toshio Sugizaki , Osamu Moriya
发明人： Mikihiro Kashio , Toshio Sugizaki , Osamu Moriya
CPC分类号： C08G77/04 , C08G77/08 , C08K3/32 , H01L33/56 , H01L2224/48091 , H01L2924/00014
摘要： A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要翻译： 提供了可以制造密封材料的固化物和密封光学元件的具有优异的透明性，抗裂性和耐热性的光学元件用密封材料。 用于光学元件的密封材料包括具有梯形结构的化合物，其在分子中含有下式（A）的重复单元作为主要成分，所述化合物是通过将下式表示的化合物（1） R1Si（OR3）P（X1）3-p和由式R2Si（OR4）q（X2）3-q表示的化合物（2）的摩尔比为1:9至10:0， 的磷酸催化剂，其中R 1表示具有反应性官能团的基团，R 2表示具有1至20个碳原子的烷基，R 3和R 4各自表示具有1至6个碳原子的烷基，X 1和X 2各自表示 卤素原子，p和q分别表示0〜3的整数，l，m，n分别表示0或任意的整数，条件是l和n不同时为0。
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公开(公告)号：US20120088053A1
公开(公告)日：2012-04-12
申请号：US13331161
申请日：2011-12-20
申请人： Sou Miyata , Takuo Nishida , Toshio Sugizaki
发明人： Sou Miyata , Takuo Nishida , Toshio Sugizaki
CPC分类号： C09J109/00 , C09J7/38 , C09J7/385 , C09J7/401 , C09J2203/334 , C09J2409/005 , C09J2433/00 , Y10T428/1452 , Y10T428/265
摘要： Disclosed herein is a release sheet including: a base material; and a release agent layer provided on the base material, wherein the release agent layer is formed by curing a material mainly constituted of a diene-based polymer and contains substantially no silicone compound, and wherein Mooney viscosity (ML1+4 (100° C.)) of the diene-based polymer before curing which is measured according to JIS K6300 at a temperature of 100° C. is in the range of 40 to 70. It is preferred that the material before curing is mainly constituted of one or two or more diene-based polymers having a cis-1,4 bond content of 90 to 99%.
摘要翻译： 本文公开了一种剥离片，包括：基材; 和脱模剂层，其中脱模剂层通过固化主要由二烯类聚合物构成的材料形成，并且基本上不含有硅氧烷化合物，其中门尼粘度（ML1 + 4（100℃） ）根据JIS K6300在100℃下测量的固化前的二烯类聚合物的摩尔比在40〜70的范围内。固化前的材料优选主要由1个或2个或 更多的二烯基聚合物的顺式-1,4键含量为90-99％。
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公开(公告)号：US20110288257A1
公开(公告)日：2011-11-24
申请号：US13195591
申请日：2011-08-01
申请人： Mikihiro KASHIO , Toshio Sugizaki , Osamu Moriya
发明人： Mikihiro KASHIO , Toshio Sugizaki , Osamu Moriya
CPC分类号： C08G77/04 , C08G77/08 , C08K3/32 , H01L33/56 , H01L2224/48091 , H01L2924/00014
摘要： A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided. The sealing material for optical elements comprising a compound with a ladder structure, which contains a repeating unit of the following formula (A) in the molecule as a major component, the compound being obtained by condensing a compound (1) shown by the formula, R1Si(OR3)P(X1)3-p, and a compound (2) shown by the formula, R2Si(OR4)q(X2)3-q, at a molar ratio of 1:9 to 10:0 in the presence of a phosphoric acid catalyst, wherein R1 represents a group having a reactive functional group, R2 represents an alkyl group having 1 to 20 carbon atoms, R3 and R4 individually represents an alkyl group having 1 to 6 carbon atoms, X1 and X2 individually indicate a halogen atom, p and q individually represent an integer from 0 to 3, and l, m, and n individually represent 0 or an arbitrary integer, provided that l and n are not 0 at the same time.
摘要翻译： 提供了可以制造密封材料的固化物和密封光学元件的具有优异的透明性，抗裂性和耐热性的光学元件用密封材料。 用于光学元件的密封材料包括具有梯形结构的化合物，其在分子中含有下式（A）的重复单元作为主要成分，所述化合物是通过将下式表示的化合物（1） R1Si（OR3）P（X1）3-p和由式R2Si（OR4）q（X2）3-q表示的化合物（2）的摩尔比为1:9至10:0， 的磷酸催化剂，其中R 1表示具有反应性官能团的基团，R 2表示具有1至20个碳原子的烷基，R 3和R 4各自表示具有1至6个碳原子的烷基，X 1和X 2各自表示 卤素原子，p和q分别表示0〜3的整数，l，m，n分别表示0或任意的整数，条件是l和n不同时为0。
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公开(公告)号：US07947361B2
公开(公告)日：2011-05-24
申请号：US11653049
申请日：2007-01-12
申请人： Tomomi Fukaya , Toshio Sugizaki
发明人： Tomomi Fukaya , Toshio Sugizaki
CPC分类号： B29C33/68 , B29K2105/12 , B29K2707/04 , B29K2995/0005 , C09J7/40 , C09J7/401 , C09J2205/31 , C09J2421/005 , C09J2423/005 , C09J2433/005 , C09J2461/005 , C09J2483/005 , H01G4/12 , H01G4/308 , Y10T428/249924 , Y10T428/25 , Y10T428/26 , Y10T428/263 , Y10T428/265 , Y10T428/31663 , Y10T428/31855
摘要： A film having an antistatic releasing agent layer comprising fiber-shaped carbon and disposed on at least one of the faces of a substrate film, a release film having a releasing agent layer disposed on one face of a substrate and an antistatic layer which comprises a cured product of a resin composition of the active energy ray curing type comprising fiber-shaped carbon or a combination of fiber-shaped carbon and an electrically conductive macromolecular compound and is disposed on the other face of the substrate film, and processes for producing the films. The release films have a relatively small thickness of the antistatic layer, exhibit the stable antistatic function, are excellent in smoothness, do not adversely affect hardening of the resin releasing agent, exhibit the excellent releasing function and provide the excellent productivity.
摘要翻译： 一种具有抗静电脱模剂层的薄膜，其包含纤维状碳并设置在基材膜的至少一个表面上，具有设置在基材的一个表面上的脱模剂层的脱模膜和抗静电层，所述抗静电层包含固化 包括纤维状碳或纤维状碳和导电性高分子化合物的组合的活性能量射线固化型树脂组合物的产品，并且设置在基材膜的另一面上，以及用于制备膜的方法。 剥离膜的抗静电层厚度相对较小，抗静电功能稳定，平滑性优异，不会对树脂剥离剂的硬化产生不利影响，显示出优异的剥离功能，提供优异的生产率。
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