摘要:
Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR″x(OR′)3−x) (I), structural unit (II) —N(X—SiR″x(OR′)3−x)n(X′—SiR″y(OR′)3−y)m (II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structural units (II).
摘要:
Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR″x(OR′)3-x) (I), structural unit (II) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structural units (II).
摘要:
The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).
摘要:
The present invention relates to a coating composition comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (C) for the crosslinking of silane groups, one or more constituents of the coating composition containing hydrolyzable silane groups, wherein the coating composition contains a water scavenger as further constituent (D).
摘要:
Disclosed are nonaqueous coating material compositions comprising (A) at least one polyhydroxyl-group-containing compound, (B) at least one polyisocyanate-group-containing compound having free or blocked isocyanate groups, and (D) at least one catalyst for the crosslinking of silane groups, where component (B) comprises at least one structural unit —NR—(X—SiR″x(OR′)3-x) (I), and at least one structural unit —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II), wherein in component (B) (i) more than 30 mol % and less than 70 mol % of the originally present isocyanate groups have undergone reaction to form structural units (I) and (II), (ii) more than 25 and less than 36 mol % of the originally present isocyanate groups have undergone reaction to form structural units (II), and (iii) component (B) has at least one polyisocyanate group-containing compound (B2) having free or blocked isocyanate groups and having an acyclic, aliphatic polyisocyanate parent structure.
摘要:
The present invention relates to a coating composition comprising (d) at least one binder (A) having reactive groups, (e) at least one crosslinking agent (B) which is able to react, with crosslinking with the reactive groups of the binder (A), and at least one catalyst (C) for the crosslinking of silane groups, one or more constituents (A) and/or (B) and/or at least one further constituent of the coating composition containing hydrolyzable silane groups, wherein the catalyst (C) is a phosphoric acid compound, more particularly phosphoric acid or phosphonic acid, which is blocked with an amine having a pKb≧3 and a boiling point >100° C.
摘要:
Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
摘要:
Disclosed is a coating composition for coating polycarbonate substrates. The coating composition comprises (A) at least one radiation-curing binder, (B) nanoparticles, and (C) optionally at least one reactive diluent and/or optionally a solvent, and wherein the nanoparticles (B) comprise silicon dioxide nanoparticles, the silicon dioxide nanoparticles have a d50 of between 80 and 300 nm, and the silicon dioxide nanoparticles have a particle size distribution wherein less than 15% by weight of the particles have a size in the range of less than 80 nm, 75% to 95% by weight of the particles have a size in the range from 80 to 300 nm, 0% to 5% by weight of the particles have a size in the range from more than 300 to 1000 nm, and 0% to 5% by weight of the particles have a size in the range from more than 1000 nm to 10 000 nm.
摘要:
Disclosed are nonaqueous coating material compositions comprising (A) at least one polyhydroxyl-group-containing compound, (B) at least one polyisocyanate-group-containing compound having free or blocked isocyanate groups, and (D) at least one catalyst for the crosslinking of silane groups, where component (B) comprises at least one structural unit —NR—(X—SiR″x(OR′)3−x) (I), and at least one structural unit —N(X—SiR″x(OR′)3−x)n(X′—SiR″y(OR′)3−y)m (II), wherein in component (B) (i) more than 30 mol % and less than 70 mol % of the originally present isocyanate groups have undergone reaction to form structural units (I) and (II), (ii) more than 25 and less than 36 mol % of the originally present isocyanate groups have undergone reaction to form structural units (II), and (iii) component (B) has at least one polyisocyanate group-containing compound (B2) having free or blocked isocyanate groups and having an acyclic, aliphatic polyisocyanate parent structure.
摘要:
The present invention relates to a process for the coating of polycarbonate substrates, in particular of transparent polycarbonate substrates, by applying a transparent coating composition encompassing at least one radiation-curing binder resin (A) and/or reactive diluent (C), nanoparticles (B), optionally solvent and at least one light stabilizer (L), to a polycarbonate substrate, wherein the coating composition comprises at least one light stabilizer (L) which comprises, per molecule, an average of at least one ethylenically unsaturated group bonded by way of a urethane group.The present invention also relates to the coating compositions used in said process, and to the coated polycarbonate substrates obtainable via the process, and to their use.