公开(公告)号：US08580886B2

公开(公告)日：2013-11-12

申请号：US13310004

申请日：2011-12-02

Applicant: Michael Backer ,  John Gohndrone ,  Don Kleyer ,  Xiaobing Zhou

Inventor： Michael Backer ,  John Gohndrone ,  Don Kleyer ,  Xiaobing Zhou

IPC: C08K5/5419 ,  C07F7/18

CPC classification number: B01J31/0239 ,  B01J2231/4288 ,  B01J2531/985 ,  C07F7/1804

Abstract: A method for preparing a bis(alkoxysilylorgano)dicarboxylate includes reacting a haloorganoalkoxysilane, a dimetal salt of a dicarboxyl functional compound, and a phase transfer catalyst. A quaternary iminium compound of a polyaza, polycycloalkene is useful as the phase transfer catalyst. The product may be a bis(alkoxysilylalkyl)fumarate, which is useful as a coupling agent in rubber compositions for tire applications.

Abstract translation: 制备双（烷氧基甲硅烷基有机）二羧酸酯的方法包括使卤代有机烷氧基硅烷，二羧基官能化合物的二盐和相转移催化剂反应。 多氮化合物的季铵化合物，聚环烯烃可用作相转移催化剂。 产物可以是富马酸双（烷氧基甲硅烷基）烷基酯，其可用作轮胎用橡胶组合物中的偶联剂。

公开(公告)号：US20120283388A1

公开(公告)日：2012-11-08

申请号：US13520855

申请日：2010-12-22

Applicant: Michael Backer ,  Thomas Chausse ,  Francois De Buyl ,  Damien Deheunynck ,  Satoshi Onodera ,  Valerie Smits

Inventor： Michael Backer ,  Thomas Chausse ,  Francois De Buyl ,  Damien Deheunynck ,  Satoshi Onodera ,  Valerie Smits

IPC: C08F255/02 ,  C08F8/00

CPC classification number: C08L23/06 ,  C08F8/42 ,  C08F290/04 ,  C08F290/042 ,  C08F299/08 ,  C08L23/12 ,  C08L51/06 ,  C08L83/10 ,  C08F10/00 ,  C08L2666/24 ,  C08L2666/06 ,  C08F230/08 ,  C08F236/14

Abstract: The invention provides a process for grafting silicone onto a polyolefin comprising reacting the polyolefin with a silicon compound containing an unsaturated group in the presence of means capable of generating free radical sites in the polyolefin, characterized in that the silicon compound is a branched silicone resin containing at least one group of the formula —X—CH═CH—R″ (I) or —X—C≡C—R″ (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH═CH— or —C≡C-bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH═CH—R″ or with the acetylenic unsaturation of —X—C≡C—R″, X being bonded to the branched silicone resin by a C—Si bond, and R″ represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH═CH— or —C□C-bond. The polyolefin is reinforced by grafting the branched silicone resin onto it.

Abstract translation: 本发明提供一种将聚硅氧烷接枝到聚烯烃上的方法，包括使聚烯烃与含有不饱和基团的硅化合物在能够在聚烯烃中产生自由基位点的方式存在下反应，其特征在于硅化合物是含有 至少一个式-X-CH = CH-R“（I）或-X-C≡C-R”（II）的基团，其中X表示具有相对于 -CH = CH-或-C≡C-键和/或含有芳环或另外的烯属双键或炔属不饱和键，所述芳环或其它烯属双键或炔属不饱和键与-X 1的烯属不饱和键 -CH = CH-R“或-X-C≡C-R”的炔属不饱和度，X通过C-Si键与支链硅氧烷树脂键合，R“表示氢或具有吸电子基团 翼效应或相对于-CH = CH-或-C≡C-键的任何其它活化效应。 通过将支化硅树脂接枝到其上来增强聚烯烃。

公开(公告)号：US20110172367A1

公开(公告)日：2011-07-14

申请号：US13001660

申请日：2009-07-02

Applicant: Michael Backer ,  Francois De Buyl

Inventor： Michael Backer ,  Francois De Buyl

IPC: C08F8/00

CPC classification number: C08F255/00 ,  C08F255/02 ,  C08L51/06 ,  F16L9/12 ,  C08L2666/02 ,  C08L2666/04

Abstract: A process for grafting hydrolysable silane groups to polyethylene includes reacting polyethylene with an unsaturated silane having at least one hydrolysable group bonded to Si, in the presence of a compound capable of generating free radical sites in the polyethylene. The grafted polyethylene prepared by the process can be shaped into a pipe and crosslinked by water flowing through the pipe.

Abstract translation: 将可水解硅烷基团接枝到聚乙烯的方法包括使聚乙烯与在聚乙烯中能够产生自由基位点的化合物存在下使具有至少一个与Si结合的可水解基团的不饱和硅烷反应。 通过该方法制备的接枝聚乙烯可以成形为管，并通过流过管的水交联。

公开(公告)号：US07727579B2

公开(公告)日：2010-06-01

申请号：US11671120

申请日：2007-02-05

Applicant: Michael Backer ,  Brigitte Schlobach ,  Kerstin Knoth ,  Barbara Schupp-Niewa ,  Ruben Huhne ,  Martina Falter

Inventor： Michael Backer ,  Brigitte Schlobach ,  Kerstin Knoth ,  Barbara Schupp-Niewa ,  Ruben Huhne ,  Martina Falter

IPC: B05D5/12 ,  H01L39/24

CPC classification number: C23C18/1216 ,  C23C18/06 ,  C23C18/1225 ,  C23C18/1241 ,  C23C18/1283 ,  H01L39/2461 ,  Y10S505/741

Abstract: The formation of band-shaped HTSL on a metal substrate is disclosed. The HTSL includes at least one buffer layer comprising zirconates and/or rare-earth oxides. The HTSL layer is formed on the buffer layer. The buffer layer has a texturing that in the case of a RHEED measurement results in discrete reflexes and not only in diffraction rings. In particular, the buffer layer may be textured along its interface with the HTSL layer.

Abstract translation: 公开了在金属基底上形成带状HTSL。 HTSL包括至少一个包含锆酸盐和/或稀土氧化物的缓冲层。 HTSL层形成在缓冲层上。 缓冲层具有纹理，在RHEED测量的情况下，导致离散的反射，并且不仅在衍射环中。 特别地，缓冲层可以沿其与HTSL层的界面纹理化。

公开(公告)号：US20130072625A1

公开(公告)日：2013-03-21

申请号：US13310004

申请日：2011-12-02

Applicant: Michael Backer ,  John Gohndrone ,  Don Kleyer ,  Xiaobing Zhou

Inventor： Michael Backer ,  John Gohndrone ,  Don Kleyer ,  Xiaobing Zhou

IPC: C08K5/5419 ,  C07F7/18 ,  C08L47/00

CPC classification number: B01J31/0239 ,  B01J2231/4288 ,  B01J2531/985 ,  C07F7/1804

Abstract: A method for preparing a bis(alkoxysilylorgano)dicarboxylate includes reacting a haloorganoalkoxysilane, a dimetal salt of a dicarboxyl functional compound, and a phase transfer catalyst. A quaternary iminium compound of a polyaza, polycycloalkene is useful as the phase transfer catalyst. The product may be a bis(alkoxysilylalkyl)fumarate, which is useful as a coupling agent in rubber compositions for tire applications.

Abstract translation: 制备双（烷氧基甲硅烷基有机）二羧酸酯的方法包括使卤代有机烷氧基硅烷，二羧基官能化合物的二盐和相转移催化剂反应。 多氮化合物的季铵化合物，聚环烯烃可用作相转移催化剂。 产物可以是富马酸双（烷氧基甲硅烷基）烷基酯，其可用作轮胎用橡胶组合物中的偶联剂。

公开(公告)号：US20130066009A1

公开(公告)日：2013-03-14

申请号：US13698852

申请日：2011-05-16

Applicant: Michael Backer ,  Pierre Chevalier ,  Zhihua Liu ,  Ana Marques ,  Satoshi Onodera ,  Vincent Rerat ,  Motoshi Sasaki

Inventor： Michael Backer ,  Pierre Chevalier ,  Zhihua Liu ,  Ana Marques ,  Satoshi Onodera ,  Vincent Rerat ,  Motoshi Sasaki

IPC: C08G77/18 ,  C08K3/36 ,  C08L83/08 ,  C08G77/395 ,  C08L69/00

CPC classification number: C08G77/395 ,  C08G77/26 ,  C08G77/30 ,  C08G77/388

Abstract: Branched silicone (organopolysiloxane) resins and preparation method and use thereof are provided, which contain at least one group selected from phosphonate and phosphinate groups and at least one organic group containing nitrogen. Such silicone resins can be used in thermoplastic, thermosetting or rubber organic polymer compositions to reduce the flammability of the organic polymer compositions.

Abstract translation: 提供了分支硅氧烷（有机聚硅氧烷）树脂及其制备方法和用途，其含有至少一种选自膦酸酯和次膦酸酯基团和至少一种含氮的有机基团。 这种有机硅树脂可用于热塑性，热固性或橡胶有机聚合物组合物中以降低有机聚合物组合物的可燃性。

公开(公告)号：US20120283362A1

公开(公告)日：2012-11-08

申请号：US13520929

申请日：2010-12-22

Applicant: Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Valerie Smits

Inventor： Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Valerie Smits

IPC: C08L83/07 ,  C08K11/00 ,  C08G77/20

CPC classification number: C08G77/20 ,  C08G77/16 ,  C08L23/04 ,  C08L23/10 ,  C08L83/00

Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH═CH—R″ (I) or —X—C≡C—R″ (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH═CH— or —C≡C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH═CH—R″ or with the acetylenic unsaturation of —X—C≡C—R″ and R″ represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH═CH— or —C≡C— bond.

Abstract translation: 本发明提供包含聚烯烃和聚有机硅氧烷的组合物，其中至少50摩尔％的硅氧烷单元是如本文所定义的D单元，并且含有至少一个不饱和基团，其特征在于不饱和基团是式-X -CH = CH-R“（I）或-X-C≡C-R”（II），其中X表示相对于-CH = CH-或-C≡C具有吸电子效应的二价有机键 C键和/或含有芳环或另外的烯属双键或炔属不饱和键，芳环或其它烯属双键或炔属不饱和键与-X-CH = CH-R“的烯属不饱和键合或与 -X-C≡C-R“和R”的炔属不饱和度表示氢或相对于-CH = CH-或-C≡C-键具有吸电子作用或任何其它活化作用的基团。

公开(公告)号：US20120065319A1

公开(公告)日：2012-03-15

申请号：US13318115

申请日：2010-04-28

Applicant: Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

Inventor： Michael Backer ,  Thomas Chaussee ,  Francois De Buyl ,  Valerie Smits

IPC: C08L43/04 ,  C08F291/02

CPC classification number: C08F253/00 ,  B60C1/00 ,  C08C19/25 ,  C08C19/28 ,  C08F279/02 ,  C08K3/36 ,  C08K5/5425 ,  C08K5/548 ,  C08L51/04 ,  C08F230/08 ,  C08L15/00 ,  C08L7/00 ,  C08L2666/02

Abstract: This invention relates to the modification of elastomers by reaction with unsaturated silanes, to the modified elastomers produced and to articles produced by shaping and curing modified elastomer compositions. It also relates to the use of unsaturated silanes as coupling agents in filled elastomer compositions. In a process according to the present invention, the silane has the formula: R″—CH═CH—C(O)X—Y—SiRaR′(3-a) (I) or R″—C≡C—C(O)X—Y—SiRaR′(3-a) (II) in which R represents a hydrolysable group; R′ represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; Y represents a divalent organic spacer linkage comprising at least one carbon atom separating the linkage —C(O)X— from the Si atom, X is selected from S or O; and R″ represents hydrogen or a group having an electron withdrawing effect with respect to the —CH═CH— or —C≡C— bond. This provides silanes able to react efficiently with a diene elastomer in the presence of a free radical initiator.

Abstract translation: 本发明涉及通过与不饱和硅烷反应对所生产的改性弹性体和通过改性和固化改性弹性体组合物制备的制品来改性弹性体。 它还涉及在填充的弹性体组合物中使用不饱和硅烷作为偶联剂。 在根据本发明的方法中，硅烷具有下式：R“-CH = CH-C（O）X-Y-SiRaR'（3-a）（I）或R”-C≡C-C O）X-Y-SiRaR'（3-a）（II）其中R表示可水解基团; R'表示碳原子数1〜6的烃基。 a的值在1到3的范围内; Y表示包含至少一个碳原子的二价有机间隔键，所述碳原子与Si原子分开连接-C（O）X，X选自S或O; 并且R“表示氢或相对于-CH = CH-或-C≡C-键具有吸电子作用的基团。 这提供能够在自由基引发剂存在下与二烯弹性体有效反应的硅烷。

公开(公告)号：US20070197397A1

公开(公告)日：2007-08-23

申请号：US11678704

申请日：2007-02-26

Applicant: Michael Backer ,  Brigitte Schlobach ,  Kerstin Knoth ,  Barbara Schupp-Niewa ,  Bernhard Holzapfel ,  Martina Falter

Inventor： Michael Backer ,  Brigitte Schlobach ,  Kerstin Knoth ,  Barbara Schupp-Niewa ,  Bernhard Holzapfel ,  Martina Falter

IPC: H01L39/24

CPC classification number: C23C18/1216 ,  C23C18/1225 ,  C23C18/1283 ,  H01L39/2425 ,  H01L39/2461

Abstract: A wet-chemical method for producing strip-shaped high-temperature superconductors with a substrate, optionally with a buffer layer and with a high-temperature superconductive layer is improved by increasing the texturing and the layer thickness of the high-temperature superconductive layer. To this end, precursor solutions are applied in layers to the substrate, of which the first is low in fluorine or does not contain fluorine, and the following have a fluorine concentration that increases with each layer.

Abstract translation: 通过增加高温超导层的纹理和层厚度，可以提高带有衬底，任选地具有缓冲层和高温超导层的带状高温超导体的湿式化学方法。 为此，将前体溶液分层施加到基底上，其首先是低氟或不含氟，并且以下的氟浓度随着各层而增加。

公开(公告)号：US09493615B2

公开(公告)日：2016-11-15

申请号：US13520929

申请日：2010-12-22

Applicant: Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Valerie Smits

Inventor： Michael Backer ,  Francois De Buyl ,  Damien Deheunynck ,  Valerie Smits

IPC: C08L23/04 ,  C08G77/20 ,  C08G77/16 ,  C08L23/10

CPC classification number: C08G77/20 ,  C08G77/16 ,  C08L23/04 ,  C08L23/10 ,  C08L83/00

Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH═CH—R″ (I) or —X—C≡C—R″ (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH═CH— or —C≡C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH═CH—R″ or with the acetylenic unsaturation of —X—C≡C—R″ and R″ represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH═CH— or —C≡C— bond.

Abstract translation: 本发明提供包含聚烯烃和聚有机硅氧烷的组合物，其中至少50摩尔％的硅氧烷单元是如本文所定义的D单元，并且含有至少一个不饱和基团，其特征在于不饱和基团是式-X -CH = CH-R“（I）或-X-C≡C-R”（II），其中X表示相对于-CH = CH-或-C≡C具有吸电子效应的二价有机键 C键和/或含有芳环或另外的烯属双键或炔属不饱和键，芳环或其它烯属双键或炔属不饱和键与-X-CH = CH-R“的烯属不饱和键合或与 -X-C≡C-R“和R”的炔属不饱和度表示氢或相对于-CH = CH-或-C≡C-键具有吸电子作用或任何其它活化作用的基团。