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    Method for the preparation and use of polyether ester amides with units of the starting components randomly distributed in the polymer chain
    6.
    发明授权
    Method for the preparation and use of polyether ester amides with units of the starting components randomly distributed in the polymer chain 失效
    制备和使用聚醚酯酰胺的方法，其中起始组分的单元随机分布在聚合物链中

    公开(公告)号：US4207410A

    公开(公告)日：1980-06-10

    申请号：US888649

    申请日：1978-03-21

    申请人： Klaus Burzin ,  Salih Mumcu ,  Rainer Feldmann ,  Hans Jadamus ,  Roland Feinauer

    发明人： Klaus Burzin ,  Salih Mumcu ,  Rainer Feldmann ,  Hans Jadamus ,  Roland Feinauer

    IPC分类号： C08G69/00 ,  C08G69/44 ,  C08L77/12 ,  C08G63/42

    CPC分类号： C08G69/44

    摘要： Method for preparing and using thermoplastic polyether ester amides with units of the starting components randomly distributed in the polymer chain. A mixture of:I. one or more polyamide forming compounds from the group of the omega-aminocarboxylic acids and/or lactams having at least 10 carbon atoms;II. an alpha, omega-dihydroxy-(polytetrahydrofuran) having an average degree of polymerization of between about 2 and 42 or a molecular weight of between 160 and 3,000; andIII. at least one organic dicarboxylic acid is heated in a weight ratio of I to (II+III) of between 30:7 and 98:2. In (II+III) the hydroxy and carboxy groups are present in equivalent amounts. The heating takes place in the presence of 2-30% by weight of water, based on the polyamide-forming compounds of component I, under the internal pressure attained in a closed container at temperatures of between 230.degree. and 300.degree. C. Water is removed as steam and after removal of the water, the product is further treated at 250.degree.-280.degree. C. with the exclusion of oxygen under normal pressure or under reduced pressure.

    摘要翻译： 制备和使用具有随机分布在聚合物链中的起始组分单元的热塑性聚醚酯酰胺的方法。 一种混合物：I.一种或多种来自具有至少10个碳原子的ω-氨基羧酸和/或内酰胺基团的聚酰胺形成化合物; 二， 平均聚合度为约2至42或分子量为160至3,000的α，ω-二羟基 - （聚四氢呋喃）; 和III。 将至少一种有机二羧酸按I至（II + III）的重量比加热至30:7至98:2之间。 在（II + III）中，羟基和羧基以相等的量存在。 基于形成组分I的聚酰胺形成化合物，在230℃至300℃之间的封闭容器内的压力下，在2-30重量％水的存在下进行加热。水是 作为蒸汽除去并除去水后，在常压或减压下排除氧气，在250℃-280℃下进一步处理该产物。

    Thermoplastic molding compositions having improved _flexibility and cold impact strength based upon polyamides from _omega-aminocarboxylic acids and/or lactams having at least 10 carbon atoms
    7.
    发明授权
    Thermoplastic molding compositions having improved _flexibility and cold impact strength based upon polyamides from _omega-aminocarboxylic acids and/or lactams having at least 10 carbon atoms 失效
    基于具有至少10个碳原子的聚甲基氨基羧酸和/或内酰胺的聚酰胺具有改进的柔性和冷冲击强度的热塑性模塑组合物

    公开(公告)号：US4218549A

    公开(公告)日：1980-08-19

    申请号：US888652

    申请日：1978-03-21

    申请人： Hans Jadamus ,  Salih Mumcu ,  Klaus Burzin ,  Rainer Feldmann ,  Roland Feinauer

    发明人： Hans Jadamus ,  Salih Mumcu ,  Klaus Burzin ,  Rainer Feldmann ,  Roland Feinauer

    IPC分类号： F16L11/04 ,  C08L67/00 ,  C08L77/00 ,  C08L77/12

    CPC分类号： C08L77/00 ,  C08L77/12

    摘要： Thermoplastic molding compositions having improved flexibility and cold impact strength, comprising a mixture of:I. at least one polyamide from omega-aminocarboxylic acids or lactams having at least 10 carbon atoms; andII. at least one polyether ester amide with units of the starting components randomly distributed in the polymer chain produced from:(a) omega-aminocarboxylic acid or lactams having at least 10 carbon atoms,(b) alpha, omega-dihydroxy(polytetrahydrofuran) having a molecular weight of between 160 and 3,000 and(c) a dicarboxylic acid.The mixture contains about 95 to 20 percent by weight of component I and about 5 to 80 percent by weight of component II.

    摘要翻译： 具有改善的柔韧性和抗冷冲击强度的热塑性模制组合物，其包含以下混合物：I.至少一种来自ω-氨基羧酸或具有至少10个碳原子的内酰胺的聚酰胺; 和II。 至少一种聚醚酯酰胺，其起始组分的单元随机分布在聚合物链中，所述聚合物链由以下物质制备：（a）ω-氨基羧酸或具有至少10个碳原子的内酰胺，（b）α，ω-二羟基（聚四氢呋喃） 分子量在160和3,000之间，和（c）二羧酸。 该混合物含有约95至20重量％的组分I和约5至80重量％的组分II。