Method of producing cation-exchange membrane having roughed surface
    1.
    发明授权
    Method of producing cation-exchange membrane having roughed surface 失效
    生产具有粗糙表面的阳离子交换膜的方法

    公开(公告)号:US4537910A

    公开(公告)日:1985-08-27

    申请号:US550338

    申请日:1983-11-09

    IPC分类号: C08J5/22

    CPC分类号: C08J5/2231 C08J2327/18

    摘要: A method of producing a cation-exchange membrane having roughed surface which is characterized in mixing silica powder with water to give a suspended or pasty mixture, supporting the resultant mixture on art paper or filter paper, drying the mixture to form silica powder layer, adhering with heating and pressing the silica powder layer on surface of membrane composed of perfluorocarbon polymer, and removing the silica powder layer formed on the surface of said membrane with caustic alkali aqueous solution.

    摘要翻译: 一种生产具有粗糙表面的阳离子交换膜的方法,其特征在于将二氧化硅粉末与水混合以得到悬浮或糊状混合物,将所得混合物支撑在艺术纸或滤纸上,干燥混合物以形成二氧化硅粉末层,粘附 通过在由全氟化碳聚合物构成的膜的表面上加热压制二氧化硅粉末层,并用苛性碱水溶液除去形成在所述膜表面上的二氧化硅粉末层。

    Halogen-containing polyacrylate derivatives
    3.
    发明授权
    Halogen-containing polyacrylate derivatives 失效
    含卤素的聚丙烯酸酯衍生物

    公开(公告)号:US4752635A

    公开(公告)日:1988-06-21

    申请号:US946055

    申请日:1986-12-24

    CPC分类号: G03F7/039 C08F20/22

    摘要: A halogen-containing polyacrylate derivative having the formula: ##STR1## wherein A is a structural unit derived from a copolymerizable monomer having a double bond; R is ##STR2## wherein each of R.sub.1 and R.sub.2 is a hydrogen atom or a fluorinated methyl group, provided R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, and R.sub.3 is a hydrogen atom or a lower alkyl group; X is a halogen atom or a methyl group; and m is a positive integer, n is 0 or a positive integer, and n/m is from 0 to 2, preferably from 0 to 1.

    摘要翻译: 具有下式的含卤素聚丙烯酸酯衍生物:其中A是衍生自具有双键的可共聚单体的结构单元; R为,其中R1和R2各自为氢原子或氟化甲基,其中R1和R2不同时为氢原子,R3为氢原子或低级烷基; X是卤素原子或甲基; m为正整数,n为0或正整数,n / m为0〜2,优选为0〜1。

    Process for producing cation exchange membrane by impregnating a diene
monomer having carboxylic acid groups into a fluorinated membrane
having cation exchange groups and polymerizing
    5.
    发明授权
    Process for producing cation exchange membrane by impregnating a diene monomer having carboxylic acid groups into a fluorinated membrane having cation exchange groups and polymerizing 失效
    通过将具有羧酸基团的二烯单体浸渍到具有阳离子交换基团并且聚合的氟化膜中来生产阳离子交换膜的方法

    公开(公告)号:US4189540A

    公开(公告)日:1980-02-19

    申请号:US4535

    申请日:1979-01-18

    摘要: A cation exchange membrane is produced by impregnating a diene derivative having carboxylic acid group and/or carboxylic acid convertible group into a cation exchange membrane of a fluorinated polymer having at least one type cation exchange groups having lower acidity than that of sulfonic acid group wherein a ratio of sulfonic acid groups to total cation exchange groups on one surface (A surface layer) is higher than that of the other surface (B surface layer); performing a partial polymerization of the diene derivative and dipping the resulting membrane into an organic solvent which is miscible with water and has a boiling point of higher than 30.degree. C. at 760 mmHg; holding the membrane between a pair of smooth plates; and heating the membrane at 50.degree. to 180.degree. C.; and if the diene derivative having carboxylic acid convertible group is used, converting said groups into carboxylic acid groups.

    摘要翻译: 通过将具有羧酸基和/或羧酸可转换基团的二烯衍生物浸渍到具有比磺酸基的酸性低的至少一种阳离子交换基团的氟化聚合物的阳离子交换膜中来制备阳离子交换膜,其中a 一个表面(A表面层)上的磺酸基与总阳离子交换基团的比例高于另一个表面(B表面层)的比例。 进行二烯衍生物的部分聚合并将所得膜浸入与水混溶并在760mmHg下具有高于30℃的沸点的有机溶剂; 将膜保持在一对光滑的板之间; 并在50℃至180℃加热膜。 并且如果使用具有羧酸可转换基团的二烯衍生物,则将所述基团转化为羧酸基团。

    Electrolysis of sodium chloride
    6.
    发明授权
    Electrolysis of sodium chloride 失效
    电解氯化钠

    公开(公告)号:US4189361A

    公开(公告)日:1980-02-19

    申请号:US962991

    申请日:1978-11-22

    摘要: An electrolysis of sodium chloride is carried out by using a cation exchange membrane obtained by the following treatment.The cation exchange membrane is prepared by treating one surface of a membrane of a perfluorocarbon polymer having sulfonyl halide groups with a diamine or a polyamine at a temperature of 170.degree. C. to a deterioration temperature of the membrane and immersing a diene derivative having a carboxyl group or a group which can be converted to carboxyl group into the membrane to polymerize the diene derivative and treating the membrane with a water miscible organic solvent having a boiling point of higher than 120.degree. C. in 760 mmHg between smooth plates at 80.degree. C. to 180.degree. C.

    摘要翻译: 通过使用通过以下处理获得的阳离子交换膜进行氯化钠的电解。 阳离子交换膜通过将具有磺酰卤基团的全氟化碳聚合物的膜的一个表面与二胺或多胺在170℃的温度下处理至膜的劣化温度并浸渍具有羧基的二烯衍生物 基团或可以转化成羧基的基团,以使二烯衍生物聚合,并在80℃下在平滑板之间的760mmHg的沸点高于120℃的水混溶性有机溶剂处理膜 至180℃

    Pellicle having reflection-preventing function
    8.
    发明授权
    Pellicle having reflection-preventing function 失效
    防护薄膜具有防反射功能

    公开(公告)号:US5229229A

    公开(公告)日:1993-07-20

    申请号:US689340

    申请日:1991-04-23

    IPC分类号: G03F1/62

    摘要: A pellicle having a reflection-preventing function comprised of a transparent polyvinyl acetal film and a reflection-preventing film formed on at least one surface of the polyvinyl acetal film. The reflection-preventing film is made of a copolymer of a perfluoroalkyl acrylate or methacrylate with a hydroxyalkyl acrylate or methacrylate having (i) a hydroxyalkyl group having 2-3 OH groups on the terminal or side chain and 3-5 carbon atoms, (ii) a hydroxyalkyl group having an OH group on the terminal or side chain and 2-4 carbon atoms, or (iii) a fluorine-containing hydroxyalkyl group having an OH group on the terminal or side chain and 4-12 carbon atoms.

    摘要翻译: 一种具有抗反射功能的防护薄膜组件,其由聚乙烯醇缩醛膜的至少一个表面上形成的透明聚乙烯醇缩醛膜和防反射膜构成。 防反射膜由丙烯酸全氟烷基酯或甲基丙烯酸全氟烷基酯与丙烯酸羟烷基酯或(甲基)丙烯酸羟烷基酯的共聚物制成,(i)末端或侧链具有2-3个OH基团的羟基烷基和3-5个碳原子,(ii) )在末端或侧链具有2-4个碳原子上具有OH基团的羟基烷基,或(iii)末端或侧链具有4-12个碳原子上具有OH基团的含氟羟基烷基。

    Process for preparing a highly selective fluorinated anion exchange
membrane
    10.
    发明授权
    Process for preparing a highly selective fluorinated anion exchange membrane 失效
    制备高选择性氟化阴离子交换膜的方法

    公开(公告)号:US4900420A

    公开(公告)日:1990-02-13

    申请号:US177844

    申请日:1988-03-28

    IPC分类号: C08J5/22

    CPC分类号: C08J5/2237 C08J2327/12

    摘要: A process for preparing an anion exchange membrane, which comprises subjecting a carboxylate membrane made of a copolymer having repeating units of the formula: ##STR1## wherein X is F or CF.sub.3, l is an integer of from 0 to 5, m is 0 or 1, n is an integer of from 1 to 5, and p/q is from 4 to 16, and R is an alkyl group, to an acid or base treatment, and then introducing anion exchange groups thereinto.

    摘要翻译: 一种制备阴离子交换膜的方法,包括使由具有下式的重复单元的共聚物制成的羧酸盐膜:其中X为F或CF 3,I为0至5的整数,m为0或 1,n为1〜5的整数,p / q为4〜16,R为烷基,进行酸或碱处理,然后向其中引入阴离子交换基团。