公开(公告)号：US4307319A

公开(公告)日：1981-12-22

申请号：US921948

申请日：1978-07-05

申请人： Motoyasu Terao ,  Tadaaki Hirai ,  Eiichi Maruyama ,  Hideaki Yamamoto ,  Tsutomu Fujita ,  Naohiro Goto ,  Keiichi Shidara

发明人： Motoyasu Terao ,  Tadaaki Hirai ,  Eiichi Maruyama ,  Hideaki Yamamoto ,  Tsutomu Fujita ,  Naohiro Goto ,  Keiichi Shidara

IPC分类号： H01J29/45 ,  H01L31/08

CPC分类号： H01J29/451

摘要： A photoelectric device comprises a signal electrode, a layer of amorphous photoconductor containing 50 atomic percent or more of selenium and an N-type semiconductor layer made of a material selected from the group consisting of oxygen depletion type cerium oxide and oxygen depletion type lead oxide and disposed therebetween, which has a thickness greater than 8 nm and up to and including 500 nm and a Fermi level located within an energy range of 0.2 to 0.8 eV from the bottom of a conduction band.

摘要翻译： 光电装置包括信号电极，含有50原子％以上的硒的非晶质感光体层和由选自氧耗尽型氧化铈和氧耗尽型氧化铅的材料制成的N型半导体层，以及 其间具有大于8nm的厚度并且包括500nm的厚度以及从导带的底部位于0.2至0.8eV的能量范围内的费米能级。

公开(公告)号：US4040985A

公开(公告)日：1977-08-09

申请号：US674086

申请日：1976-04-06

申请人： Keiichi Shidara ,  Naohiro Goto ,  Eiichi Maruyama ,  Tadaaki Hirai ,  Tsutomu Fujita

发明人： Keiichi Shidara ,  Naohiro Goto ,  Eiichi Maruyama ,  Tadaaki Hirai ,  Tsutomu Fujita

IPC分类号： H01J29/45 ,  H01L31/0248 ,  H01L31/00

CPC分类号： H01J29/456 ,  Y10T428/31678

摘要： A photoconductive film comprises a first region containing Se in which Te and an element capable of forming deep levels in Se are added at concentrations lower than 10 atomic % inclusive on average, respectively, a second region disposed on the first region and containing Se in which Te is added with a continuous distribution of concentration having a peak value greater than 15 atomic % inclusive, a third region disposed on the second region and containing Se in which an element capable of forming deep levels in Se is added with a continuous distribution of concentration having a peak value greater than 15 atomic % inclusive, and a fourth region disposed on the third region and containing Se in which Te and an element capable of forming deep levels in Se are added at concentrations lower than 10 atomic % inclusive on average, respectively.

摘要翻译： 光电导膜包括含有Se的第一区域，其中Te和能够形成Se的深度水平的元素分别平均加入低于10原子％的平均值，第二区域设置在第一区域上并包含Se，其中 加入具有峰值大于15原子％的浓度的连续分布的浓度，第三区域设置在第二区域上，并且包含Se，其中能够形成Se中的深层次的元素具有连续的浓度分布 具有大于15原子％的峰值的第一区域，以及设置在第三区域上并且含有Se的Se的第四区域，其中Te和Se中能够形成深度水平的元素分别以低于10原子％ 。

公开(公告)号：US3984722A

公开(公告)日：1976-10-05

申请号：US469760

申请日：1974-05-14

申请人： Eiichi Maruyama ,  Hiroaki Hachino ,  Yasushi Saitoh ,  Tadaaki Hirai ,  Naohiro Goto ,  Yukinao Isozaki ,  Keiichi Shidara ,  Saiichi Koizumi

发明人： Eiichi Maruyama ,  Hiroaki Hachino ,  Yasushi Saitoh ,  Tadaaki Hirai ,  Naohiro Goto ,  Yukinao Isozaki ,  Keiichi Shidara ,  Saiichi Koizumi

IPC分类号： H01J29/45 ,  H01L31/08 ,  H01L31/109 ,  H01J31/38

CPC分类号： H01L31/109 ,  H01J29/456 ,  H01J9/233

摘要： An image pickup tube target wherein a rectifying contact which is formed at a boundary of a first layer of a material selected from the group consisting of tin oxide, indium oxide, titanium oxide, cadmium sulfide, zinc sulfide, cadmium selenide, zinc selenide, n-type germanium, n-type silicon and mixture thereof, and a second layer of a material mainly consisting of selenium and including halogen, is reversely biased and operated at a region where signal current is saturated with respect to applied voltage. The second layer of the material includes 50 atomic percent or more of selenium and 0.1 - 1000 atomic ppm of halogen. More preferably, the second layer comprises 3-20 atomic % of arsenic, 0.1-20 atomic ppm of iodine and balance mainly consisting of selenium.

摘要翻译： 一种图像拾取管目标，其中形成在选自氧化锡，氧化铟，氧化钛，硫化镉，硫化锌，硒化镉，硒化锌，氮化镍的材料的第一层的边界处的整流接触 型锗，n型硅及其混合物，以及主要由硒组成并包括卤素的材料的第二层反向偏置并在信号电流相对于施加电压饱和的区域操作。 材料的第二层包括50原子％或更多的硒和0.1-1000原子ppm的卤素。 更优选地，第二层包含3-20原子％的砷，0.1-20原子ppm的碘，余量主要由硒组成。

公开(公告)号：US5233265A

公开(公告)日：1993-08-03

申请号：US561678

申请日：1990-08-01

申请人： Yukio Takasaki ,  Kazutaka Tsuji ,  Tatsuo Makishima ,  Tadaaki Hirai ,  Sachio Ishioka ,  Tatsuro Kawamura ,  Keiichi Shidara ,  Eikyu Hiruma ,  Kenkichi Tanioka ,  Junichi Yamazaki ,  Kenji Sameshima ,  Hirokazu Matsubara ,  Kazuhisa Taketoshi ,  Mitsuo Kosugi ,  Shiro Suzuki ,  Takashi Yamashita ,  Masaaki Aiba ,  Yoshizumi Ikeda ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Hirofumi Ogawa

发明人： Yukio Takasaki ,  Kazutaka Tsuji ,  Tatsuo Makishima ,  Tadaaki Hirai ,  Sachio Ishioka ,  Tatsuro Kawamura ,  Keiichi Shidara ,  Eikyu Hiruma ,  Kenkichi Tanioka ,  Junichi Yamazaki ,  Kenji Sameshima ,  Hirokazu Matsubara ,  Kazuhisa Taketoshi ,  Mitsuo Kosugi ,  Shiro Suzuki ,  Takashi Yamashita ,  Masaaki Aiba ,  Yoshizumi Ikeda ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Hirofumi Ogawa

IPC分类号： H01J29/45 ,  H01L31/0376 ,  H01L31/09 ,  H01L31/107 ,  H01L31/20

CPC分类号： H01J29/456 ,  H01L31/03765 ,  H01L31/095 ,  H01L31/107 ,  H01L31/204 ,  Y02E10/548 ,  Y02P70/521

摘要： A photoconductive device having a photoconductive layer which includes an amorphous semiconductor layer capable of charge multiplication in at least a part thereof is disclosed. The method of operating such a photoconductive device is also disclosed. By using the avalanche effect of the amorphous semiconductor layer, it is possible to realize a highly sensitive photoconductive device while maintaining low lag property. In one aspect of the present invention, the amorphous semiconductor layer is amorphous Se. In another aspect of the present invention, the amorphous semiconductor layer is composed mainly of tetrahedral elements including at least an element of hydrogen or halogens. When using the amorphous semiconductor layer composed mainly of tetrahedral elements, the charge multiplication effect is produced mainly in the interior of the amorphous semiconductor, and thus it is possible to obtain a thermally stable photoconductive device having a high sensitivity while keeping a good photoresponse.

摘要翻译： 公开了一种具有光电导层的光电导器件，该光电导层包括至少部分能够进行电荷倍增的非​​晶半导体层。 还公开了操作这种光电导器件的方法。 通过使用非晶半导体层的雪崩效应，可以实现高灵敏度的感光器件，同时保持低滞后特性。 在本发明的一个方面，非晶半导体层是非晶态Se。 在本发明的另一方面，非晶半导体层主要由至少包含氢或卤素元素的四面体元素组成。 当使用主要由四面体元素组成的非晶半导体层时，电荷倍增效应主要在非晶半导体的内部产生，因此可以获得具有高灵敏度的热稳定的光电导器件，同时保持良好的光响应。

公开(公告)号：US4866332A

公开(公告)日：1989-09-12

申请号：US16403

申请日：1987-02-19

申请人： Yukio Takasaki ,  Tatsuo Makishima ,  Kazutaka Tsuji ,  Tadaaki Hirai ,  Eisuke Inoue ,  Yasuhiko Nonaka ,  Naohiro Goto ,  Masanao Yamamoto ,  Keiichi Shidara ,  Kenkichi Tanioka ,  Takashi Yamashita ,  Tatsuro Kawamura ,  Eikyuu Hiruma ,  Shirou Suzuki ,  Masaaki Aiba

发明人： Yukio Takasaki ,  Tatsuo Makishima ,  Kazutaka Tsuji ,  Tadaaki Hirai ,  Eisuke Inoue ,  Yasuhiko Nonaka ,  Naohiro Goto ,  Masanao Yamamoto ,  Keiichi Shidara ,  Kenkichi Tanioka ,  Takashi Yamashita ,  Tatsuro Kawamura ,  Eikyuu Hiruma ,  Shirou Suzuki ,  Masaaki Aiba

IPC分类号： H01J29/45

CPC分类号： H01J29/456

摘要： A target of an image pickup tube, having a transparent substrate, a transparent conductive film, a p-type photoconductive film made mainly from amorphous Se, and an n-type conductive film capable of forming a rectifying contact at the interface with the p-type photoconductive film, using the rectifying contact as a reverse bias, characterized in that the p-type photoconductive film containing at least a region having more than 35%, and to 60% by weight of Te in the film thickness direction, and at least a region containing 0.005 to 5% by weight of at least a material capable of forming shallow levels in the amorphous Se in the film thickness direction, has good after-image characteristics even if operated at a high temperature.

摘要翻译： 具有透明基板，透明导电膜，主要由非晶形Se形成的p型光电导膜的图像拾取管的目标和能够在与p型交联的界面处形成整流接触的n型导电膜， 使用整流接触作为反向偏压，其特征在于，所述p型光电导膜至少含有在膜厚度方向上具有大于35％的区域和至少60重量％的Te，至少 至少含有0.005〜5重量％的能够在膜厚度方向上形成非晶态Se的浅层的材料的区域即使在高温下操作也具有良好的后图像特性。

公开(公告)号：US4330733A

公开(公告)日：1982-05-18

申请号：US152291

申请日：1980-05-22

申请人： Keiichi Shidara ,  Naohiro Goto ,  Tatsuro Kawamura ,  Eikyu Hiruma ,  Yohitsumu Ikeda ,  Kenkichi Tanioka ,  Tadaaki Hirai ,  Yukio Takasaki ,  Chushirou Kusano ,  Tsuyoshi Uda ,  Yasuhiko Nonaka

发明人： Keiichi Shidara ,  Naohiro Goto ,  Tatsuro Kawamura ,  Eikyu Hiruma ,  Yohitsumu Ikeda ,  Kenkichi Tanioka ,  Tadaaki Hirai ,  Yukio Takasaki ,  Chushirou Kusano ,  Tsuyoshi Uda ,  Yasuhiko Nonaka

IPC分类号： H01J29/45 ,  H01L31/0264 ,  H01L31/0272 ,  H01L31/08 ,  H01J31/38

CPC分类号： H01L31/02725 ,  H01J29/45

摘要： A photoconductive target having an electrode and a P-type conductive layer mainly made of Se and making rectifying contact at an interface with the electrode, with at least Te being doped in a portion of the P-type conductive layer. At least one metal fluoride forming shallow levels is doped in the region where the signal current is generated for the most part of the P-type conductive layer with an average concentration of not less than 50 ppm and not more than 5% by weight. The metal fluoride is preferably at least one selected from the group consisting of LiF, NaF, MgF.sub.2, CaF.sub.2, BaF.sub.2, AlF.sub.3, CrF.sub.3, MnF.sub.2, CoF.sub.2, PbF.sub.2, CeF.sub.3 and TlF. The high light sticking of the photoconductive target can thus be considerably reduced.

摘要翻译： 一种光电导体，其具有主要由Se制成的电极和P型导电层，并在与电极的界面处进行整流接触，至少在P型导电层的一部分中掺杂有Te。 在大部分P型导电层产生信号电流的区域中掺杂有至少一种金属氟化物，平均浓度不低于50ppm且不超过5重量％。 金属氟化物优选为选自LiF，NaF，MgF 2，CaF 2，BaF 2，AlF 3，CrF 3，MnF 2，CoF 2，PbF 2，CeF 3和TlF中的至少一种。 因此可以显着地降低光导目标的高光粘附。

公开(公告)号：US4952839A

公开(公告)日：1990-08-28

申请号：US420773

申请日：1989-10-12

申请人： Kenkichi Tanioka ,  Mitsuo Kosugi ,  Junichi Yamazaki ,  Keiichi Shidara ,  Kazuhisa Taketoshi ,  Tatsuro Kawamura ,  Eikyuu Hiruma ,  Shiro Suzuki ,  Takashi Yamashita ,  Masaaki Aiba ,  Yochizumi Ikeda ,  Tadaaki Hirai ,  Yukio Takasaki ,  Sachio Ishioka ,  Tatsuo Makishima ,  Kenji Sameshima ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Kazutaka Tsuji ,  Hirofumi Ogawa

发明人： Kenkichi Tanioka ,  Mitsuo Kosugi ,  Junichi Yamazaki ,  Keiichi Shidara ,  Kazuhisa Taketoshi ,  Tatsuro Kawamura ,  Eikyuu Hiruma ,  Shiro Suzuki ,  Takashi Yamashita ,  Masaaki Aiba ,  Yochizumi Ikeda ,  Tadaaki Hirai ,  Yukio Takasaki ,  Sachio Ishioka ,  Tatsuo Makishima ,  Kenji Sameshima ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Kazutaka Tsuji ,  Hirofumi Ogawa

IPC分类号： H01J29/45

CPC分类号： H01J29/456

摘要： A photoconductive device having a photoconductive layer which includes an amorphous semiconductor layer capable of charge multiplication in at least a part thereof is disclosed. The method of operating such a photoconductive device is also disclosed. By using the avalanche effect of the amorphous semiconductor layer, it is possible to realize a highly sensitive photoconductive device while maintaining low lag property.

公开(公告)号：US4888521A

公开(公告)日：1989-12-19

申请号：US69156

申请日：1987-07-02

申请人： Kenkichi Tanioka ,  Keiichi Shidara ,  Tatsuro Kawamura ,  Junichi Yamazaki ,  Eikyuu Hiruma ,  Kazuhisa Taketoshi ,  Shiro Suzuki ,  Takashi Yamashita ,  Mitsuo Kosugi ,  Yochizumi Ikeda ,  Masaaki Aiba ,  Tadaaki Hirai ,  Yukio Takasaki ,  Sachio Ishioka ,  Tatsuo Makishima ,  Kenji Sameshima ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Kazutaka Tsuji ,  Hirofumi Ogawa

发明人： Kenkichi Tanioka ,  Keiichi Shidara ,  Tatsuro Kawamura ,  Junichi Yamazaki ,  Eikyuu Hiruma ,  Kazuhisa Taketoshi ,  Shiro Suzuki ,  Takashi Yamashita ,  Mitsuo Kosugi ,  Yochizumi Ikeda ,  Masaaki Aiba ,  Tadaaki Hirai ,  Yukio Takasaki ,  Sachio Ishioka ,  Tatsuo Makishima ,  Kenji Sameshima ,  Tsuyoshi Uda ,  Naohiro Goto ,  Yasuhiko Nonaka ,  Eisuke Inoue ,  Kazutaka Tsuji ,  Hirofumi Ogawa

IPC分类号： H01J29/45 ,  H01J31/38

CPC分类号： H01J29/456

摘要： A photoconductive device having a photoconductive layer which includes an amorphous semiconductor layer capable of charge multiplication in at least a part thereof is disclosed. The method of operating such a photoconductive device is also disclosed. By using the avalanche effect of the amorphous semiconductor layer, it is possible to realize a highly sensitive photoconductive device while maintaining low lag property.

摘要翻译： 公开了一种具有光电导层的光电导器件，该光电导层包括至少部分能够进行电荷倍增的非​​晶半导体层。 还公开了操作这种光电导器件的方法。 通过使用非晶半导体层的雪崩效应，可以实现高灵敏度的感光器件，同时保持低滞后特性。

公开(公告)号：US4007473A

公开(公告)日：1977-02-08

申请号：US580539

申请日：1975-05-23

申请人： Yasuhiko Nonaka ,  Tadaaki Hirai ,  Naohiro Goto ,  Keiichi Shidara

发明人： Yasuhiko Nonaka ,  Tadaaki Hirai ,  Naohiro Goto ,  Keiichi Shidara

IPC分类号： H01J9/233 ,  H01J29/45 ,  H01L31/08 ,  H01L27/14

CPC分类号： H01J29/456 ,  Y10S148/063 ,  Y10S148/072 ,  Y10S148/12 ,  Y10S148/15

摘要： In a target structure for use in a photoconductive image pickup tube, a P-type photoconductive film is deposited on an N-type transparent conductive film which is deposited on a transparent substrate. The P-type photosensitive film comprises first and second photoconductive substances. The commencement of the deposition of the first photoconductive substance is delayed a predetermined time from that of the second photoconductive substance thereby forming a film of the first photoconductive substance which is not contiguous to the junction surface between the N-type transparent conductive film and the P-type photoconductive film.

摘要翻译： 在用于光电导图像拾取管的目标结构中，P型光电导膜沉积在沉积在透明衬底上的N型透明导电膜上。 P型感光膜包含第一和第二光电导物质。 开始第一光电导物质的沉积比第二光电导物质的延迟预定时间，从而形成第一光电导物质的膜，其不与N型透明导电膜和P型结合面之间的接合面邻接 型感光膜。

公开(公告)号：US4394749A

公开(公告)日：1983-07-19

申请号：US154999

申请日：1980-05-30

申请人： Toshihisa Tsukada ,  Yukio Takasaki ,  Tadaaki Hirai ,  Toru Baji ,  Hideaki Yamamoto ,  Yasuo Tanaka ,  Eiichi Maruyama ,  Sachio Ishioka

发明人： Toshihisa Tsukada ,  Yukio Takasaki ,  Tadaaki Hirai ,  Toru Baji ,  Hideaki Yamamoto ,  Yasuo Tanaka ,  Eiichi Maruyama ,  Sachio Ishioka

IPC分类号： H01L27/146 ,  G11C13/00

CPC分类号： H01L27/14665

摘要： A photoelectric device having at least a predetermined impurity region which is disposed in a semiconductor substrate, and a photoelectric conversion portion which is constructed by stacking an electrode layer lying in contact with at least a part of the impurity region, a photoconductive material layer overlying the electrode layer, and a transparent electrode overlying the photoconductive material layer, characterized in that the photoconductive material layer is made of an amorphous chalcogenide material which principally contains Se, is disclosed. It is very favorable that the photoelectric conversion material layer made of the amorphous material principally containing Se is partially doped with Te so as to enhance its sensitivity. The amorphous chalcogenide material is very useful in the following point. In the course of forming, or after having formed, at least one photoconductive layer on a semiconductor body whose surface is uneven, a heat treatment is performed at a temperature of at least the softening point of the photoconductor so as to flatten the layer, whereby discontinuous parts of the photoconductor ascribable to the uneven surface of the semiconductor body can be avoided.

摘要翻译： 具有至少设置在半导体衬底中的预定杂质区域的光电器件和通过堆叠与至少一部分杂质区域接触的电极层构成的光电转换部分，覆盖 电极层和覆盖光导材料层的透明电极，其特征在于，所述光导材料层由主要包含Se的无定形硫族化物材料制成。 非常有利的是，由主要含有Se的非晶体材料制成的光电转换材料层部分地掺杂有Te以提高其灵敏度。 无定形硫族化物材料在以下方面非常有用。 在形成表面不均匀的半导体本体上形成或形成至少一个光电导层的过程中，至少在光电导体的软化点的温度下进行热处理以使层平坦化，由此 可以避免归因于半导体本体的不平坦表面的感光体的不连续部分。