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1.发明授权Moldable polyester compositions, processes of manufacture, and articles thereof 失效可成型聚酯组合物，制造方法及其制品公开(公告)号：US08791189B2
公开(公告)日：2014-07-29
申请号：US12187723
申请日：2008-08-07
申请人： Parminder Agarwal , Donald Howard Ellington , Robert Russell Gallucci , Josephus Gerardus M. van Gisbergen , Vishvajit Chandrakant Juikar , Ihab Odeh , Sathish Kumar Ranganathan , Kenneth Frederick Miller , Veeraraghavan Srinivasan
发明人： Parminder Agarwal , Donald Howard Ellington , Robert Russell Gallucci , Josephus Gerardus M. van Gisbergen , Vishvajit Chandrakant Juikar , Ihab Odeh , Sathish Kumar Ranganathan , Kenneth Frederick Miller , Veeraraghavan Srinivasan
CPC分类号： C08L67/02 , B29C47/0004 , B29C47/0026 , B29C47/40 , B29C49/0005 , B29C49/04 , B29C49/041 , B29K2067/00 , C08K3/013 , C08K5/134 , C08K5/1515 , C08K5/38 , C08K5/524 , C08L23/0884 , C08L27/18 , C08L55/02 , C08L2666/24
摘要： A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % polyester, 10-49 wt % ABS impact modifier; 0-20 wt % of multifunctional epoxy compound; 0-40 wt % filler; 0-2 wt % fibrillated fluoropolymer; and more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 30-100 Joules at −30° C. and a ductility of more than 90%; a permeability of more than 0 and less than or equal to 1.5 g/m2-day to ASTM D 471-98 Fuel C, measured after exposure to ASTM D 471-98 Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min., measured at 265° C.; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break, after exposure to Fuel E85 for 28 days at 70° C.
摘要翻译： 基于组合物的总重量，热塑性组合物包含：5-1-90wt％聚酯，10-49wt％ABS抗冲改性剂; 0-20重量％多官能环氧化合物; 0-40重量％填料; 0-2重量％原纤化含氟聚合物; 和大于0至5重量％的稳定剂组合物。 由该组合物吹塑或注射成型的制品在-30℃下具有30-100焦耳的多轴冲击总能量和大于90％的延展性; 根据ASTM D 471-98燃料C，在40℃下暴露于ASTM D 471-98燃料C蒸气20周后测量的渗透率大于0且小于或等于1.5g / m 2·天。 在265℃下测量的，为1-20cc / 10分钟的MVR。 弯曲模量大于1300MPa; 并且在70℃下暴露于Fuel E85 28天后，保持其初始拉伸伸长率的至少75％
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2.发明授权Moldable polyester compositions, processes of manufacture, and articles thereof 有权可成型聚酯组合物，制造方法及其制品公开(公告)号：US08168707B2
公开(公告)日：2012-05-01
申请号：US12187630
申请日：2008-08-07
申请人： Parminder Agarwal , Donald Howard Ellington , Robert Russell Gallucci , Josephus Gerardus M. van Gisbergen , Vishvajit Chandrakant Juikar , Ihab Odeh , Sathish Kumar Ranganathan , Kenneth Frederick Miller , Veeraraghavan Srinivasan
发明人： Parminder Agarwal , Donald Howard Ellington , Robert Russell Gallucci , Josephus Gerardus M. van Gisbergen , Vishvajit Chandrakant Juikar , Ihab Odeh , Sathish Kumar Ranganathan , Kenneth Frederick Miller , Veeraraghavan Srinivasan
IPC分类号： C08K5/37
CPC分类号： C08L67/02 , B29C47/0004 , B29C47/0026 , B29C47/40 , B29C49/0005 , B29C49/04 , B29C49/041 , B29K2067/00 , C08K3/013 , C08K5/134 , C08K5/1515 , C08K5/38 , C08K5/524 , C08K5/5317 , C08L23/0884 , C08L25/12 , C08L27/18 , C08L55/02 , Y10T428/1386 , C08L2666/24 , C08L2666/02
摘要： A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % of a polyester, 10-49 wt % of an ABS impact modifier; 0 to 20 wt % of a multifunctional epoxy compound; 0-40 wt % of a filler; 0-2 wt % of a fibrillated fluoropolymer; and from more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 40-100 Joules at −30° C.; a ductility of more than 90%, a permeability of more than 0 to less than or equal to 1.5 g/m2-day, measured after exposure Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break after exposure to Fuel E85 for 28 days at 70° C.
摘要翻译： 基于组合物的总重量，热塑性组合物包含：5-1-90wt％的聚酯，10-49wt％的ABS抗冲改性剂; 0〜20重量％的多官能环氧化合物; 0-40重量％的填料; 0-2重量％的原纤化含氟聚合物; 和超过0至5重量％的稳定剂组合物。 由该组合物吹塑或注射成型的制品在-30℃下具有40-100焦耳的多轴冲击总能量; 在40℃下暴露燃料C蒸气20周后测量的延展性大于90％，渗透率大于0至小于或等于1.5g / m 2·天。 一个20cc / 10min的MVR; 弯曲模量大于1300MPa; 并且在70℃下暴露于Fuel E85 28天后保持其初始拉伸伸长率的至少75％
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公开(公告)号：US20080246191A1
公开(公告)日：2008-10-09
申请号：US11697456
申请日：2007-04-06
CPC分类号： C08G63/916 , C08L23/0884 , C08L27/18 , C08L67/02 , C08L2666/04 , C08L2666/06
摘要： A polyester composition comprising a reaction product of 50 to 95 wt. % of a polyester having a number average molecular weight of greater than or equal to 42,450 g/mol, wherein the polyester is of the formula wherein T is a divalent C6-10 aromatic group derived from a dicarboxylic acid, and D is a divalent C2-4 aliphatic group derived from a dihydroxy compound; 16 to 25 wt. % of a carboxy reactive impact modifier; and more than 0 to 5 wt. % of a fluoropolymer; wherein the composition has less than 70 wt. % of a polyester derived from a dicarboxylic acid and an aliphatic diol component selected from 1,3-propylene glycol, neopentyl glycol, 1,5-pentanediol, 1,6-hexanediol, decamethylene glycol, cyclohexanediol, and 1,4-cyclohexanedimethanol.
摘要翻译： 一种聚酯组合物，其包含50至95重量％ 数均分子量大于或等于42,450g / mol的聚酯，其中聚酯具有下式：其中T是衍生自二羧酸的二价C 6-10-10芳族基团 酸，D是衍生自二羟基化合物的二价C 2-4脂肪族基团; 16〜25wt。 ％的羧基反应性抗冲改性剂; 和大于0至5重量％ ％的含氟聚合物; 其中所述组合物具有小于70wt。 来自二羧酸的聚酯和选自1,3-丙二醇，新戊二醇，1,5-戊二醇，1,6-己二醇，癸二醇，环己二醇和1,4-环己烷二甲醇的脂族二醇组分的％。
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4.发明申请公开(公告)号：US20120184662A1
公开(公告)日：2012-07-19
申请号：US13007031
申请日：2011-01-14
CPC分类号： C08L67/02 , C08L27/12 , C08L51/003 , C08L51/04 , C08L55/02 , C08L69/00 , C08L69/005 , C08L2205/02 , C08L2207/53
摘要： Disclosed herein is a thermoplastic composition comprising, based on the total weight of the composition: (a) from 10 to 80 wt. % of a polybutylene terephthalate; (b) from 10 to 80 wt. % of a copolyestercarbonate component, comprising a first copolyestercarbonate having a number average molecular weight of 15,000 to less than 28,000 Daltons, and a second copolyestercarbonate having a number average molecular weight of more than 28,000 to 40,000 Daltons, wherein a weight ratio of the first polyestercarbonate to the second polyestercarbonate is 95:5 to 20:80; (c) from 3 to 30 wt. % of a particulate filler; (d) from 0.1 to 10 wt. % of a fluoropolymer; and (e) from 3 to 25 wt. % of a polymeric impact modifier. A method of making the composition and an article comprising the thermoplastic composition are also disclosed.
摘要翻译： 本文公开了一种热塑性组合物，其包含基于组合物的总重量：（a）10至80重量％ ％的聚对苯二甲酸丁二醇酯; （b）10〜80wt。 ％的共聚酯碳酸酯组分，其包含数均分子量为15,000至小于28,000道尔顿的第一共聚酯碳酸酯和数均分子量大于28,000至40,000道尔顿的第二共聚酯碳酸酯，其中第一聚酯碳酸酯的重量比 至第二聚酯碳酸酯为95:5至20:80; （c）3〜30wt。 ％的颗粒填料; （d）0.1〜10wt。 ％的含氟聚合物; 和（e）3至25wt。 ％的聚合抗冲改性剂。 还公开了制备组合物的方法和包含热塑性组合物的制品。
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公开(公告)号：US07022776B2
公开(公告)日：2006-04-04
申请号：US09683002
申请日：2001-11-07
申请人： Jozef Herman Peter Bastiaens , Gerardus Johannes Cornelis Doggen , Josephus Gerardus M. van Gisbergen
发明人： Jozef Herman Peter Bastiaens , Gerardus Johannes Cornelis Doggen , Josephus Gerardus M. van Gisbergen
CPC分类号： H01B1/24 , C08G2261/514 , C08L71/12 , C08L71/123 , C08L77/00 , C08L77/02 , C08L77/06 , H01B1/128 , H01B1/20 , H01B1/22 , C08L71/00
摘要： A conductive thermoplastic composition includes specific amounts of a polyphenylene ether copolymer, a polyamide, and an electrically conductive filler. The composition exhibits excellent high-temperature dimensional stability and impact strength, and it is particularly useful for molding automotive body panels that are subsequently electrostatically painted.
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6.发明申请FLOW ENHANCED THERMOPLASTIC COMPOSITIONS AND METHODS FOR ENHANCING THE FLOW OF THERMOPLASTIC COMPOSITIONS 审中-公开流动增强热塑性组合物和增强热塑性组合物流动的方法公开(公告)号：US20150126664A1
公开(公告)日：2015-05-07
申请号：US14598605
申请日：2015-01-16
申请人： Josephus Gerardus M. van Gisbergen , Chris van der Weele , Sreepadaraj Karanam , Mark Adrianus Johannes van der Mee
发明人： Josephus Gerardus M. van Gisbergen , Chris van der Weele , Sreepadaraj Karanam , Mark Adrianus Johannes van der Mee
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08K3/01 , C08K2201/014 , C08L2201/02 , C08L2205/025 , C08L2205/035 , C08L2207/53 , C08K3/0008 , C08L67/00
摘要： A composition that contains from 30 to 95 wt. %, based on the total weight of the composition, of a thermoplastic component and an effective amount of a flow-enhancing component. The effective amount of the flow-enhancing component reduces the viscosity of the composition by at least 10% compared to the viscosity of a composition comprising the thermoplastic component, but not an effective amount of the flow-enhancing component. The thermoplastic component is selected from the group consisting of polycarbonates, polyesters, and combinations thereof. The flow-enhancing component comprises b1) a component selected from the group consisting of metal oxides, metalloid oxides, metal alkoxides, metalloid alkoxides, and combinations thereof and b2) a mineral filler component. The weight ratio of component b1) to component b2) ranges from 1:25 to 25:1. A method for enhancing the flow of compositions comprising thermoplastic components is also disclosed.
摘要翻译： 含有30〜95重量％ ％，基于组合物的总重量，热塑性组分和有效量的流动增强组分。 与含有热塑性组分的组合物的粘度相比，流动增强组分的有效量将组合物的粘度降低至少10％，而不是有效量的流动增强组分。 热塑性组分选自聚碳酸酯，聚酯及其组合。 流动增强组分包括b1）选自金属氧化物，准金属氧化物，金属醇盐，准金属醇盐及其组合的组分，和b2）矿物填料组分。 组分b1）与组分b2）的重量比范围为1:25至25:1。 还公开了一种增强包含热塑性组分的组合物流动的方法。
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7.发明授权公开(公告)号：US08404772B2
公开(公告)日：2013-03-26
申请号：US13006996
申请日：2011-01-14
CPC分类号： C08L67/02 , C08G59/226 , C08G59/26 , C08G59/3218 , C08K3/013 , C08L27/18 , C08L51/04 , C08L55/02 , C08L69/005
摘要： A thermoplastic composition comprises, based on the total weight of the composition, (a) from 10 to 80 wt. % of a polybutylene terephthalate; (b) from 10 to 80 wt. % of a copolyestercarbonate having a number average molecular weight of more than 21,500 Daltons; (c) from 7 to 30 wt. % of a particulate filler; (d) from 0.1 to 10 wt. % of a fluoropolymer; and (e) from 3 to 25 wt. % of a polymeric impact modifier. The thermoplastic composition can be prepared by melt blending components, and the thermoplastic composition can be used for making automotive body panels or enclosures.
摘要翻译： 基于组合物的总重量，热塑性组合物包含（a）10至80wt。 ％的聚对苯二甲酸丁二醇酯; （b）10〜80wt。 ％的数均分子量大于21,500道尔顿的共聚酯碳酸酯; （c）7〜30wt。 ％的颗粒填料; （d）0.1〜10wt。 ％的含氟聚合物; 和（e）3至25wt。 ％的聚合抗冲改性剂。 热塑性组合物可以通过熔融共混组分制备，并且热塑性组合物可用于制造汽车车身面板或外壳。
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8.发明申请公开(公告)号：US20120184661A1
公开(公告)日：2012-07-19
申请号：US13006996
申请日：2011-01-14
IPC分类号： C08K3/34 , B29C49/00 , B29C41/00 , B29C47/00 , B29C51/00 , B29C43/00 , C08L67/02 , C08L33/20 , C08L69/00 , C08L9/06 , B29C44/00 , B29C45/00
CPC分类号： C08L67/02 , C08G59/226 , C08G59/26 , C08G59/3218 , C08K3/013 , C08L27/18 , C08L51/04 , C08L55/02 , C08L69/005
摘要： Disclosed herein is a thermoplastic composition comprising, based on the total weight of the composition, (a) from 10 to 80 wt. % of a polybutylene terephthalate; (b) from 10 to 80 wt. % of a copolyestercarbonate having a number average molecular weight of more than 21,500 Daltons; (c) from 7 to 30 wt. % of a particulate filler; (d) from 0.1 to 10 wt. % of a fluoropolymer; and (e) from 3 to 25 wt. % of a polymeric impact modifier. A method of making the composition and an article comprising the thermoplastic composition are also disclosed.
摘要翻译： 本文公开了一种热塑性组合物，其包含基于组合物的总重量，（a）10至80重量％ ％的聚对苯二甲酸丁二醇酯; （b）10〜80wt。 ％的数均分子量大于21,500道尔顿的共聚酯碳酸酯; （c）7〜30wt。 ％的颗粒填料; （d）0.1〜10wt。 ％的含氟聚合物; 和（e）3至25wt。 ％的聚合抗冲改性剂。 还公开了制备组合物的方法和包含热塑性组合物的制品。
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9.发明申请FLAME-RESISTANT POLYESTER-POLYCARBONATE COMPOSITIONS, METHODS OF MANUFACTURE, AND ARTICLES THEREOF 审中-公开阻燃聚酯 - 聚碳酸酯组合物，制造方法及其制品公开(公告)号：US20130317150A1
公开(公告)日：2013-11-28
申请号：US13990519
申请日：2010-11-05
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08G77/448 , C08K5/0008 , C08K5/523 , C08K5/526 , C08L27/12 , C08L27/18 , C08L51/04 , C08L53/00 , C08L67/02 , C08L83/10
摘要： A composition comprising a polyester, polycarbonate, organopolysiloxane-polycarbonate block copolymer, organophosphorus flame retardant, fluorinated polyolefin, and one or more additives. In one embodiment, the composition has an improved balance of properties, including one or more of a melt volume rate, Vicat softening temperature, notched Izod impact strength and a UL 94 flammability rating.
摘要翻译： 包含聚酯，聚碳酸酯，有机聚硅氧烷 - 聚碳酸酯嵌段共聚物，有机磷阻燃剂，氟化聚烯烃和一种或多种添加剂的组合物。 在一个实施方案中，组合物具有改进的性能平衡，包括熔体体积率，维卡软化温度，缺口伊佐德冲击强度和UL94可燃性等级中的一种或多种。
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10.发明授权Method for improving the paint adhesion of compatibilized polyphenylene ether-polyamide compositions 失效改善相容的聚苯醚 - 聚酰胺组合物的漆附着力的方法公开(公告)号：US06936652B2
公开(公告)日：2005-08-30
申请号：US10289664
申请日：2002-11-07
IPC分类号： C08J5/00 , C08K3/04 , C08K5/00 , C08K5/134 , C08K5/372 , C08K7/24 , C08L23/30 , C08L53/00 , C08L53/02 , C08L71/12 , C08L77/00 , C09K15/08 , C09K15/12 , C08K5/13
CPC分类号： C08K5/1345 , B82Y30/00 , C08K3/04 , C08K3/041 , C08K5/005 , C08K5/372 , C08K2201/011 , C08L25/08 , C08L53/02 , C08L53/025 , C08L65/00 , C08L71/12 , C08L77/00 , C08L77/02 , C08L77/06 , Y10S524/902 , Y10S524/904 , Y10S977/753 , C08L77/12 , C08K7/24 , C08L2666/14 , C08L2666/20 , C08L2666/22
摘要： Thermoplastic resin composition are provided that comprise a thermoplastic resin and an amount of antioxidant effective to increase the adhesion of paint to an article made from the composition. Also provided are methods to improve the paint adhesion of articles wherein the articles have been subjected to a temperature of at least about 330° F. for period of at least about 10 minutes. In a preferred embodiment, the antioxidant, also known as a stabilizer, or mixture of stabilizers is selected from the group consisting of the phenolic antioxidants, the 3-arylbenzofuranones, the hindered amine stabilizers, the ultraviolet light absorbers, the alkaline metal salts of fatty acids, the hydrotalcites, the epoxydized soybean oils, the hydroxylamines, the tertiary amine oxides, thermal reaction products of tertiary amine oxides, the thiosynergists, and mixture containing at least one of the foregoing.
摘要翻译： 提供热塑性树脂组合物，其包含热塑性树脂和一定量的抗氧化剂，其有效地增加涂料对由该组合物制成的制品的粘附性。 还提供了改善制品的涂料附着力的方法，其中制品已经经受至少约330°F的温度至少约10分钟的时间。 在优选的实施方案中，还称为稳定剂的抗氧化剂或稳定剂的混合物选自酚类抗氧化剂，3-芳基苯并呋喃酮，受阻胺稳定剂，紫外光吸收剂，脂肪族的碱金属盐 酸，水滑石，环氧化大豆油，羟胺，叔胺氧化物，叔胺氧化物的热反应产物，硫代增效剂和含有至少一种上述物质的混合物。
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