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    Process for manufacturing a catalyst containing iron, chromium and potassium oxides and at least one rare earth metal oxide, for use in dehydrogenation reactions
    2.
    发明授权
    Process for manufacturing a catalyst containing iron, chromium and potassium oxides and at least one rare earth metal oxide, for use in dehydrogenation reactions 失效
    用于制造含有铁，铬和钾的氧化物和至少一种稀土金属氧化物的催化剂的方法，用于脱氢反应

    公开(公告)号：US4533650A

    公开(公告)日：1985-08-06

    申请号：US561374

    申请日：1983-12-14

    申请人： Philippe Courty ,  Michel Roussel ,  Serge Leporq ,  Jean-Francois Le Page ,  Philippe Varin

    发明人： Philippe Courty ,  Michel Roussel ,  Serge Leporq ,  Jean-Francois Le Page ,  Philippe Varin

    IPC分类号： B01J23/86 ,  C07C5/333 ,  B01J21/16 ,  B01J23/10

    CPC分类号： B01J23/862 ,  C07C5/3332

    摘要： A process for manufacturing catalysts containing, as oxides, iron, chromium, potassium, as well as a rare earth metal in a proportion, calculated in oxide weight, of 1-15% with respect to the final catalyst, comprises:a first step, wherein a product is prepared by a reaction between compounds of rare earth metal(s) and of another metal selected from Fe, Cr, Co, Al or V, and a calcination; anda second step wherein a mixture is formed between the product resulting from the first step, the other necessary reactants and water; the resulting paste is dried after optional shaping and calcined. A clayish material can be used in the step.The catalysts obtained present an improved efficiency in dehydrogenation reactions, particularly of ethylbenzene to styrene.

    摘要翻译： 一种制备催化剂的方法，所述催化剂包含以相对于最终催化剂为1-15％的氧化物重量计，氧化物，铁，铬，钾以及稀土金属的一部分，以氧化物重量计，含有：第一步， 其中通过稀土金属化合物和选自Fe，Cr，Co，Al或V的另一种金属之间的反应和煅烧来制备产物; 第二步，其中在由第一步产生的产物，其它必需的反应物和水之间形成混合物; 所得糊状物在任选成型和干燥后进行干燥。 在该步骤中可以使用粘土材料。 获得的催化剂提供了脱氢反应，特别是乙苯至苯乙烯的改进效率。

    Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst
    8.
    发明授权
    Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst 失效
    使用碱性固体催化剂不经常地加入碱性溶液来甜化石油馏分的方法

    公开(公告)号：US5591323A

    公开(公告)日：1997-01-07

    申请号：US474766

    申请日：1995-06-07

    申请人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

    发明人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

    IPC分类号： B01J21/16 ,  B01J27/26 ,  B01J29/06 ,  B01J37/00 ,  C10G25/00 ,  C10G27/10 ,  C10G27/00 ,  C10G27/04

    CPC分类号： B01J21/16 ,  B01J27/26 ,  C10G27/10 ,  B01J37/0009

    摘要： A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by being contacted with a porous catalyst, in the presence of air said process being characterised in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of an alkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milligrams of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.

    摘要翻译： 一种用于甜化含有硫醇的石油馏分的方法，其中所述石油馏分通过与多孔催化剂接触而经受氧化条件，在空气存在下，所述方法的特征在于所述催化剂至少包含10至98重量％ 一个矿物固相由Si / Al原子比小于或等于5,1-60重量％的活性炭，0.02-2重量％的至少一种金属螯合物和0-20重量％的碱性硅铝酸盐构成， 的至少一种有机或矿物结合剂，具有根据2896 ASTM标准确定的碱度，每克20mg的钾碱和10m 2 g -1的总BET表面积，并且在其孔结构内部含有永久性水性 相为干燥催化剂的0.1-40重量％。

    Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst
    9.
    发明授权
    Process for sweetening petroleum cuts without regular addition of alkaline solution using a basic solid catalyst 失效
    使用碱性固体催化剂不经常地加入碱性溶液来甜化石油馏分的方法

    公开(公告)号：US5633216A

    公开(公告)日：1997-05-27

    申请号：US474767

    申请日：1995-06-07

    申请人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

    发明人： Christian Marcilly ,  Serge Leporq ,  Philippe Courty

    IPC分类号： B01J21/16 ,  B01J27/26 ,  B01J37/00 ,  C10G27/10 ,  B01J29/072

    CPC分类号： B01J21/16 ,  B01J27/26 ,  C10G27/10 ,  B01J37/0009

    摘要： A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by its being passed in the presence of air in contact with a porous catalyst said process being characterized in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of analkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milli-equivalents of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.

    摘要翻译： 一种用于甜化含有硫醇的石油馏分的方法，其中所述石油馏分通过在与多孔催化剂接触的空气存在下通过氧化条件，所述方法的特征在于所述催化剂包含10至98重量％ 至少一种由Si / Al原子比小于或等于5,1-60重量％的活性炭，0.02-2重量％的至少一种金属螯合物和0至20重量份的由矾土铝硅酸盐构成的矿物固相 至少一种有机或矿物结合剂的重量百分比具有根据2896 ASTM标准确定的碱度，每克20毫克当量钾和总共BET表面积为10m 2·g -1，并包含在其孔结构内 代表0.1-40重量％干催化剂的永久性水相。