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1.发明申请公开(公告)号：US20100048389A1
公开(公告)日：2010-02-25
申请号：US12520702
申请日：2007-12-07
IPC分类号： B01J27/185 , B01J27/135
CPC分类号： B01J23/622 , B01J27/135 , B01J27/1856 , B01J35/002 , B01J37/0205 , B01J37/0207 , B01J37/024 , C10G35/09
摘要： The invention relates to a catalyst that comprises a metal M from the group of platinum, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally at least one promoter X2 that is selected from the group that consists of gallium, indium and thallium, a halogenated compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108. The invention also relates to the process for the preparation of this catalyst and a reforming process using said catalyst.
摘要翻译： 本发明涉及一种催化剂，其包含来自铂族的金属M，至少一种选自由锡，锗和铅组成的基团的启动子X1，以及任选地至少一种选自以下的启动子X2： 由镓，铟和铊组成的组，卤化化合物和多孔基材，其中原子比X1 / M和任选的X2 / M为0.3至8，通过氢吸附测量的Hir / M比较大 并且通过氢/氧滴定测量的双金属指数BMI大于108.本发明还涉及制备该催化剂的方法和使用所述催化剂的重整方法。
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2.发明授权Bimetallic or multi-metallic catalyst that has an optimized bimetallicity index and an optimized hydrogen adsorption capacity 有权双金属或多金属催化剂具有优化的双金属指数和优化的氢吸附能力公开(公告)号：US08148288B2
公开(公告)日：2012-04-03
申请号：US12520702
申请日：2007-12-07
IPC分类号： B01J21/06 , B01J27/185 , B01J27/135 , B01J27/13 , B01J23/00 , B01J23/42 , B01J23/44 , C10G57/00 , C10G69/02 , C10G35/04 , C10G59/02 , C10G35/06 , C10G63/02 , C10G69/08 , C10G35/00
CPC分类号： B01J23/622 , B01J27/135 , B01J27/1856 , B01J35/002 , B01J37/0205 , B01J37/0207 , B01J37/024 , C10G35/09
摘要： The invention relates to a catalyst that comprises a metal M from the group of platinum, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally at least one promoter X2 that is selected from the group that consists of gallium, indium and thallium, a halogenated compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108. The invention also relates to the process for the preparation of this catalyst and a reforming process using said catalyst.
摘要翻译： 本发明涉及一种催化剂，其包含来自铂族的金属M，至少一种选自由锡，锗和铅组成的基团的启动子X1，以及任选地至少一种选自以下的启动子X2： 由镓，铟和铊组成的组，卤化化合物和多孔基材，其中原子比X1 / M和任选的X2 / M为0.3至8，通过氢吸附测量的Hir / M比较大 并且通过氢/氧滴定测量的双金属指数BMI大于108.本发明还涉及制备该催化剂的方法和使用所述催化剂的重整方法。
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3.发明授权Process for dehydrogenation in the presence of a bimetallic or multi-metallic catalyst that has an optimized bimetallicity index and an optimized hydrogen adsorption capacity 有权在双金属或多金属催化剂存在下脱氢的方法，其具有优化的双金属指数和优化的氢吸附能力公开(公告)号：US08309782B2
公开(公告)日：2012-11-13
申请号：US12520445
申请日：2007-12-07
申请人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
发明人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
IPC分类号： C07C5/333
CPC分类号： B01J23/626 , B01J21/04 , B01J23/62 , B01J35/1019 , B01J35/1042 , B01J37/0063 , B01J37/0207 , B01J37/06 , C07C5/3337 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C10G35/09 , C07C11/02
摘要： The invention relates to a process for dehydrogenation of a hydrocarbon feedstock in the presence of a catalyst that comprises a noble metal M that is selected from the group that consists of platinum, palladium, rhodium, and iridium, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally a promoter X2 that is selected from the group that consists of gallium, indium and thallium, an alkaline or alkaline-earth compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108.
摘要翻译： 本发明涉及一种在催化剂存在下烃原料脱氢的方法，所述催化剂包含贵金属M，所述贵金属M选自由铂，钯，铑和铱组成的组，所述催化剂选自至少一个选自 来自由锡，锗和铅组成的组，以及任选的选自由镓，铟和铊，碱金属或碱土金属化合物和多孔基材组成的组的启动子X2，其中原子比 X1 / M和任选的X2 / M在0.3和8之间，通过氢吸附测量的Hir / M比大于0.40，并且通过氢/氧滴定测量的双金属指数BMI大于108。
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4.发明申请公开(公告)号：US20100168493A1
公开(公告)日：2010-07-01
申请号：US12520445
申请日：2007-12-07
申请人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
发明人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
IPC分类号： C07C5/333
CPC分类号： B01J23/626 , B01J21/04 , B01J23/62 , B01J35/1019 , B01J35/1042 , B01J37/0063 , B01J37/0207 , B01J37/06 , C07C5/3337 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C10G35/09 , C07C11/02
摘要： The invention relates to a process for dehydrogenation of a hydrocarbon feedstock in the presence of a catalyst that comprises a noble metal M that is selected from the group that consists of platinum, palladium, rhodium, and iridium, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally a promoter X2 that is selected from the group that consists of gallium, indium and thallium, an alkaline or alkaline-earth compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108.
摘要翻译： 本发明涉及一种在催化剂存在下烃原料脱氢的方法，所述催化剂包含贵金属M，所述贵金属M选自由铂，钯，铑和铱组成的组，所述催化剂选自至少一个选自 来自由锡，锗和铅组成的组，以及任选的选自由镓，铟和铊，碱金属或碱土金属化合物和多孔基材组成的组的启动子X2，其中原子比 X1 / M和任选的X2 / M在0.3和8之间，通过氢吸附测量的Hir / M比大于0.40，并且通过氢/氧滴定测量的双金属指数BMI大于108。
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公开(公告)号：US20110040136A1
公开(公告)日：2011-02-17
申请号：US12989278
申请日：2009-03-27
IPC分类号： C07C7/148
CPC分类号： C10G45/04 , B01D53/04 , B01D53/75 , B01D53/8662 , B01D2253/104 , B01D2255/1021 , B01D2255/1023 , B01D2255/202 , B01D2255/204 , B01D2257/2045 , B01D2257/2064 , C10G25/003 , C10G35/04 , C10G45/10 , C10G69/08 , C10G2300/201
摘要： The invention concerns a process for purification by elimination of chlorine in the form of hydrogen chloride and organochlorine compounds by contacting in the presence of hydrogen of at least a part of the effluent from a reforming, aromatics production, dehydrogenation, isomerisation or hydrogenation zone, said part of the effluent comprising olefins, hydrogen chloride and organochlorine compounds, on an elimination zone comprising a chain arrangement of two masses, the first mass being a mass comprising at least one metal from group VIII deposited on a mineral carrier and the second mass being a hydrogen chloride adsorbent.
摘要翻译： 本发明涉及一种通过以氯化氢和有机氯化合物的形式消除氯的纯化方法，其通过在氢气存在下与来自重整，芳族化合物生产，脱氢，异构化或氢化区的至少一部分流出物接触来进行纯化，所述方法 包含烯烃，氯化氢和有机氯化合物的一部分流出物在包括两个质量块的链排列的消除区上，第一质量块是包含至少一种沉积在矿物载体上的来自第VIII族的金属的物质，第二质量是 氯化氢吸附剂。
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6.发明授权Catalyst of the galloaluminosilicate type containing gallium, a nobel metal of the platinum family and at least on additional metal, and its use in the aromatization of hydrocarbons 失效包含镓的镓铝硅酸盐型催化剂，铂族的诺贝尔金属，至少在额外的金属上，以及其在烃类芳构化中的应用
公开(公告)号：US5456822A
公开(公告)日：1995-10-10
申请号：US141000
申请日：1993-10-26
IPC分类号： B01J29/44 , B01J29/87 , C07C2/00 , C07C15/00 , C10G35/095 , C10G35/085
CPC分类号： B01J29/87 , B01J29/44 , C07C2/00 , B01J2229/26 , B01J2229/42 , C07C2521/04 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/40 , C07C2523/46 , C07C2523/50 , C07C2523/72 , C07C2523/74 , C07C2523/745 , C07C2523/755 , C07C2529/44
摘要： Disclosed are reactions for the aromatization of hydrocarbons containing 2 to 9 carbon atoms per molecule, with a composite catalyst containing:an MFI zeolite in hydrogen form, the framework containing at least one of the elements silicon, aluminum and/or gallium; a matrix; gallium; at least one noble metal of the platinum family, at least one additional metal selected from the group made up of tin, germanium, indium, copper, iron, molybdenum, gallium, thallium, gold, silver, ruthenium, chromium, tungsten and lead, and possibly a compound selected from the group made up of alkali and alkaline earth metals.
摘要翻译： 公开了每分子含有2至9个碳原子的烃的芳构化反应，其中复合催化剂包含：氢形式的MFI沸石，所述骨架含有至少一种元素硅，铝和/或镓; 矩阵 镓; 至少一种铂族贵金属，选自由锡，锗，铟，铜，铁，钼，镓，铊，金，银，钌，铬，钨和铅组成的组中的至少一种另外的金属， 并且可能是选自碱金属和碱土金属组成的组中的化合物。
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7.发明授权Process for the production of high-quality kerosene and diesel fuels for the coproduction of hydrogen from saturated light cuts 有权用于生产高质量煤油和柴油燃料的方法，用于从饱和光切割共同生产氢气公开(公告)号：US08470165B2
公开(公告)日：2013-06-25
申请号：US12944981
申请日：2010-11-12
CPC分类号： C10G69/126 , C10G35/09 , C10G50/00 , C10G2300/1022 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2400/04 , C10G2400/08
摘要： Process for the production of high-quality kerosene and diesel fuels and for the coproduction of hydrogen from a so-called light naphtha cut to which any quantity of LPG cut can be added where the steps of the process include: separating normal and iso-paraffins, dehydrogenation of the paraffins, oligomerization of the olefins and hydrogenation of the oligomerized olefins, the process permitting the production of kerosene and diesel fuels meeting market specifications, or even improved relative to the latter.
摘要翻译： 用于生产高质量煤油和柴油燃料的方法以及从所谓的轻石脑油切割生产氢气的方法，在该方法中可以加入任何量的LPG馏分，其中该方法的步骤包括：分离正烷烃和异链烷烃 ，链烷烃的脱氢，烯烃的低聚和低聚烯烃的氢化，允许生产符合市场规格的煤油和柴油的方法，甚至相对于后者的改进。
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8.发明授权Method and apparatus for detecting and quantifying a chemical compound in a fluid flow 有权用于检测和定量流体流中的化合物的方法和装置公开(公告)号：US08393195B2
公开(公告)日：2013-03-12
申请号：US12669227
申请日：2008-06-24
CPC分类号： G01N1/4005 , G01N1/2214 , G01N1/2247 , G01N2001/4011
摘要： A method and apparatus for capturing a chemical compound, typically an impurity, and for accumulating said chemical compound on a capture mass CAPT included in at least one removable adsorbent cartridge MC over a period exceeding 2 days, with a view to the external chemical analysis thereof. The apparatus ST suitable for capturing at least one chemical compound in a fluid flow for its detection and/or quantification comprise, downstream of said cartridge or cartridges, at least one device for measuring the cumulative flow which has traversed the cartridge or cartridges over a set time period. In a preferred variation of the invention, the capture mass CAPT is fragmented into a plurality of elementary masses CAPTi which allows for the spread of an irreversible adsorption front or the displacement of a chromatographic zone.
摘要翻译： 为了对其进行外部化学分析，本发明提供了一种用于捕获化合物（通常为杂质）的方法和装置，并且用于在超过2天的时间内将所述化合物累积在包含在至少一个可移除吸附剂盒MC中的捕获质量CAPT 。 适于捕获流体流中的至少一种化学化合物用于其检测和/或定量的装置ST包括在所述药筒或药筒的下游的至少一个装置，用于测量已经穿过药筒或药筒的累积流量 时间段。 在本发明的优选变型中，捕获质量CAPT被分段成多个基本质量CAPTi，其允许不可逆吸附前沿的扩散或色谱区的移位。
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公开(公告)号：US08361798B2
公开(公告)日：2013-01-29
申请号：US12668992
申请日：2008-06-24
IPC分类号： G01N31/10
CPC分类号： B01J8/0285 , B01J8/008 , B01J8/0453 , B01J35/00 , B01J2208/00061 , B01J2208/00407 , B01J2208/00814 , B01J2208/00964 , B01J2208/00973 , B01J2219/00286 , B01J2219/00495 , B01J2219/00585 , B01J2219/00747 , G01N31/10
摘要： For testing performance levels and/ or changes over time of at least one catalyst (CAT) for a fixed-bed reactor: a device (CT) for a test, comprising at least one hollow metal cartridge (MC) containing the catalyst (CAT) is connected at a point A of an industrial chemical installation containing a reaction feedstock suitable for testing the catalyst (CAT); a liquid stream containing a fraction that is less than or equal to 1% of preheated reagents circulating in the industrial chemical installation is circulated in the cartridge (MC) through the catalyst (CAT) and sampled at a reaction temperature for a period (T), and returned to the industrial chemical installation at point B downstream of the device.
摘要翻译： 用于测试用于固定床反应器的至少一种催化剂（CAT）的性能水平和/或随时间的变化：用于测试的装置（CT），包括至少一个含有催化剂（CAT）的空心金属盒（MC） 在含有适用于测试催化剂（CAT）的反应原料的工业化学设备的A点连接; 含有小于或等于在工业化学设备中循环的预热试剂的1％的馏分的液体流在筒（MC）中通过催化剂（CAT）循环，并在反应温度下进行一段时间（T）采样， 并返回设备下游B点的工业化学品安装。
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10.发明授权Catalytic reduction of substituted or unsubstituted nitroaromatic compound to corresponding aminoaromatic compounds 失效取代或未经取代的硝基化合物的催化还原相应的氨基化合物
公开(公告)号：US5235106A
公开(公告)日：1993-08-10
申请号：US817559
申请日：1992-01-07
申请人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
发明人： Blaise Didillon , Fabienne Le Peltier , Jean-Pierre Candy , Patrick Sarrazin , Jean-Paul Boitiaux , Jean-Marie Basset
IPC分类号： B01J23/62 , C07B61/00 , C07C209/36 , C07C209/38 , C07C211/52 , C07C211/56 , C07C213/02 , C07C215/76 , C07C217/82 , C07C219/34
CPC分类号： B01J23/622 , C07C209/36 , C07C209/365
摘要： The invention concerns the production of a substituted or unsubstituted aniline by selective hydrogenation of the corresponding nitroaromatic compound. It is characterized by the use of a catalyst based on a metal selected from rhodium and ruthenium and based on a metal selected from the group comprising tin, germanium and lead.
摘要翻译： 本发明涉及通过相应的硝基芳族化合物的选择性氢化生产取代或未取代的苯胺。 其特征在于使用基于选自铑和钌的金属和基于选自锡，锗和铅的金属的催化剂。
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